Search Results (1,228)

Metal–organic frameworks (MOFs) are unique microporous materials being explored for a wide range of applications. Their porosity and high surface areas can readily be exploited for guest–host interactions, separations, and photochemical catalysis, but many suffer from poor charge separation and fast electron–hole recombination. Introducing structural defects, such as missing linkers or metal nodes, can create unsaturated metal sites and alter band structure, conductivity, and light absorption, improving photocatalytic performance. UiO-66-NH₂ and MIL-125-NH₂ are water-stable, visible-light-absorbing MOFs well suited for photocatalytic degradation of organic dyes. In this work, the influence of defect engineering on photocatalytic properties of MOFs was investigated using formic and acetic acid modulators with UiO-66-NH₂ and variable temperature with MIL-125-NH₂ during synthesis. The resulting materials were characterized by XRD, FTIR and SEM/EDS. Defect states were tracked using N₂ adsorption/BET analysis and UV–Vis spectroscopy. Photocatalytic activity was evaluated by monitoring Rhodamine B (RhB) degradation in aqueous solution under simulated solar irradiation. It was found that increased temperature beyond 120 °C during synthesis promotes mesopore formation and decreases the bandgap in MIL-125-NH₂, resulting in a more photoactive material. Defective MIL-125-NH₂ synthesized at 150 °C showed the most defects and proved to be the best photocatalyst investigated in this study. Formic acid modulation in UiO-66-NH₂ generated smaller crystallites that slightly increased the bandgap; however, the surface area decreased proportionally with the amount of formic acid used. The decreased surface area and observed enhancement in photocatalytic degradation of RhB suggest that formic acid introduces defects into the UiO-66-NH₂ framework that enhance photocatalytic properties. UiO-66-NH₂ treated with acetic acid resulted in larger crystals, increased bandgaps, and increased surface areas, suggesting that acetic acid simply modulates growth rather than imparting defects to the framework. Full article

One of the strongest electromagnetic engineering approaches for enhancing antenna performance is the use of photonic crystal (PhC) substrates. This technique can be efficiently applied to antenna design and offers notable advantages, such as gain improvement, increased bandwidth, and frequency-dependent beam scanning. In this paper, a bow-tie dipole antenna has been developed for terahertz operation over the 0.39–1.3 THz band, presenting a novel structure capable of producing strong ultra-wideband (UWB) field enhancement within its feed gap. The feed gap between the two metallic arms has a slot width of 1.24 λ0 (λ0 is the wavelength in free space at a center range of 0.8 THz), which facilitates the generation of an enhanced electric field. The PhC substrate enables surface-wave control through dispersion engineering, thereby enhancing the radiation efficiency of the antenna. The proposed antenna exhibits a radiation efficiency of approximately 73–93% over the entire UWB frequency band. Furthermore, the PhC substrate antenna achieves a maximum gain of 21 dB, exceeding that of a homogeneous-substrate THz bow-tie antenna by at least 3.3 dB. The results indicate that the antenna achieves |S₁₁| < −10 dB impedance matching over the bandwidth of 105.9%, ranging from 0.4 to 1.3 THz. The proposed bow-tie dipole antenna integrated with a PhC substrate demonstrates a wide beam-scanning capability from −54° to +74° across the 0.39–1.16 THz band, while maintaining a compact footprint of 14.9 λ₀ × 22.4 λ₀. This combination of wide scanning, broad bandwidth, and ultra-low profile represents a notable advancement in the development of compact THz radiating structures. Full article

In this work, a comprehensive first-principles investigation of the electronic, magnetic, and optical properties of pristine and Fe-, Co-, and Ni-doped MoS₂ monolayers is presented within the framework of density functional theory. Substitutional transition-metal doping at the Mo site is shown to induce spin-polarized impurity states within the pristine band gap, leading to significant modifications of the electronic structure, including metallic, semimetallic, or half-metallic behavior depending on the dopant species. The calculated spin-resolved band structures and projected density of states reveal a strong hybridization between the dopant $3d$ orbitals and the Mo-$4d$/S-$3p$ states, giving rise to sizable magnetic moments and dopant-dependent exchange splitting. When spin–orbit coupling is included, the combined effect of exchange interactions and relativistic effects leads to an effective valley splitting at the K and $K^{\prime }$ points, whose magnitude and sign depend sensitively on the chemical nature of the dopant. Optical properties are analyzed within a linear-response framework, showing pronounced dopant-induced modifications of the optical spectra. While the pristine monolayer exhibits well-defined excitonic features, transition-metal substitution introduces low-energy optical transitions associated with impurity-related states. Consequently, the exciton binding energies estimated from the difference between the electronic and optical gaps are interpreted as effective measures of dopant-induced perturbations to optical transitions, rather than as quantitative many-body excitonic binding energies in the strict sense. These results provide microscopic insight into the interplay between magnetism, spin–orbit coupling, and optical response in doped MoS₂ monolayers, highlighting the potential of transition-metal substitution as a route to engineer spin- and valley-dependent phenomena in two-dimensional materials. Full article

Wildfires represent a significant global environmental challenge, necessitating advanced monitoring and assessment techniques. This study explores the integration of Sentinel-1 Synthetic Aperture Radar (SAR) and Sentinel-2 optical data within a Google Earth Engine (GEE) framework to enhance wildfire detection, burned area estimation, and severity assessment. By leveraging SAR’s capability to penetrate atmospheric obstructions and optical data’s spectral sensitivity to vegetation changes, the proposed methodology addresses limitations of single-sensor approaches. The results demonstrate strong correlations between SAR-based indices, such as the Radar Vegetation Index (RVI) and Dual-Polarized SAR Vegetation Index (DPSVI), and traditional optical indices, including the Normalized Burn Ratio (NBR) and differenced NBR (ΔNBR). Despite challenges related to terrain influence, sensor resolution differences, and computational demands, the integration of multi-sensor data in a cloud-based environment offers a scalable and efficient solution for wildfire monitoring. During the peak of the fire events, significant atmospheric obstruction was technically verified using Sentinel-2 metadata and the QA60 cloud mask band, which confirmed persistent cloud cover and thick smoke plumes over the study areas. This interference limited the reliability of purely optical monitoring, further justifying the integration of SAR data. Future research should focus on refining data fusion techniques, incorporating additional datasets such as thermal infrared imagery and meteorological variables, and enhancing automation through artificial intelligence (AI). This study underscores the potential of remote sensing advancements in improving fire management strategies and global wildfire mitigation efforts. Full article

Gearbox housing stiffness strongly influences radiated noise in electric drivetrains, particularly in the absence of engine masking. While high-fidelity vibro-acoustic simulations provide detailed insight, they are computationally demanding for early-stage design screening. This study investigates whether extremely compact spectral descriptors can encode stiffness-related information. The descriptors consist of five 1 kHz band-averaged sound pressure levels between 1 and 6 kHz. These band-averaged quantities are treated as compact spectral descriptors representing the acoustic response of each gearbox housing configuration. The analysis is based on a simulation-derived dataset of twelve spectra representing three ribbing configurations of a single gearbox housing geometry. A Random Forest classifier evaluated using leave-one-out cross-validation (LOOCV) achieved 0.75 accuracy. Confusion matrix analysis indicates clear separation of the flexible concept. Intermediate and rigid configurations show partial spectral overlap. Permutation testing suggests that the observed classification performance exceeds random chance, although uncertainty remains substantial due to the small dataset size. Feature-importance analysis identifies the 2–4 kHz region as the most stiffness-sensitive frequency range, supporting physical interpretations of mid-frequency structural–acoustic coupling. This exploratory study highlights both the potential and the statistical limits of minimal frequency-band descriptors for rapid NVH stiffness screening under small-sample conditions. Full article

Suspended sediment concentration (SSC) strongly influences estuarine erosion–deposition processes, navigation safety, and coastal engineering stability. However, conventional remote sensing techniques are limited to surface SSC and cannot characterize vertical sediment structures. In this study, Landsat 8 OLI imagery was combined with in situ SSC profiles from six stations in the Guan River Estuary–Haizhou Bay system to retrieve full-depth sediment distributions. A band-combination inversion model using (B3 + B2)/B1 achieved the highest accuracy (R² = 0.679), and an improved vertical distribution model was developed by incorporating turbulent shear (G) into the Rouse framework. Results indicate that surface SSC ranged from 0.15 to 0.86 kg/m³, while middle- and bottom-layer SSC reached up to 1.20 kg/m³ and 1.77 kg/m³, respectively, exhibiting a consistent east–high and west–low spatial pattern. Settling velocity (SSV) varied from 3 × 10⁻⁶ to 1.49 × 10⁻² m/s and showed a positive correlation with SSC at low concentrations and a negative correlation at high concentrations due to flocculation effects. This integrated framework provides a rapid, low-cost method for full-water-column sediment assessment in estuaries and coastal zones, supporting engineering design, navigation maintenance, and sediment management. A better understanding of sediment transport processes in Haizhou Bay is important for maintaining shoreline stability and ecological balance in this semi-enclosed coastal system. The findings of this study provide a scientific basis for sediment management and environmental regulation, which can contribute to the long-term sustainable development of coastal environments in the Yellow Sea region. Full article

Aiming at the problem that insulation fault location in multi-branch cable networks of train DC medium-voltage power supply systems is disturbed by impedance mismatch at the injection end, this paper proposes an impedance matching method based on a resistance–capacitance composite coupling network to suppress false reflections and improve location accuracy. Firstly, the mechanism of multiple false reflections caused by injection-end mismatch is theoretically analyzed, and the expression of reflected waves and their influence on waveform superposition are derived. On this basis, an RC coupling network is designed to achieve effective matching between the measurement end and the cable characteristic impedance (about 97 Ω) within the 8–12 MHz frequency band, suppressing the amplitude of false reflections to less than 2% of the incident wave. Verification through MATLAB R2022b/ANSYS Q3D 2024R2 co-simulation and a 1:8 scaled experimental platform shows that the proposed coupling network reduces the absolute fault location error in a multi-branch network from 6.936 m to 0.188 m, decreases waveform distortion by about 40.8% and lowers the equivalent noise enhancement factor by about 55.2%. This study provides a reliable front-end matching solution for accurate fault location in complex cable networks, with clear value for engineering applications. Full article

Carbonate reservoirs in the Shunbei area develop pronounced fracture networks after acidized hydraulic fracturing and thus have the potential to be repurposed as underground gas storage (UGS) after hydrocarbon depletion. Characterizing their mechanical behavior is essential for safe UGS operation; however, deep to ultra-deep natural cores are difficult to obtain, and conventional macroscopic tests often cannot provide parameters that meet engineering requirements. To address this issue, nanoindentation combined with QEMSCAN (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) was employed to quantify microscale mineral distributions and the mechanical properties of the major constituents. The investigated rock is calcite-dominated (89.62%), with minor quartz (9.89%) and trace feldspar-group minerals (1.89%). Minerals are randomly embedded, and soft–hard phase boundaries are widely distributed. A finite–discrete element method (FDEM) model was then constructed and calibrated in ABAQUS. The discrepancies in uniaxial compressive strength and elastic modulus relative to laboratory results were 6.51% and 9.91%, respectively, indicating good agreement in both mechanical response and failure mode. Parametric analyses using three additional models with different mineral proportions show that damage preferentially initiates at mineral phase boundaries and stress concentration zones induced by end constraints. Microcracks then propagate and coalesce into a dominant compressive–shear band, and final failure is mainly governed by slip along the shear band with localized tensile cracking. With increasing quartz and feldspar contents, enhanced heterogeneity and a higher density of phase boundaries lead to a higher density of crack nucleation sites and increased crack branching, and the failure pattern transitions from a single shear-band–controlled mode to a more network-like fracture system. Moreover, macroscopic strength is not determined solely by the intrinsic strength of individual minerals; heterogeneity and phase-boundary characteristics strongly govern microcrack behavior, such that higher hard-phase contents may result in a lower peak strength. Full article

High-resolution long-wave infrared imaging is critical for lunar mineralogy. However, it must balance a large FOV, a small F-number, chromatic aberration correction, optical efficiency, and system compactness. We introduce a push-broom multispectral imager employing a collaborative integrated filter array and an off-axis two-mirror Gregorian telescope. The system, utilizing an uncooled Vanadium Oxide detector, has an F-number of 1.0, an IFOV of 0.04943 mrad, and a 2.90° × 2.83° FOV that covers eight bands ranging between 7.38 and 14.3 μm. Optical simulation confirms that the modulation transfer function exceeds 0.25 at the Nyquist frequency of 42 lp/mm, with a maximum RMS spot radius of less than 12 μm. The system has remarkable versatility within an operating temperature range of 0 °C to 40 °C. Thermal background radiation analysis, stray light analysis, and detection sensitivity were conducted, which indicated that the system has good compliance with indicators and engineering feasibility. This high-throughput optical design meets the rigorous criteria for lunar remote sensing and provides a reliable device for site evaluation in future manned lunar missions. Full article

The 100 GHz-class ultrafast photonic integrated circuit (PIC) positions itself as a promising technology in the post-Moore era, when the bandwidth limit of metallic interconnections constrains current electronic integrated circuits. Nevertheless, the lack of an effective on-chip, CMOS-compatible laser source challenges the ongoing development of PIC. Germanium straintronics facilitate bandgap transformation from indirect to direct, thereby enabling effective band-to-band radiative recombination. Some parameters, such as nanowire diameters or crystalline orientation and strain direction, have a profound effect on the bandgap transformation of Ge nanowires. In this review, we will discuss changes in the fundamental physical properties of Ge nanowires under strain, including mechanical, electronic, optical, and thermal properties. Subsequently, we summarize common methods for strain engineering, as well as novel approaches that have emerged in recent years. Some notable application cases reported in the last few decades will be discussed in detail. This review may fill knowledge gaps and provide a solid background for forthcoming investigations of on-chip strained Ge lasers. Full article

Zinc titanate (ZnTiO₃) is a chemically stable and non-toxic oxide perovskite whose photovoltaic potential remains largely unexplored due to its wide indirect bandgap. This study evaluates whether oxygen-vacancy (F-center) engineering can tailor its electronic structure and improve its suitability as a photovoltaic absorber. Density Functional Theory (DFT) calculations using VASP (PAW − GGA/PBE + U) were performed to evaluate structural stability, electronic properties, and electron affinity, while optical absorption was modeled through a combined Tauc–Gaussian approach. Device performance was assessed via SCAPS-1D simulations in an FTO/ZnO/ZnTiO₃/Spiro-OMeTAD architecture. Oxygen vacancies induce bandgap narrowing from ~2.96 eV to ~1.47 eV and generate Ti-3d-dominated donor-like and deep intragap states. The calculated electron affinity is ~3.77 eV. Simulated single-layer devices reach Voc ≈ 1.11 V, Jsc ≈ 8.27 mA·cm⁻², FF ≈ 83%, and a maximum efficiency of ~7.65%, primarily limited by moderate absorption strength and defect-assisted recombination. Multilayer configurations indicate that geometric optimization can significantly enhance projected efficiency, approaching 19.25% under idealized conditions. Although vacancy engineering extends visible-light absorption, the intrinsic indirect band-gap character constrains the ultimate photovoltaic performance of ZnTiO₃. Full article

High-Al-content AlGaN microrods represent an effective platform for engineering deep-ultraviolet (DUV) emission. Here, we fabricated AlGaN microrods with varying diameters (2, 3, and 4 μm) via a top-down approach involving inductively coupled plasma dry etching followed by a KOH wet chemical modification. Their crystallographic facets and size-dependent optical properties were systematically investigated using scanning electron microscopy (SEM), cathodoluminescence (CL) spectroscopy, and CL mapping. We found that the KOH treatment selectively forms a-plane-dominated sidewalls on the high-Al-content portion of the microrods, whereas the etch pit bottoms stabilize as m-plane facets. Notably, the CL spectra show that the band-edge emission intensity of the 2 μm microrods is enhanced by a factor of 3.76 compared to the 4 μm structures. CL mapping further unveils the competitive dynamics between radiative recombination within the quantum wells and non-radiative recombination at surface states. These findings pinpoint 2 μm as the optimal diameter among the investigated range for maximizing spontaneous emission from these high-Al-content AlGaN microrods. Full article

To facilitate the next generation of renewable energy devices, it is important to engineer oxygen reduction reaction (ORR) catalysts that balance efficiency and production costs. This work examines oxygen adsorption on the WC (0001) surface as a function of electrode potential, utilizing DFT simulations with an implicit solvent environment. The results demonstrate that electrode potential significantly influences oxygen adsorption energy and electronic structure. Among the adsorption sites examined, the top site exhibits the highest stability across the entire potential range. The observed reduction in adsorption energy at lower potentials is attributed to the d-band center moving further from the Fermi energy, which weakens C–O orbital interactions, as revealed by DOS and COHP analyses. Our results demonstrate the crucial role of electrochemical conditions in modulating catalytic behavior and provide valuable insights for optimizing tungsten carbide (WC)-based electrocatalysts for ORR applications. Full article

The concurrent challenges of environmental pollution and energy scarcity necessitate advanced sustainable technologies. Photocatalytic fuel cells (PFCs) offer a promising route by coupling pollutant degradation with energy recovery. However, the synergistic interplay between anode intrinsic properties and macroscopic polarization effects remains inadequately understood. Herein, a BiOBr-doped TiO₂ nanotube array photoanode with engineered oxygen vacancies was developed to construct a synergistically enhanced PFC system. XPS, EPR, and DFT analyses confirm the formation of oxygen vacancies and favorable band bending, inducing an internal electric field that markedly promotes charge separation and interfacial reaction kinetics. As a result, the charge separation efficiency is enhanced by approximately fourfold relative to pristine TiO₂ nanotube arrays. Under the combined action of the internal electric field and self-bias-induced polarization field, photogenerated electrons and holes undergo directional transport and effective utilization. The optimized PFC achieves 78% sulfamethoxazole degradation within 180 min, representing a 1.38-fold improvement. Degradation pathways and toxicity evolution were further elucidated using LC–MS and Fukui function analysis, highlighting the critical role of electric field-driven charge regulation in high-performance PFCs. Full article

α-Fe_2−4xZ_3xO₃ (Z = Ce, Ru) nanoparticles were synthesized via a conventional solid-state reaction route. X-Ray diffraction analysis confirmed that all compositions crystallize in the single-phase hexagonal hematite (α-Fe₂O₃) structure, with no detectable secondary phases. Cerium substitution resulted in a pronounced reduction in crystallite size accompanied by a progressive narrowing of the optical band gap, which decreased to approximately 1.73 eV at higher Ce contents. The optical properties were further investigated through absorption coefficient, optical transmittance, and complex refractive index analyses, revealing that cerium-doped hematite exhibits enhanced light-harvesting capability, highlighting its strong potential for optoelectronic and solar-energy conversion applications. Magnetic hysteresis measurements on α-Fe_2−4xRu_3xO₃ samples showed a systematic increase in both coercive field (H_c) and remanent magnetization (M_r) with increasing Ru concentration. This magnetic hardening behavior is attributed to strengthened magnetocrystalline and shape anisotropy induced by Ru incorporation into the hematite lattice. Mössbauer spectroscopy confirmed the presence of Fe³⁺ and Ru⁴⁺ species, providing valuable insight into the oxidation states and local magnetic environments within the corundum-type structure. Full article