Search Results (10)

Magnesium (Mg) alloys are gaining widespread use in the automotive and construction industries for their potential to enhance performance and lower manufacturing costs, making them ideal for lightweight structural applications. However, despite these advantages, extruding Mg alloys remains technically challenging due to their inherently limited formability and the strong crystallographic textures that form during deformation. This study aimed to comprehensively characterize the ductile fracture behavior of ZM51M Mg alloy round bars under various stress states and to improve the reliability of ductile failure predictions through the application and calibration of multiple uncoupled damage criteria. Tensile and compressive tests were conducted on specimens of varying geometries (dogbone, notched R5, shear, uniaxial compression, and plane strain compression specimens) and dimensions, meticulously cut along the extrusion direction of the round bar. These tests encompassed a wide spectrum of stress–strain responses and fracture characteristics, including uniaxial tension, uniaxial compression, and shear-dominated states. An inverse analysis approach, involving iterative numerical simulation coupled with experimental data, was employed to precisely determine fracture strains from the test results. The plastic deformation behavior was accurately modeled using the combined Swift–Voce hardening law. Subsequently, three prominent uncoupled ductile fracture criteria—Rice–Tracey, DF2014, and DF2016—were calibrated against the experimental data. The DF2016 criterion demonstrated superior predictive accuracy, consistently yielding the most accurate fracture strain predictions and significantly outperforming the Rice–Tracey and DF2014 criteria across the tested stress states. The findings of this work provide significant insights for improving the assessment of formability and fracture prediction in Mg alloys. This research directly contributes to overcoming the challenges associated with their inherent formability limitations and complex deformation textures, thereby facilitating more reliable design and broader adoption of Mg alloys in advanced lightweight structural solutions. Full article

It is of great significance in the field of engineering to repair the surface defects of ZM6 cast magnesium alloy by an arc welding method. Compared with the traditional tungsten inert gas (TIG) welding repair technology, cold metal transfer (CMT) welding repair has the advantages of low heat input, small repair deformation, and high efficiency. It is of great research value to repair the surface defects of ZM6 cast magnesium alloy by CMT welding. In this paper, the effect of CMT welding repair parameters on defect repair forming is systematically studied, and a repair process window free of unfused defects is obtained. The effects of preheating temperature of base material, wire-feeding speed, welding speed, stick-out length of welding wire and shielding gas flow on the spread of magnesium alloy melt and weld formation were investigated by a surface surfacing method. During the welding process, a camera was used to capture images of the arc and droplet features. A pit defect with a depth of 11.5 mm was machined on the surface of the casting, and the effect of five different repair paths on the formation of the repair area was studied. In order to make the repair area have better fusion, reasonable repair parameters are as follows: The preheating temperature range is 310–450 °C, the wire-feeding speed range is 5–7 m/min, the welding speed range is 8–10 mm/s, the stick-out length of the welding wire is 12 mm, the shielding gas flow rate is 20 L/min, and the repair path adopts a continuous linear reciprocating welding path. This study has important significance for guiding the development of CMT repair technology of cast magnesium alloy. Full article

Hard ceramic coatings were successfully prepared on the surface of ZM5 magnesium alloy by micro-arc oxidation (MAO) technology in silicate and aluminate electrolytes, respectively. The optimization of hard ceramic coatings prepared in these electrolyte systems was investigated through an orthogonal experimental design. The microstructure, elemental composition, phase composition, and tribological properties of the coatings were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and tribological testing equipment. The results show that the growth of the hard ceramic coatings is significantly influenced by the different electrolyte systems. Coatings prepared from both systems have shown good wear resistance, with the aluminate electrolyte system being superior to the silicate system in performance. The optimized formulation for the silicate electrolyte solution has been determined to be sodium silicate at 8 g/L, sodium dihydrogen phosphate at 0.2 g/L, sodium tetraborate at 2 g/L, and potassium hydroxide at 1 g/L. The optimized formulation for the aluminate electrolyte solution consists of sodium aluminate at 5 g/L, sodium fluoride at 3 g/L, sodium citrate at 3 g/L, and sodium hydroxide at 0.5 g/L. Full article

Extensive research into magnesium (Mg) alloys highlights their possible applications in the field of biodegradable implants. As magnesium alloys are highly electronegative, it is imperative to tailor their degradation rate for clinical safety. Surface coatings have been widely used for the corrosion protection of Mg alloys, but the presence of spatial defects limits their effectiveness. An innovative and near-defect-free hydroxyapatite (HA)-TiO₂ nano-channeled (TNC) coating architecture has been developed on ZM21 Mg alloy in the present study by combining anodization and the sol-gel dip coating technique. The HA-TNC coating positively shifted the E_corr of ZM21 Mg alloy from −1.38 to −0.61 V. Accordingly, the corrosion current density (I_corr, 5.8 × 10⁻⁶ A/cm²) was suppressed by 53.4 times compared to uncoated ZM21 Mg alloy. The polarization resistance (R_p) and charge transfer resistance (R_ct) values are the highest among all other samples, indicating the superior shielding ability of the coating. During in vitro immersion for up to 28 days in simulated body fluid (SBF), the HA−TNC coating maintained the lowest degradation rate and hydrogen evolution rate (HER) of 1.10 ± 0.22 mg/cm²/day and 1.83 ± 0.41 mL/cm²/day, respectively. A compact and structurally stable 2D plate-like HA (Ca/P:1.55), mineralized on HA-TNC-coated ZM21, provides effective shielding against the penetration of aggressive ions with prolonged SBF immersion. The findings of the present study provide a rational design for the development of bioactive ceramic coatings on Mg-based bioimplants. Full article

Magnesium (Mg) alloy has attracted significant attention as a bioresorbable scaffold for use as a next-generation stent because of its mechanical properties and biocompatibility. However, Mg alloy quickly degrades in the physiological environment. In this study, we investigated whether applying a parylene C coating can improve the corrosion resistance of a Mg alloy stent, which is made of ‘Original ZM10’, free of aluminum and rare earth elements. The coating exhibited a smooth surface with no large cracks, even after balloon expansion of the stent, and improved the corrosion resistance of the stent in cell culture medium. In particular, the parylene C coating of a hydrofluoric acid-treated Mg alloy stent led to excellent corrosion resistance. In addition, the parylene C coating did not affect a polymer layer consisting of poly(ε-caprolactone) and poly(D,L-lactic acid) applied as an additional coating for the drug release to suppress restenosis. Parylene C is a promising surface coating for bioresorbable Mg alloy stents for clinical applications. Full article

An Al₈₆Ni₆Y_4.5Co₂La_1.5 amorphous coating was prepared on a ZM5 magnesium alloys substrate by using high-velocity air fuel (HVAF) spray. The coating contained a 75.8% amorphous phase (volume fraction) in addition to the crystallization phases of α-Al, Al₄NiY, and Al₉Ni₅Y₃. The microhardness reached 420 HV_0.05 for the coating. The coating could endure 500 h neutral salt spray tests without apparent corrosion. Moreover, the coating exhibited a much nobler corrosion potential and two orders of magnitude smaller corrosion current density compared to the substrate. These improvements can be attributed to the compact coating structure and the passive film formed during corrosion. Full article

In the present study, different solid solution and aging processes of as-cast and as-compressed ZM6 (Mg_2.6Nd_0.4Zn_0.4Zr) alloy were designed, and the microstructure and precipitation strengthening mechanisms were discussed. After the pre-aging treatment, a large amount of G.P. zones formed in the α-Mg matrix over the course of the subsequent secondary G.P. prescription, where the fine and dispersed Mg₁₂(Nd,Zn) phases were precipitated at the grain boundaries. The pre-aging and secondary aging processes resulted in the Mg₁₂(Nd,Zn) phase becoming globular, preventing grain boundary sliding and decreasing grain boundary diffusion. Meanwhile, precipitation phase â″(Mg₃Nd) demonstrated a coherent relationship with the α-Mg matrix after the pre-aging process, and after the secondary aging phase, Mg₁₂Nd increases and became semi-coherent in the matrix. Compared to an as-cast ZM6 alloy, the yield strength of the as-compressed ZM6 alloy increased sharply due to an increase in the yield strength that was proportional to the particle spacing, where the dislocation bypassed the second phase particle. Compared to the single-stage aging process, the two-stage aging process greatly improved the mechanical properties of both the as-cast and as-compressed ZM6 alloys. The difference between the as-cast and as-compressed states is that an as-compressed ZM6 alloy with more dislocations and twins has more dispersed precipitates in the G.P. zones after secondary aging, meaning that it is greatly strengthened after the two-stage aging treatment process. Full article

Plasma Electrolytic Oxidation (PEO) was applied to extruded ZM21 Mg alloys to improve their corrosion resistance in a chloride-containing environment. PEO was carried out in DC mode and voltage control in a fluoride-free electrolyte. Potentiodynamic polarization tests in 3.5 wt.% NaCl aqueous solution and neutral salt spray (NSS) tests were carried out. Microstructural and profilometric characterization, as well as NSS tests were performed in different conditions: (i) bare ZM21, (ii) PEO-treated ZM21, (iii) powder-coated ZM21 (without PEO interlayer), and (iv) PEO-treated ZM21 with powder coating top layer (carboxyl-functionalized polyester resin). The PEO + powder coating double layer was identified as the best-performing corrosion protection. Full article

In this study, the influence of internal pressure and axial compressive displacement on the formability of small-diameter ZM21 magnesium alloy tubes in warm tube hydroforming (THF) was examined experimentally and numerically. The deformation behavior of ZM21 tubes, with a 2.0 mm outer diameter and 0.2 mm wall thickness, was evaluated in taper-cavity and cylinder-cavity dies. The simulation code used was the dynamic explicit finite element (FE) method (FEM) code, LS-DYNA 3D. The experiments were conducted at 250 °C. This paper elucidated the deformation characteristics, forming defects and forming limit of ZM21 tubes. Their deformation behavior in the taper-cavity die was affected by the axial compressive direction. Additionally, the occurrence of tube buckling could be inferred by changes of the axial compression force, which were measured by the load cell during the processing. In addition, grain with twin boundaries and refined grain were observed at the bended areas of tapered tubes. The hydroformed samples could have a high strength. Moreover, wrinkles, which are caused under a lower internal pressure condition, were employed to avoid tube fractures during the axial feeding. The tube with wrinkles was expanded by a straightening process after the axial feed. It was found that the process of warm THF of the tubes in the cylinder-cavity die was successful. Full article

Magnesium alloys as bioresorbable materials with good biocompatibility have raised a growing interest in the past years in temporary implant manufacturing, as they offer a steady resorption rate and optimal healing in the body. Magnesium exhibits tensile strength properties similar to those of natural bone, which determines its application in load-bearing mechanical medical devices. In this paper, we investigated the biodegradation rate of Mg-Zn-Mn biodegradable alloys (ZMX410 and ZM21) before and after coating them with hydroxyapatite (HAP) via the electrophoretic deposition method. The experimental samples were subjected to corrosion tests to observe the effect of HAP deposition on corrosion resistance and, implicitly, the rate of biodegradation of these in simulated environments. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) provided detailed information on the quality, structure, and morphology of the HAP coating. The obtained results demonstrate that coating of Mg-Zn-Mn alloys by HAP led to the improvement of corrosion resistance in simulated environments, and that the HAP coating could be used in order to control the biodegradation rate. Full article