Search Results (6)

Soil salinization presents a significant challenge, driven by factors such as inadequate drainage, shallow aquifers, and high evaporation rates, threatening global food security. The sunflower emerges as a key cash crop in such areas, providing the opportunity to convert its straw into biochar, which offers additional agronomic and environmental benefits. This study investigates the effectiveness of biochar interlayers in enhancing salt leaching and suppressing upward salt migration through integrated laboratory and field experiments. The effectiveness of varying biochar interlayer application rates was assessed in promoting salt leaching, decreasing soil electrical conductivity (EC), and enhancing crop performance in saline soils through a systematic approach that combines laboratory and field experiments. The biochar treatments included a control (CK) and different applications of 20 (BL20), 40 (BL40), 60 (BL60), and 80 (BL80) tons of biochar per hectare, all applied below a depth of 20 cm, with each treatment replicated three times. The laboratory and field experimental setups maintained consistency in terms of biochar treatments and interlayer placement methodology. During the laboratory column experiments, the soil columns were treated with deionized water, and their leachates were analyzed for EC and major ionic components. The results showed that columns with biochar interlayers exhibited significantly higher efflux rates compared to those of the control and notably accelerated the time required for the effluent EC to decrease to 2 dS m⁻¹. The CK required 43 days for full discharge and 38 days for EC stabilization below 2 dS m⁻¹. In contrast, biochar treatments notably reduced these times, with BL80 achieving discharge in just 7 days and EC stabilization in 10 days. Elution events occurred 20–36 days earlier in the biochar-treated columns, confirming biochar’s effectiveness in enhancing leaching efficiency in saline soils. The field experiment results supported the laboratory findings, indicating that increased biochar application rates significantly reduced soil EC and ion concentrations at depths of 0–20 cm and 20–40 cm, lowering the EC from 7.12 to 2.25 dS m⁻¹ and from 6.30 to 2.41 dS m⁻¹ in their respective layers. The application of biochar interlayers resulted in significant reductions in Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄²⁻, and HCO₃⁻ concentrations across both soil layers. In the 0–20 cm layer, Na⁺ decreased from 3.44 to 2.75 mg·g⁻¹, K⁺ from 0.24 to 0.11 mg·g⁻¹, Ca²⁺ from 0.35 to 0.20 mg·g⁻¹, Mg²⁺ from 0.31 to 0.24 mg·g⁻¹, Cl⁻ from 1.22 to 0.88 mg·g⁻¹, SO₄²⁻ from 1.91 to 1.30 mg·g⁻¹ and HCO₃⁻ from 0.39 to 0.18 mg·g⁻¹, respectively. Similarly, in the 20–40 cm layer, Na⁺ declined from 3.62 to 3.05 mg·g⁻¹, K⁺ from 0.28 to 0.12 mg·g⁻¹, Ca²⁺ from 0.39 to 0.26 mg·g⁻¹, Mg²⁺ from 0.36 to 0.27 mg·g⁻¹, Cl⁻ from 1.18 to 0.80 mg·g⁻¹, SO₄²⁻ from 1.95 to 1.33 mg·g⁻¹ and HCO₃⁻ from 0.42 to 0.21 mg·g⁻¹ under increasing biochar rates. Moreover, the use of biochar interlayers significantly improved the physiological traits of sunflowers, including their photosynthesis rates, stomatal conductance, and transpiration efficiency, thereby boosting biomass and achene yield. These results highlight the potential of biochar interlayers as a sustainable strategy for soil desalination, water conservation, and enhanced crop productivity. This approach is especially promising for managing salt-affected soils in regions like California, where soil salinization represents a considerable threat to agricultural sustainability. Full article

Addressing aquatic phosphate pollution requires advanced materials that combine high selectivity with recyclability. Here, we present a hierarchically structured composite integrating Mg-Fe layered double hydroxides (LDHs) with magnetic biochar derived from mulberry branches—an abundant agricultural byproduct. Through hydrothermal synthesis, the composite achieves a unique architecture combining Fe₃O₄-enabled magnetic recovery (2.63 emu·g⁻¹ saturation) with LDHs’ anion exchange capacity and biochar’s porous network. Systematic characterization reveals phosphate capture mechanisms dominated by hydrogen bonding through deprotonated carboxyl groups, inner-sphere complexation with metal oxides, and interlayer anion exchange, enabling 99.22% phosphate removal at optimal conditions (pH 6, 25 °C). Crucially, the material demonstrates exceptional selectivity over competing Cl⁻ and NO₃⁻ ions while maintaining 87.83% efficiency after three regeneration cycles via alkaline treatment. Kinetic and thermodynamic analyses confirm chemisorption-driven uptake aligned with pseudo-second-order kinetics (R² > 0.9998) and Langmuir monolayer adsorption (7.72 mg·g⁻¹ capacity). This waste-derived magnetic composite establishes a sustainable paradigm for eutrophication control, merging selective phosphate sequestration with energy-efficient recovery for circular water treatment applications. Full article

Using rapeseed straw as a raw material and potassium bicarbonate (KHCO₃) and urea (CO(NH₂)₂) as modification reagents, the pyrolysis raw materials were mixed in a certain proportion, and the unmodified biochar GBC800, KHCO₃-modified biochar KGBC800, and (KHCO₃)/(CO(NH₂)₂) co-modified biochar N-KGBC800 were, respectively, prepared using the one-pot method at 800 °C. The physicochemical properties, such as surface morphology, pore characteristics, functional group distribution, and elemental composition of the three biochars, were characterized, and the adsorption performance and mechanism of the typical antibiotic tetracycline (TC) in water were studied. The results showed that the surface of GBC800 was smooth and dense, with no obvious pore structure, and both the specific surface area and total pore volume were small; the surface of KGBC800 showed an obvious coral-like three-dimensional carbon skeleton, the number of micropores and the specific surface area were significantly improved, and the degree of carbonization and aromatization was enhanced; N-KGBC800 had a coral-like three-dimensional carbon skeleton similar to KGBC800, and there were also many clustered carbon groups. The carbon layer changed significantly with interlayer gaps, presenting a multi-level porous structure. After N doping, the content of N increased, and new nitrogen-containing functional groups were formed. When the initial TC concentration was 100 mg/L, pH ≈ 3.4, the temperature was 25 °C, and the dosage of the three biochars was 0.15 g/L, the adsorption equilibrium was reached before 720 min. The adsorption capacities of GBC800, KGBC800, and N-KGBC800 for TC were 16.97 mg/g, 294.86 mg/g, and 604.71 mg/g, respectively. Fitting the kinetic model to the experimental data, the adsorption of TC by the three biochars was more in line with the pseudo-second-order adsorption kinetic model, and the adsorption isotherm was more in line with the Langmuir model. This adsorption process was a spontaneous endothermic reaction, mainly chemical adsorption, specifically involving multiple adsorption mechanisms such as pore filling, electrostatic attraction, hydrogen bonds, n−π interaction, Lewis acid–base interaction, π−π stacking, or cation −π interaction between the aromatic ring structure of the carbon itself and TC. A biochar-adsorption column was built to investigate the dynamic adsorption process of tetracycline using the three biochars against the background of laboratory pure water and salt water. The adsorption results show that the Thomas model and the Yoon–Nelson model both provide better predictions for dynamic adsorption processes. The modified biochars KGBC800 and N-KGBC800 can be used as preferred materials for the efficient adsorption of TC in water. Full article

The management of crop production in a sandy soil “culture” is difficult, mainly due to its low soil-water-holding capacity, organic matter and poor fertilizer efficiency. Options to increase soil water and nutrient retention for these soils include the addition of surface mulch covers, amendment with biochar and the use of layers of a mixture of charcoal and compost material. Our objective was to measure the distribution of water and nutrients for layers of control 1 (CK1), control 2 (CK2) and compost material of different thicknesses (0.02, 0.05 and 0.10 m) buried 0.01 m from the surface in a column (0.2 m radius, 0.5 m height) filled with sand. The experiment was conducted in a greenhouse located at the Agricultural Science Training Base of Ningxia University, China. There were three replicates per treatment and one soil column per replicate. The soil columns were watered with 2 L via a surface drip emitter and 45 days later, soil samples were obtained in 0.01 m increments across the diameter and depth of 0.4 m, with a total of 12 samples per column. In each sample, we measured soil water, pH, electrical conductivity, ammonium and nitrate nitrogen and available P and K. The results showed that the distribution of water content and nutrient contents were centered on the dripper and diffused to its surroundings. Notably, the horizontal diffusion distance was smaller than that of the vertical direction. In the vertical direction, compared with control 1, adding compost changed the spatial distribution of WC and nutrients and had a greater impact on available potassium (AK) than on inorganic nitrogen (IN) and available phosphorus (AP). Compared with control 1, the composting treatment decreased the content of water in the 0–10 cm surface soil, reduced the electrical conductivity (EC) and nitrate nitrogen (NO₃-N), C5 and C10 increased the available potassium. Moreover, composting treatments increased the electrical conductivity, available phosphorus, available potassium and nitrate nitrogen of the 10–30 cm substrate by 61–384%, 10–240%, 11–45% and 133–929%, respectively, when compared with control 1.The nutrients increased as the thickness of the compost interlayer increased. A principal component analysis (PCA) of the C5 and C10 treatments significantly distinguished them from control 1. A linear regression fitting analysis showed that the inorganic nitrogen, available potassium and total nutrients positively correlated with the water content and electrical conductivity of the sand. The 5 cm and 10 cm composting interlayers had a high water content and ability to conserve fertilizer for sand culture, but C10 caused an excessive accumulation of nutrients. Thus, it was concluded that a composting interlayer that was less than 5 cm reduced the base fertilizer input by 24–84%. All these results suggest that applying a composting interlayer of 5 cm could retain more suitable root zone water and fertilizer for the next crop season and provide technological support to reduce fertilizer inputs. Full article

To reveal the mechanisms of water conservation and soil salinity control in the biochar interlayer, the effects of biochar addition as an interlayer on soil water infiltration, evaporation, and salt transport were studied. Through the indoor soil-column simulation test, soil columns were set up by packing homogeneous soil (CK) and biochar spacers into columns at different burial depths of 10, 20, and 30 cm. The biochar interlayer decreased the infiltration capacity of the soil, with the average infiltration rate decreasing from 0.72 cm·h⁻¹ to the ranges of 0.39–0.48 cm·h⁻¹ in the CK soil column, and salt leaching efficiency was improved. The salt content in the bottom layer of soil in the CK column was reduced to within the range of 19.96–47.46% compared with that in the barrier soil column. The presence of the biochar interlayer improved the distribution of soil water and salt. The soil water content in the upper layer above the interlayer was around 7.79–13.68% higher than that in CK, whereas the average salt content was 6.44–60.40% lower than that in CK. The biochar interlayer inhibited soil water evaporation, and cumulative evaporation in this layer decreased by 32.34–42.10% compared with that in CK. The salt accumulation in the interlayer in the soil column decreased within the range of 16.36–51.36% compared with that in the CK soil column. The biochar interlayer could not only retain water for a long time, but also adsorb the salt leached from the upper layer, and thus, inhibit the reverse salt flux from the lower layer. The creation of the biochar interlayer of 30 cm could play a role in soil salinity control and water conservation, and can also provide a basis and reference for the improvement of saline-alkali farmland in arid and semi-arid areas. Full article

Herein, MnMgFe-layered double hydroxides/biochar (MnMgFe-LDHs/BC) composite was fabricated by immobilizing MnMgFe-LDHs on BC via the coprecipitation method, which was employed as an effective material for the detection and removal of Cd²⁺ from aqueous media. A lamellar structure of MnMgFe-LDHs with abundant surface-hydroxyl groups and various interlayer anions inside present a greater chance of trapping Cd²⁺. Meanwhile, the conductive BC with a porous structure provides numerous channels for the adsorption of Cd²⁺. Using the MnMgFe-LDHs/BC-based sensor, Cd²⁺ can be detected with a low limit of detection down to 0.03 ng/L. The feasibility of detecting Cd²⁺ in paddy water was also carried out, with satisfactory recoveries ranging from 97.3 to 102.3%. In addition, the MnMgFe-LDHs/BC material as an adsorbent was applied to remove Cd²⁺ from water with adsorption capacity of 118 mg/g, and the removal efficiency can reach 91%. These results suggest that the as-prepared MnMgFe-LDHs/BC can serve as a favorable platform for efficient determination and removal of Cd²⁺ in water. Full article