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Keywords = anti-weathering materials

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34 pages, 99537 KB  
Article
Microchemical Analysis of Rammed Earth Residential Walls Surface in Xiaochikan Village, Guangdong
by Liang Zheng, Qingnian Deng, Jingwei Liang, Zekai Guo, Yufei Zhu, Wei Liu and Yile Chen
Coatings 2025, 15(11), 1351; https://doi.org/10.3390/coatings15111351 - 19 Nov 2025
Viewed by 75
Abstract
Xiaochikan Village, located in Guangdong Province in South China, is one of the few remaining traditional rammed earth dwellings of the Cantonese ethnic group in the Lingnan region. However, the influence of Zhuhai’s subtropical maritime monsoon climate has led to continuous physical and [...] Read more.
Xiaochikan Village, located in Guangdong Province in South China, is one of the few remaining traditional rammed earth dwellings of the Cantonese ethnic group in the Lingnan region. However, the influence of Zhuhai’s subtropical maritime monsoon climate has led to continuous physical and chemical erosion of the rammed earth walls. For example, cracking occurs due to high temperatures and heavy rain, accelerated weathering occurs due to salt spray deposition, and biological erosion occurs due to high humidity and high temperatures. Therefore, two experimental analysis techniques, X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS), were used to explore the structural anti-erosion mechanism of the ancient, rammed earth buildings in Xiaochikan Village. The results show that (1) the morphological characteristics of the east and west walls of the rammed earth dwellings in Xiaochikan Village are more similar. The particles on the east wall are regular spherical or polygonal, small, and evenly distributed, while the particles on the west wall are mainly spherical and elliptical, with consistent size and less agglomeration. The surfaces of the particles on both walls are relatively smooth and flat. (2) The core element bases of the four wall samples are consistent, with C, Si, Al, Ca, and Fe as the core, accounting for more than 93%, reflecting the base characteristics of the local alluvial soil “silicate skeleton–carbonate cementation–organic matter residue” and reflecting the “local material” attribute of rammed earth. Except for the south wall sample, the Cl content of the remaining samples exceeds 1%. In the thermal map, Cl shows “pore/interstitial enrichment”, which confirms that the salinization process of marine aerosols with rainwater infiltration and evaporation residue is a common influence of marine climate. (3) The rammed earth walls in Xiaochikan Village consist of three main minerals: Quartz (SiO2, including alpha-type SiO2), Calcite (CaCO3, including synthetic calcite), and Gibbsite (Al(OH)3). Full article
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15 pages, 2876 KB  
Article
Standard Procedures Proposal of Laboratory Experimental Tests Assessment for Water Permeability of Anti-Rain Agricultural Nets
by Audrey Maria Noemi Martellotta, Sergio Castellano, Ileana Blanco, Greta Mastronardi, Pietro Picuno, Roberto Puglisi and Giacomo Scarascia Mugnozza
Horticulturae 2025, 11(10), 1253; https://doi.org/10.3390/horticulturae11101253 - 17 Oct 2025
Viewed by 372
Abstract
Climate change threatens the agricultural field by affecting production yields and crop quality. Yield protection is an increasingly pressing priority to preserve the ability of agriculture to meet food demand with more sustainable production of appropriate quality and quantity and with less demand [...] Read more.
Climate change threatens the agricultural field by affecting production yields and crop quality. Yield protection is an increasingly pressing priority to preserve the ability of agriculture to meet food demand with more sustainable production of appropriate quality and quantity and with less demand for plant protection products. For this reason, nowadays the use of agricultural nets is becoming increasingly widespread to counteract possible risks from abiotic stresses. Among all agricultural nets, the anti-rain ones have the predominant purpose of protecting crops from damage caused by severe weather events. The present study aims to verify whether anti-rain nets could be used as greenhouse covering material, starting from the evaluation of the rainwater permeability index Φrw. For this purpose, a laboratory rain simulator was designed and several tests were performed on the chosen anti-rain net, varying its inclination and the duration and intensity of the simulated rainfall, returning different normalized permeability indices NPI, of which the standard deviation (SD) was calculated. The optimal rainfall duration of the artificial rain test was determined at the minimum value of the sum of the SDs, identified as about 25%, at a duration of 10 min. Subsequently, tests were carried out to define the Φrw index for a rainfall lasting 10 min, by varying the other parameters, returning the lowest Φrw index of approximately 45% at a 20° net inclination and with the weave perpendicular to the slope. The results highlight the possibility to use anti-rain nets for greenhouse covering, replacing or supplementing commonly used nets, facilitating oxygen exchange and maximizing light capture capacity, essential for vegetative–productive balance. A proposal for standardizing the procedures to test nets, based on experimental tests, has never been proposed in the scientific literature. Regarding fruit and vegetable crops, there are several issues to be evaluated; this study only considers rain protection, through nets can be used for different fruit and vegetable varieties. Full article
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18 pages, 273 KB  
Review
Incorporation of E-Waste Plastics into Asphalt: A Review of the Materials, Methods, and Impacts
by Sepehr Mohammadi, Dongzhao Jin, Zhongda Liu and Zhanping You
Encyclopedia 2025, 5(3), 112; https://doi.org/10.3390/encyclopedia5030112 - 1 Aug 2025
Cited by 1 | Viewed by 968
Abstract
This paper presents a comprehensive review of the environmentally friendly management and reutilization of electronic waste (e-waste) plastics in flexible pavement construction. The discussion begins with an overview of e-waste management challenges and outlines key recycling approaches for converting plastic waste into asphalt-compatible [...] Read more.
This paper presents a comprehensive review of the environmentally friendly management and reutilization of electronic waste (e-waste) plastics in flexible pavement construction. The discussion begins with an overview of e-waste management challenges and outlines key recycling approaches for converting plastic waste into asphalt-compatible materials. This review then discusses the types of e-waste plastics used for asphalt modification, their incorporation methods, and compatibility challenges. Physical and chemical treatment techniques, including the use of free radical initiators, are then explored for improving dispersion and performance. Additionally, in situations where advanced pretreatment methods are not applicable due to cost, safety, or technical constraints, the application of alternative approaches, such as the use of low-cost complementary additives, is discussed as a practical solution to enhance compatibility and performance. Finally, the influence of e-waste plastics on the conventional and rheological properties of asphalt binders, as well as the performance of asphalt mixtures, is also evaluated. Findings indicate that e-waste plastics, when combined with appropriate pretreatment methods and complementary additives, can enhance workability, cold-weather cracking resistance, high-temperature anti-rutting performance, and resistance against moisture-induced damage while also offering environmental and economic benefits. This review highlights the potential of e-waste plastics as sustainable asphalt modifiers and provides insights across the full utilization pathway, from recovery to in-field performance. Full article
(This article belongs to the Collection Sustainable Ground and Air Transportation)
19 pages, 4319 KB  
Article
Investigation of Corrosion Resistance of 60Si2MnA Spring Steel Coated with Zn-Al in Atmospheric Environments
by Yurong Wang, Hui Xiao, Baolong Liu, Shilong Chen, Xiaofei Jiao, Shuwei Song, Wenyue Zhang and Ying Jin
Materials 2025, 18(14), 3215; https://doi.org/10.3390/ma18143215 - 8 Jul 2025
Viewed by 577
Abstract
To investigate the corrosion resistance of 60Si2MnA spring steel coated with Zn-Al in a domestic atmospheric environment containing harmful salts, the corrosion environmental factors (temperature, humidity, deposited salts, and pH) were obtained through field research. The deliquescence and weathering behavior of harmful salts [...] Read more.
To investigate the corrosion resistance of 60Si2MnA spring steel coated with Zn-Al in a domestic atmospheric environment containing harmful salts, the corrosion environmental factors (temperature, humidity, deposited salts, and pH) were obtained through field research. The deliquescence and weathering behavior of harmful salts were studied using impedance methods to establish their characteristic curves. Additionally, a self-designed salt deposition test apparatus was employed to conduct accelerated atmospheric corrosion tests under constant salt deposition (10 g/m2) and controlled temperature and humidity conditions (20 °C/75% RH and 40 °C/75% RH) over different corrosion periods. The results show that noticeable red rust appeared on the samples after one month of corrosion. As the temperature increased, the consumption of the coating accelerated. XRD and Raman analyses reveal that the main corrosion products of the coating materials were ZnO, Zn(OH)2, and Zn5(CO3)2(OH)6, while the red rust primarily consisted of iron oxides and hydroxides. In the early stages of corrosion, the self-corrosion current density was relatively low due to the protective effects of the coating and the corrosion product layer, indicating good corrosion resistance. However, in the later stages, the integrity of the coating and the corrosion product layer deteriorated, leading to a significant increase in the self-corrosion current density and a decline in corrosion resistance. This study provides a data foundation for understanding the corrosion behavior of Zn-Al-coated spring steel in atmospheric environments and offers theoretical insights for developing more corrosion-resistant coatings and optimizing anti-corrosion measures. Full article
(This article belongs to the Section Metals and Alloys)
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28 pages, 5449 KB  
Review
The Evolution and Development Trends of LNG Loading and Unloading Arms
by Mingqin Liu, Jiachao Wang, Han Zhang, Yuming Zhang, Jingquan Zhu and Kun Zhu
Appl. Sci. 2025, 15(8), 4316; https://doi.org/10.3390/app15084316 - 14 Apr 2025
Cited by 1 | Viewed by 2623
Abstract
In recent years, the rapid growth in demand for liquefied natural gas (LNG) has brought significant challenges and opportunities to LNG storage and transportation technologies. As critical equipment for LNG loading operations, marine and land-based LNG loading and unloading arms play a vital [...] Read more.
In recent years, the rapid growth in demand for liquefied natural gas (LNG) has brought significant challenges and opportunities to LNG storage and transportation technologies. As critical equipment for LNG loading operations, marine and land-based LNG loading and unloading arms play a vital role in improving LNG storage and transportation efficiency and ensuring safety performance. By extensively collecting relevant domestic and international literature, technical standards, and engineering cases, systematically reviewing and analyzing existing achievements, and engaging with technical personnel from related enterprises, the current development status of marine and land-based LNG loading and unloading arms is introduced from multiple perspectives, including overall structure, sealing technology, safety protection devices, and intelligent and automated development. This paper highlights trajectory planning and image processing involved in the automatic docking technology. Marine loading/unloading arms need to operate in high-humidity, high-corrosion, and even extreme weather conditions. In the future, they should further enhance stability in marine high-corrosion environments and improve anti-overturning capability under extreme conditions by simplifying mechanical structures, developing new balancing systems, and using low-temperature-resistant alloy materials. Land-based loading and unloading arms focus on multi-vehicle parallel operations, improving operational efficiency through simplified mechanical structures, integrated intelligent positioning systems, and adaptive control algorithms. Full article
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32 pages, 2425 KB  
Review
Development, Challenges, and Applications of Concrete Coating Technology: Exploring Paths to Enhance Durability and Standardization
by Hongbin Zhao, Qingzhou Wang, Ruipeng Shang and Shengkai Li
Coatings 2025, 15(4), 409; https://doi.org/10.3390/coatings15040409 - 30 Mar 2025
Cited by 2 | Viewed by 3231
Abstract
Concrete coating technology is a key measure that enhances the durability of concrete structures. This paper systematically studies the performance, applicability, and impact of different types of anti-corrosion coatings on concrete durability, focusing on their resistance to chloride ion penetration, freeze–thaw cycles, carbonation, [...] Read more.
Concrete coating technology is a key measure that enhances the durability of concrete structures. This paper systematically studies the performance, applicability, and impact of different types of anti-corrosion coatings on concrete durability, focusing on their resistance to chloride ion penetration, freeze–thaw cycles, carbonation, and sulfate corrosion. The applicability of existing testing methods and standard systems is also evaluated. This study shows that surface-film-forming coatings can create a dense barrier, reducing chloride ion diffusion coefficients by more than 50%, making them suitable for humid and high-chloride environments. Pore-sealing coatings fill capillary pores, improving the concrete’s impermeability and making them ideal for highly corrosive environments. Penetrating hydrophobic coatings form a water-repellent layer, reducing water absorption by over 75%, which is particularly beneficial for coastal and underwater concrete structures. Additionally, composite coating technology is becoming a key approach to addressing multi-environment adaptability challenges. Experimental results have indicated that combining penetrating hydrophobic coatings with surface-film-forming coatings can enhance concrete’s resistance to chloride ion penetration while ensuring weather resistance and wear resistance. However, this study also reveals that there are several challenges in the standardization, engineering application, and long-term performance assessment of coating technology. The lack of globally unified testing standards leads to difficulties in comparing the results obtained from different test methods, affecting the practical application of these coatings in engineering. Moreover, construction quality control and long-term service performance monitoring remain weak points in their use in engineering applications. Some engineering case studies indicate that coating failures are often related to an insufficient coating thickness, improper interface treatment, or lack of maintenance. To further improve the effectiveness and long-term durability of coatings, future research should focus on the following aspects: (1) developing intelligent coating materials with self-healing, high-temperature resistance, and chemical corrosion resistance capabilities; (2) optimizing multilayer composite coating system designs to enhance the synergistic protective capabilities of different coatings; and (3) promoting the creation of global concrete coating testing standards and establishing adaptability testing methods for various environments. This study provides theoretical support for the optimization and standardization of concrete coating technology, contributing to the durability and long-term service safety of infrastructure. Full article
(This article belongs to the Special Issue Recent Progress in Reinforced Concrete and Building Materials)
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16 pages, 4901 KB  
Article
Thermal Characterization of Ceramic Composites for Optimized Surface Dielectric Barrier Discharge Plasma Actuators
by Kateryna O. Shvydyuk, Frederico F. Rodrigues, João Nunes-Pereira, José C. Páscoa and Abílio P. Silva
Actuators 2025, 14(3), 127; https://doi.org/10.3390/act14030127 - 6 Mar 2025
Cited by 3 | Viewed by 1172
Abstract
Ice accretion is a significant drawback in an aircraft’s and wind turbine’s aerodynamic performance in cold climate weather. Plasma actuators are an attractive technology for ice removal; however, dielectric barriers are typically restricted to borosilicate glass and various polymers, such as Teflon® [...] Read more.
Ice accretion is a significant drawback in an aircraft’s and wind turbine’s aerodynamic performance in cold climate weather. Plasma actuators are an attractive technology for ice removal; however, dielectric barriers are typically restricted to borosilicate glass and various polymers, such as Teflon® and Kapton®. Nevertheless, new materials capable of withstanding prolonged exposure to charged particles are needed. In this work, Y2O3-ZrO2, MgO-CaZrO3, and MgO-Al2O3 ceramic samples were manufactured and their thermal properties as DBD plasma actuators were measured. As foreseen, the results showed that the higher the power consumed, the higher the temperature surface of the plasma actuators. The Y2O3-ZrO2 dielectric showed the highest power consumption and ceiling temperatures (20.7 W and 155 °C at 10 kVpp, respectively), followed by MgO-CaZrO3 (9.6 W and 62 °C at 10 kVpp, respectively) and by MgO-Al2O3 (5.6 W and 47 °C at 10 kVpp, respectively). It was concluded that MgO-Al2O3 presented stable magnitudes across the entire dielectric area, whilst Y2O3-ZrO2 showed a more concentrated temperature field. Therefore, considering that about 65 to 95% of the total power supplied to the DBD plasma actuator is dissipated as heat, it becomes natural to propose ceramic-based DBD plasma actuators as de-/anti-icing means for aero-dynamic structures. Full article
(This article belongs to the Section Aerospace Actuators)
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13 pages, 11023 KB  
Article
Antibacterial Activity of Superhydrophobic-SiO2 Coatings to Inhibit the Growth of Escherichia coli and Staphylococcus aureus
by Betania Sánchez-Santamaria, Delfino Cornejo-Monroy, Imelda Olivas-Armendáriz, José Saúl Arias-Cerón, Alfredo Villanueva-Montellano, Elsa Ordoñez-Casanova, José Omar Dávalos-Ramírez, Erwin Adán Martínez-Gómez and Jesús Manuel Jaquez-Muñoz
Coatings 2024, 14(9), 1211; https://doi.org/10.3390/coatings14091211 - 20 Sep 2024
Cited by 7 | Viewed by 3085
Abstract
The emergence of superhydrophobic antibacterial materials represents a promising approach to maintaining surface cleanliness and hygiene by effectively preventing bacterial adhesion. This research outlines the synthesis of a superhydrophobic coating with anti-adhesion and bacteriostatic properties, utilizing silica nanoparticles (SiO2 NPs) modified with [...] Read more.
The emergence of superhydrophobic antibacterial materials represents a promising approach to maintaining surface cleanliness and hygiene by effectively preventing bacterial adhesion. This research outlines the synthesis of a superhydrophobic coating with anti-adhesion and bacteriostatic properties, utilizing silica nanoparticles (SiO2 NPs) modified with 1H,1H,2H,2H-Perfluorodecyltriethoxysilane (PFDTES). Transmission electron microscopy (TEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR) spectroscopy were conducted to analyze the coating’s morphology and surface characteristics. The coating was applied to glass substrates using the spray coating method, and the number of layers was varied to evaluate its antibacterial and bacteriostatic properties. These properties were measured using turbidimetry and inhibition halo techniques. Additionally, the durability of the coatings was assessed by exposing them to outdoor conditions for 35 days. This study aimed to evaluate the antibacterial and bacteriostatic capacities of the superhydrophobic coating, along with its resistance to outdoor weathering. The results indicate that a superhydrophobic coating with a contact angle ≥ 150° and a sliding angle ≤ 10° was successfully synthesized using SiO2 NPs smaller than 10 nm, modified with PFDTES. The coating demonstrated an ability to inhibit bacterial growth by preventing the adhesion of bacteria such as Escherichia coli and Staphylococcus aureus. Furthermore, the number of coating layers significantly influenced its bacteriostatic efficacy. The coating also exhibited strong durability under outdoor conditions. These findings highlight the potential application of superhydrophobic coatings for the prevention of bacterial adhesion and growth in environments where such contamination poses risks. Full article
(This article belongs to the Special Issue Synthesis and Applications of Bioactive Coatings)
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14 pages, 8824 KB  
Review
Research Progress of Superhydrophobic Coatings in the Protection of Earthen Sites
by Yisi Liu, Qian Li, Ruiting Zhou and Renaguli Yusufu
Coatings 2024, 14(6), 710; https://doi.org/10.3390/coatings14060710 - 5 Jun 2024
Cited by 1 | Viewed by 2592
Abstract
As an important part of human cultural heritage, earthen sites are subject to damage caused by a variety of environmental factors, such as cracking, weathering, and flooding. Due to the low mechanical strength of earthen site materials, especially in humid environments, they are [...] Read more.
As an important part of human cultural heritage, earthen sites are subject to damage caused by a variety of environmental factors, such as cracking, weathering, and flooding. Due to the low mechanical strength of earthen site materials, especially in humid environments, they are susceptible to hazards like moisture penetration, freeze–thaw cycles, and biological invasion. Superhydrophobic coatings show promising potential in the protection of earthen sites, with key properties that include waterproof performance, breathability, robustness, and transparency. By exploring various material systems and preparation methods, the current state of research on the protection of building materials with superhydrophobic materials has been demonstrated, highlighting advantages in the corrosion resistance, self-cleaning, frost prevention, anti-scaling, and other aspects. At the same time, it also points out the challenges faced in the practical application of earthen site protection and the prospects for future research. These include enhancing the bonding strength between the coating and soil particles, improving durability and breathability, and developing large-scale, low-cost, and efficient coating construction techniques. Full article
(This article belongs to the Special Issue New Trends in Conservation and Restoration of Cultural Heritage)
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18 pages, 10017 KB  
Article
Effect of Modifiers on the Disintegration Characteristics of Red Clay
by Baochen Liu, Haofeng Zhou, Xiaobo Wang, Guan Lian and Bai Yang
Sustainability 2024, 16(11), 4551; https://doi.org/10.3390/su16114551 - 27 May 2024
Cited by 5 | Viewed by 1772
Abstract
Due to the high degree of weathering, the red clay slope has low anti-disintegration performance, and the clay easily becomes wet and disintegrates after soaking in water. It causes geological problems such as slope collapse caused by soil softening. To study the disintegration [...] Read more.
Due to the high degree of weathering, the red clay slope has low anti-disintegration performance, and the clay easily becomes wet and disintegrates after soaking in water. It causes geological problems such as slope collapse caused by soil softening. To study the disintegration characteristics of modified red clay, the disintegration test of red clay modified by using lignin fiber, clay particles and lime was carried out, analyzing the disintegration characteristics of improved red clay from physical and chemical perspectives and analyzing the improvement mechanism of three modifiers with the scanning electron microscopy test. The analysis results show that the water-holding capacity and disintegration resistance of soil mixed with lignin fiber decrease; the disintegration time of reshaped red clay increases with the increase in clay content; and the average disintegration rate of the soil decreases with the increase in clay content. With the increase in lime content, the soil cement increases. The integrity of the soil is enhanced, and its anti-disintegration ability is improved; the saturated moisture content of reshaped red clay increases with the increase in lignin fiber and clay content, while the saturated moisture content of soil decreases with the increase in lime content. The damage analysis shows that the larger the damage factor of soil, the worse its anti-disintegration ability, and the easier the soil disintegrates. The purpose of this paper is to explore the essence of the soil disintegration phenomenon, and on this basis, using high-quality improved materials, to improve the soil, which easily disintegrates. This move aims to significantly enhance the anti-disintegration ability of the soil, thereby improving its resistance to softening and disintegration, thereby effectively improving and maintaining the ecological environment. At the same time, the improved soil will help to improve the utilization rate of the slope and foundation soil, thereby reducing the economic cost of maintenance engineering. Against the current background of sustainable economic, social, and ecological development, it is of great strategic significance to ensure the sustainable availability of land resources in specific areas and maintain their productivity and ecological stability for a long time. The research into this subject not only helps to deepen the understanding of soil disintegration, but also provides strong technical support for the rational utilization of land resources and the protection of the ecological environment. Full article
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13 pages, 3748 KB  
Article
An Experimental Investigation of the Material Properties of the A356 Aluminum Alloy Power Fittings in the Vacuum Die-Casting Process
by Jianli Zhao, Yilin Wang, Xiaowei Wang and Yisheng Zhang
Materials 2024, 17(6), 1242; https://doi.org/10.3390/ma17061242 - 8 Mar 2024
Cited by 2 | Viewed by 2402
Abstract
To enhance the performance of ultra-high voltage power fittings in severe weather conditions without altering their current structure, the high-strength and toughness aluminum alloys were rationally selected to study the optimization of the die-casting process. This approach aims to improve the overall longevity [...] Read more.
To enhance the performance of ultra-high voltage power fittings in severe weather conditions without altering their current structure, the high-strength and toughness aluminum alloys were rationally selected to study the optimization of the die-casting process. This approach aims to improve the overall longevity and function of the power fittings in extreme climates. First of all, the propose of this study is to use the material’s strength–toughness product (STP) concept to evaluate the material stability of the power fitting impact resistance and fatigue toughness in order to determine the appropriate material selection. Secondly, the location of the mold’s sprue and gate was optimized through finite element simulation to prevent gas volume and flow defects during the casting process. This improves the material’s toughness and anti-fatigue failure characteristics of the product. Then, vacuum equipment and a vacuum valve auxiliary system were added based on the existing die-casting machine, and the mold structure was optimized to enable the vacuum die-casting process. Finally, a water-based boron nitride environmentally friendly mold release agent was used to solve demolding difficulties with an A356 aluminum alloy and improve mold lubrication and surface quality. The production of quad-bundled spacers using A356 and vacuum die casting has resulted in parts with a tensile strength of at least 250 MPa and an elongation of no less than 7%. This improvement has laid a foundation for enhancing the operational reliability of existing overhead transmission line fittings. Full article
(This article belongs to the Section Metals and Alloys)
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19 pages, 5737 KB  
Article
Differentiation Study of the Damage Characteristics of Rock Cultural Heritage Sites Due to the Sulfate Weathering Process
by Jie Hong, Ye Zhu, Yue Zhang, Jizhong Huang and Ningbo Peng
Appl. Sci. 2023, 13(23), 12831; https://doi.org/10.3390/app132312831 - 29 Nov 2023
Cited by 8 | Viewed by 2187
Abstract
Salt crystallization represents one of the primary forms of weathering encountered in rock cultural heritage sites, with sulfate weathering having particularly notable destructive effects. This study focuses on sandstone and limestone, using them as test materials to conduct simulation experiments on sulfate weathering [...] Read more.
Salt crystallization represents one of the primary forms of weathering encountered in rock cultural heritage sites, with sulfate weathering having particularly notable destructive effects. This study focuses on sandstone and limestone, using them as test materials to conduct simulation experiments on sulfate weathering under specific environmental conditions. The experimental process involved documenting the surface morphology of the rock samples and analyzing changes in indicators such as wave velocity, hardness, composition, and pore size distribution. The degree of damage to the two types of rock was evaluated using the entropy weight–TOPSIS method, and the sensitivity of different weathering indicators in assessing the weathering of the two rocks was also discussed. The results revealed that sandstone exhibited obvious surface damage under sulfate erosion, with dissolution holes and pits surrounding the rock samples, while limestone primarily suffered damage at its edges. There were notable differences in the rate of attenuation observed in the macro and micro indicators between the two rock types. The wave velocity of both types of rocks exhibits linear attenuation while the intensity undergoes exponential change. It is worth noting that sandstone hardness demonstrates a pattern of “fast–rapid–slow–stable” decline characteristics, whereas limestone follows an exponential trend with an initial fast decline followed by a slower decline. Additionally, sandstone exhibited significantly greater damage and weathering thickness compared to limestone, owing to the involvement of complex and diverse physical and chemical reactions. The pore damage factor and macro-level indicators of the rock samples could be fitted using exponential and linear functions, respectively, although the fitting curves differed distinctly. The sensitivity indicators reflecting the weathering state of sandstone and limestone under sulfate erosion varied, with mass loss applicable to sandstone and porosity to limestone. Overall, with our research findings, we aim to provide a theoretical foundation for the anti-salination and precision protection of rock cultural heritage sites. Full article
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18 pages, 4139 KB  
Article
Study on Anti-Weathering Protection of Excavated Ancient Stone Arch Bridge with Nano-Composites
by Jian Zhang, Qingwen Ma, Xiaowen Zheng, Kaidi Cheng and Ruizhe Lang
Coatings 2023, 13(11), 1898; https://doi.org/10.3390/coatings13111898 - 6 Nov 2023
Cited by 1 | Viewed by 1886
Abstract
After archaeological excavation, the underground ancient bridge has changed from a relatively stable underground environment to a modern environment with a large temperature difference between day and night, long sunshine, changeable climate, rain erosion and serious air pollution. In addition to the need [...] Read more.
After archaeological excavation, the underground ancient bridge has changed from a relatively stable underground environment to a modern environment with a large temperature difference between day and night, long sunshine, changeable climate, rain erosion and serious air pollution. In addition to the need to control the external environment, it is necessary to actively carry out research on anti-weathering materials for stone cultural relics. In this study, five common weathering materials were selected, and three of them were hybridized with nano-silica to obtain nano-composites. Through a series of property tests and anti-weathering ability tests, the comprehensive anti-weathering effect of brick samples coated with anti-weathering protective materials was evaluated. The results showed that the composite of nano-silica-methyltrimethoxysilane hydrolysate showed the best comprehensive anti-weathering ability, which provides a certain reference value for the protection of similar masonry cultural relics. Full article
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14 pages, 7915 KB  
Article
Morphology Control of Electrospun Brominated Butyl Rubber Microfibrous Membrane
by Tianxiao Zhu, Ruizhi Tian, Liang Wu, Dingyi Zhang, Leying Chen, Xianmei Zhang, Xiangyang Hao and Ping Hu
Polymers 2023, 15(19), 3909; https://doi.org/10.3390/polym15193909 - 27 Sep 2023
Cited by 1 | Viewed by 2001
Abstract
Brominated butyl rubber (BIIR) is a derivative of butyl rubber, with the advantage of high physical strength, good vibration damping performance, low permeability, aging resistance, weather resistance, etc. However, it is hard to avoid BIIR fiber sticking together due to serious swelling or [...] Read more.
Brominated butyl rubber (BIIR) is a derivative of butyl rubber, with the advantage of high physical strength, good vibration damping performance, low permeability, aging resistance, weather resistance, etc. However, it is hard to avoid BIIR fiber sticking together due to serious swelling or merging, resulting in few studies on BIIR electrospinning. In this work, brominated butyl rubber membrane (mat) with BIIR microfiber has been prepared by electrospinning. The spinnability of elastomer BIIR has been explored. The factors influencing the morphology of BIIR microfiber membranes have been studied, including solvent, electrospinning parameters, concentration, and the rheological property of electrospinning solution. The optimal parameters for electrospinning BIIR have been obtained. A BIIR membrane with the ideal microfiber morphology has been obtained, which can be peeled from aluminum foil on a collector easily without being broken. Anti-bacterial property, the electrical conductivity of these membranes, and the mechanical properties of these samples were studied. The optimized BIIR electrospinning solution is Bingham fluid. The results of these experiments show that a BIIR membrane can be used in the field of medical prevention, wearable electronics, electronic skin, and in other fields that require antibacterial functional polymer materials. Full article
(This article belongs to the Collection Electrospun Nanofibers)
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17 pages, 5801 KB  
Article
Construction of Multifunctional Hierarchical Biofilms for Highly Sensitive and Weather-Resistant Fire Warning
by Tongtong Ma, Qianqian Zhou, Chaozheng Liu, Liping Li, Chuigen Guo and Changtong Mei
Polymers 2023, 15(18), 3666; https://doi.org/10.3390/polym15183666 - 6 Sep 2023
Cited by 4 | Viewed by 1802
Abstract
Multifunctional biofilms with early fire-warning capabilities are highly necessary for various indoor and outdoor applications, but a rational design of intelligent fire alarm films with strong weather resistance remains a major challenge. Herein, a multiscale hierarchical biofilm based on lignocellulose nanofibrils (LCNFs), carbon [...] Read more.
Multifunctional biofilms with early fire-warning capabilities are highly necessary for various indoor and outdoor applications, but a rational design of intelligent fire alarm films with strong weather resistance remains a major challenge. Herein, a multiscale hierarchical biofilm based on lignocellulose nanofibrils (LCNFs), carbon nanotubes (CNTs) and TiO2 was developed through a vacuum-assisted alternate self-assembly and dipping method. Then, an early fire-warning system that changes from an insulating state to a conductive one was designed, relying on the rapid carbonization of LCNFs together with the unique electronic excitation characteristics of TiO2. Typically, the L-CNT-TiO2 film exhibited an ultrasensitive fire-response signal of ~0.30 s and a long-term warning time of ~1238 s when a fire disaster was about to occur, demonstrating a reliable fire-alarm performance and promising flame-resistance ability. More importantly, the L-CNT-TiO2 biofilm also possessed a water contact angle (WCA) of 166 ± 1° and an ultraviolet protection factor (UPF) as high as 2000, resulting in excellent superhydrophobicity, antifouling, self-cleaning as well as incredible anti-ultraviolet (UV) capabilities. This work offers an innovative strategy for developing advanced intelligent films for fire safety and prevention applications, which holds great promise for the field of building materials. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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