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Keywords = PLA–metal filaments

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26 pages, 4285 KiB  
Article
Machinability and Geometric Evaluation of FFF-Printed PLA-Carbon Fiber Composites in CNC Turning Operations
by Sergio Martín-Béjar, Fermín Bañón-García, Carolina Bermudo Gamboa and Lorenzo Sevilla Hurtado
Appl. Sci. 2025, 15(15), 8141; https://doi.org/10.3390/app15158141 - 22 Jul 2025
Viewed by 214
Abstract
Fused Filament Fabrication (FFF) enables the manufacturing of complex polymer components. However, surface finish and dimensional accuracy remain key limitations for their integration into functional assemblies. This study explores the potential of conventional turning as a post-processing strategy to improve the geometric and [...] Read more.
Fused Filament Fabrication (FFF) enables the manufacturing of complex polymer components. However, surface finish and dimensional accuracy remain key limitations for their integration into functional assemblies. This study explores the potential of conventional turning as a post-processing strategy to improve the geometric and surface quality of PLA reinforced with carbon fiber (CF) parts produced by FFF. Machinability was evaluated through the analysis of cutting forces, thermal behavior, energy consumption, and surface integrity under varying cutting speeds, feed rates, and specimen slenderness. The results indicate that feed is the most influential parameter across all performance metrics, with lower values leading to improved dimensional accuracy and surface finish, achieving the most significant reductions of 63% in surface roughness (Sa) and 62% in cylindricity deviation. Nevertheless, the surface roughness is higher than that of metals, and deviations in geometry along the length of the specimen have been observed. A critical shear stress of 0.237 MPa has been identified as the limit for interlayer failure, defining the boundary conditions for viable cutting operation. The incorporation of CNC turning as a post-processing step reduced the total fabrication time by approximately 83% compared with high-resolution FFF, while maintaining dimensional accuracy and enhancing surface quality. These findings support the use of machining operations as a viable and efficient post-processing method for improving the functionality of polymer-based components produced by additive manufacturing. Full article
(This article belongs to the Special Issue Advances in Carbon Fiber Reinforced Polymers (CFRPs))
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36 pages, 13208 KiB  
Review
Additive Manufacturing of Metal-Infilled Polylactic Acid-Based Sustainable Biocomposites—A Review of Methods, Properties and Applications Abetted with Patent Landscape Analysis
by Sengottaiyan Sivalingam, Venkateswaran Bhuvaneswari, Lakshminarasimhan Rajeshkumar and Devarajan Balaji
Polymers 2025, 17(11), 1565; https://doi.org/10.3390/polym17111565 - 4 Jun 2025
Viewed by 1137
Abstract
Innovations in additive manufacturing (AM) methods represent a significant advancement in manufacturing technology, opening new avenues for creating objects in various shapes and sizes. Fused deposition modeling (FDM) is a specialized AM technique in which computers build layers upon each other to form [...] Read more.
Innovations in additive manufacturing (AM) methods represent a significant advancement in manufacturing technology, opening new avenues for creating objects in various shapes and sizes. Fused deposition modeling (FDM) is a specialized AM technique in which computers build layers upon each other to form a complete 3D object. The feasibility of producing metal parts using these methods has been thoroughly analyzed, but the design process has yet to catch up with manufacturing capabilities. Biodegradable aliphatic polyester PLA is derived from lactic acid. To enhance its strength, PLA is combined with metal particles, resulting in versatile property improvements and applications. While the aesthetic and functional qualities of PLA–metal composite filaments are intriguing, they also present difficulties related to extrusion, equipment wear, and maintaining consistent print quality. These challenges could be mitigated, to some extent, with careful tuning and specialized hardware. However, the inferior mechanical properties of bioresorbable PLA filaments highlight the need for the development of infilled PLA filaments to improve strength and other characteristics. This review discusses the 3D printing of PLA infilled with metal particles, various materials used, and their properties as a matter of interest in AM technology. Additionally, the applications of PLA–metal composites, along with their implications, limitations, and prospects, are comprehensively examined in this article. This sets the stage for the development of high-strength, sustainable materials for use in a range of engineering and technology fields. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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15 pages, 10991 KiB  
Article
A New Methodology to Fabricate Polymer–Metal Parts Through Hybrid Fused Filament Fabrication
by Sofia F. Silva, Pedro M. S. Rosado, Rui F. V. Sampaio, João P. M. Pragana, Ivo M. F. Bragança, Eurico Assunção and Carlos M. A. Silva
Sustainability 2025, 17(10), 4254; https://doi.org/10.3390/su17104254 - 8 May 2025
Viewed by 593
Abstract
This paper introduces a new methodology that enables the production of polymer–metal parts through hybrid additive manufacturing. The approach combines fused filament fabrication (FFF) of polymers with adhesive bonding of metal inserts, applied during layer-by-layer construction. The work is based on unit cells [...] Read more.
This paper introduces a new methodology that enables the production of polymer–metal parts through hybrid additive manufacturing. The approach combines fused filament fabrication (FFF) of polymers with adhesive bonding of metal inserts, applied during layer-by-layer construction. The work is based on unit cells designed and fabricated using eco-friendly materials—polylactic acid (PLA) and aluminum—which were subsequently analyzed for build quality and for mechanical performance under tensile lap-shear and three-point bending tests. The acquired knowledge in terms of optimal processing parameters for attaining strong polymer–metal bonds was then applied for the fabrication and testing of prototypes representing modular corner connectors for framing applications. Results on build quality demonstrate that issues, such as lumps and warping, can be solved by finetuning the 3D printing stages of the proposed methodology. In terms of destructive testing, significant improvements in the mechanical performance of PLA can be achieved, demonstrating the feasibility of the proposed methodology in integrating the lightweight properties of polymers with the stiffness of metals. This enables the development of innovative, sustainable and eco-friendly solutions that align with the growing demand for eco-friendly materials and processes in manufacturing. Full article
(This article belongs to the Section Sustainable Materials)
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20 pages, 6614 KiB  
Article
3D Printing of Virucidal Polymer Nanocomposites (PLA/Copper Nanoparticles)
by Waldeir Silva Dias, Luana Cristiny da Cruz Demosthenes, João Carlos Martins da Costa, Leandro Aparecido Pocrifka, Nayra Reis do Nascimento, Samantha Coelho Pinheiro, Gilberto Garcia del Pino, José Luis Valin Rivera, Meylí Valin Fernández and José Costa de Macêdo Neto
Polymers 2025, 17(3), 283; https://doi.org/10.3390/polym17030283 - 22 Jan 2025
Cited by 1 | Viewed by 1326
Abstract
Metallic nanoparticles with virucidal properties dispersed in a polymeric matrix have gained prominence in the scientific community as a rapid and effective alternative that employs the additive manufacturing (AM) or 3D printing method. This study aims to produce filaments for 3D printing using [...] Read more.
Metallic nanoparticles with virucidal properties dispersed in a polymeric matrix have gained prominence in the scientific community as a rapid and effective alternative that employs the additive manufacturing (AM) or 3D printing method. This study aims to produce filaments for 3D printing using polymer nanocomposites based on polylactic acid (PLA) and copper nanoparticles (CuNPs) in different proportions. The virucidal activity of various proportions of nanoparticles in PLA was investigated. The composites were produced following a mixture design (DOE) with concentrations ranging from 1% to 2% copper nanoparticles, which were blended with PLA using a single-screw extruder. The samples were characterized by thermogravimetry (TG), differential scanning calorimetry (DSC), tensile strength testing, and fracture analysis using scanning electron microscopy (SEM). A thermal analysis of the composites indicated that the CuNPs contributed to an increase in the degradation temperature and crystallization of the PLA. Sample S7 (1.25% of CuNPs) exhibited a 4% increase in the degradation temperature compared to pure PLA. The best tensile strength results were observed in sample S7 (1.25% of CuNPs), 30% more than sample S3 (1.33% of CuNPs) due to good material cohesion, as evidenced by microscopy analyses. Regarding virucidal analyses, most composites demonstrated virus inhibition activity. Full article
(This article belongs to the Special Issue Polymer Materials for Application in Additive Manufacturing)
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21 pages, 2586 KiB  
Article
Changes in the Antibacterial Performance of Polymer-Based Nanocomposites Induced by Additive Manufacturing Processing
by Ana C. Pinho, Paula V. Morais, Manuel F. Pereira and Ana P. Piedade
Polymers 2025, 17(2), 171; https://doi.org/10.3390/polym17020171 - 11 Jan 2025
Cited by 1 | Viewed by 1174
Abstract
The idea supporting the investigation of the current manuscript was to develop customized filters for air conditioners with different pore percentages and geometry with the additional advantage of presenting antibacterial performance. This property was expected due to the reinforcement of Cu nanoparticles in [...] Read more.
The idea supporting the investigation of the current manuscript was to develop customized filters for air conditioners with different pore percentages and geometry with the additional advantage of presenting antibacterial performance. This property was expected due to the reinforcement of Cu nanoparticles in the polymeric matrix of poly(lactic acid) (PLA) and polyurethane (TPU). The filaments were characterized by their chemical composition, thermal and mechanical properties, and antibacterial behavior before and after processing by fused filament fabrication. An X-ray photoelectron spectroscopy showed that the nanocomposite filaments presented Cu particles at their surface in different valence states, including Cu0, Cu+, and Cu2+. After processing, the metallic particles are almost absent from the surface, a result confirmed by micro-computer tomography (μ-CT) characterization. Antibacterial tests were made using solid-state diffusion tests to mimic the dry environment in air conditioner filters. The tests with the nanocomposite filaments showed that bacteria proliferation was hindered. However, no antibacterial performance could be observed after processing due to the absence of the metallic element on the surface. Nevertheless, antimicrobial performance was observed when evaluated in liquid tests. Therefore, the obtained results provide valuable indications for developing new nanocomposites that must maintain their antimicrobial activity after being processed and tested in the dry conditions of solid-state diffusion. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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21 pages, 5361 KiB  
Article
Influence of 3D Printing Conditions on Physical–Mechanical Properties of Polymer Materials
by Lubomír Beníček, Martin Vašina and Pavel Hrbáček
Polymers 2025, 17(1), 43; https://doi.org/10.3390/polym17010043 - 28 Dec 2024
Cited by 4 | Viewed by 6044
Abstract
The popularity of 3D printing technology is rapidly increasing worldwide. It can be applied to metals, ceramics, composites, hybrids, and polymers. Three-dimensional printing has the potential to replace conventional manufacturing technologies because it is cost effective and environmentally friendly. This paper focuses on [...] Read more.
The popularity of 3D printing technology is rapidly increasing worldwide. It can be applied to metals, ceramics, composites, hybrids, and polymers. Three-dimensional printing has the potential to replace conventional manufacturing technologies because it is cost effective and environmentally friendly. This paper focuses on the influence of 3D printing conditions on the physical and mechanical properties of polylactic acid (PLA), poly(methyl methacrylate) (PMMA), and poly(ethylene terephthalate glycol-modified) (PETG) materials produced using Fused Deposition Modeling (FDM) technology. The impact of nozzle diameter, layer height, and printing temperature on the mechanical (i.e., bending stiffness and vibration damping) and physical (i.e., sound absorption and light transmission) properties of the studied polymer materials was investigated. It can be concluded that 3D printing conditions significantly influenced the structure and surface shape of the 3D-printed polymer samples and, consequently, their physical and mechanical properties. Therefore, it is essential to consider the type of filament used and the 3D printing conditions for specific 3D-printed material applications. Full article
(This article belongs to the Special Issue 3D Printing and Molding Study in Polymeric Materials)
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15 pages, 4416 KiB  
Article
Investigation of the Fabrication Parameters’ Influence on the Tensile Strength of 3D-Printed Copper-Filled Metal Composite Using Design of Experiments
by Vasileios Kyratsis, Anastasios Tzotzis, Apostolos Korlos and Nikolaos Efkolidis
J. Manuf. Mater. Process. 2024, 8(6), 278; https://doi.org/10.3390/jmmp8060278 - 2 Dec 2024
Viewed by 1223
Abstract
The present study investigates the effects of fabrication parameters such as the nozzle temperature, the flow rate, and the layer thickness on the tensile strength of copper-filled metal-composite specimens. The selected material is a polylactic acid (PLA) filament filled with 65% copper powder. [...] Read more.
The present study investigates the effects of fabrication parameters such as the nozzle temperature, the flow rate, and the layer thickness on the tensile strength of copper-filled metal-composite specimens. The selected material is a polylactic acid (PLA) filament filled with 65% copper powder. Two sets of 27 specimens each were fabricated, and equivalent tensile experiments were carried out using a universal testing machine. The experiments were planned according to the full factorial design, with three printing parameters, as well as three value levels for each parameter. The analysis revealed that the temperature and the flow rate had the greatest impact on the yielded tensile strength, with their contribution percentages being 42.41% and 22.16%, respectively. In addition, a regression model was developed based on the experimental data to predict the tensile strength of the 3D-printed copper-filled metal composite within the investigated range of parameters. The model was evaluated using statistical methods, highlighting its increased accuracy. Finally, an optimization study was carried out according to the principles of the desirability function. The optimal fabrication parameters were determined to maximize the tensile strength of the specimens: temperature equal to 220 °C, flow rate equal to 110%, and layer thickness close to 0.189 mm. Full article
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15 pages, 4925 KiB  
Article
The Evaluation of Sandwich Composite Materials with Vegetable Fibers in a Castor Oil Polyurethane Matrix with Their Faces and Honeycomb Core Made in a 3D Printer
by Gilberto Garcia del Pino, Abderrezak Bezazi, Antonio Claudio Kieling, José Costa de Macedo Neto, Sofia Dehaini Garcia, José Luis Valin Rivera, Meylí Valin Fernández, Aristides Rivera Torres and Francisco Rolando Valenzuela Diaz
Polymers 2024, 16(21), 2980; https://doi.org/10.3390/polym16212980 - 24 Oct 2024
Cited by 2 | Viewed by 1086
Abstract
Sandwich panels are widely used in the naval and aerospace industries to withstand the normal tensile, compressive, and shear stresses associated with bending. The faces of sandwich composites are usually made of metals such as aluminum and, in some studies with composites, using [...] Read more.
Sandwich panels are widely used in the naval and aerospace industries to withstand the normal tensile, compressive, and shear stresses associated with bending. The faces of sandwich composites are usually made of metals such as aluminum and, in some studies with composites, using a polymeric matrix, but there are no studies in the literature using a castor oil polyurethane matrix. The core of the panel must keep the faces apart and be rigid perpendicular to them. To begin the work, a study was carried out on the influence of alkaline treatment on sisal fibers to increase the fibers’ adhesion to castor oil polyurethane. There are no relevant studies worldwide on the use of this resin and the adhesion of vegetable fibers to this polyurethane. In this work, a study was carried out through a three-point bending test of sandwich panels using faces of composite material with sisal fibers subjected to an alkaline treatment of 10% by weight of sodium hydroxide and an immersion time of 4 h in the dissolution, which was the best chemical treatment obtained initially in a castor oil polyurethane matrix. The honeycomb cores were made by 3D printer and in this study two different printing filament materials, PETG and PLA, and two different core heights were compared. As a result of a traction test, it was observed that sisal fibers with chemical treatment in a castor oil polyurethane matrix can be used in composites, although the stress levels obtained are 50% lower than the stresses obtained in other matrixes such as epoxy resin. The combination of sisal faces in a castor oil polyurethane matrix and honeycomb cores made in a 3D printer showed good properties, which allows the use of renewable, sustainable and less aggressive materials for the environment. In all tests, PETG was 21% to 32% stronger than PLA. Although there was no rupture in the test specimens, the PETG cores deformed 0.5% to 3.6% less than PLA. The composites with PLA were lighter, because the core density was 13.8% lower than the PETG cores. Increasing the height of the honeycomb increased its strength. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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18 pages, 7728 KiB  
Article
Enhancing 3D Printing Copper-PLA Composite Fabrication via Fused Deposition Modeling through Statistical Process Parameter Study
by Mahmoud Moradi, Omid Mehrabi, Fakhir A. Rasoul, Anas Abid Mattie, Friedemann Schaber and Rasoul Khandan
Micromachines 2024, 15(9), 1082; https://doi.org/10.3390/mi15091082 - 27 Aug 2024
Cited by 5 | Viewed by 2087
Abstract
The rapid advancement of additive manufacturing (AM) technologies has provided new avenues for creating three-dimensional (3D) parts with intricate geometries. Fused Deposition Modeling (FDM) is a prominent technology in this domain, involving the layer-by-layer fabrication of objects by extruding a filament comprising a [...] Read more.
The rapid advancement of additive manufacturing (AM) technologies has provided new avenues for creating three-dimensional (3D) parts with intricate geometries. Fused Deposition Modeling (FDM) is a prominent technology in this domain, involving the layer-by-layer fabrication of objects by extruding a filament comprising a blend of polymer and metal powder. This study focuses on the FDM process using a filament of Copper–Polylactic Acid (Cu-PLA) composite, which capitalizes on the advantageous properties of copper (high electrical and thermal conductivity, corrosion resistance) combined with the easily processable thermoplastic PLA material. The research delves into the impact of FDM process parameters, specifically, infill percentage (IP), infill pattern (P), and layer thickness (LT) on the maximum failure load (N), percentage of elongation at break, and weight of Cu-PLA composite filament-based parts. The study employs the response surface method (RSM) with Design-Expert V11 software. The selected parameters include infill percentage at five levels (10, 20, 30, 40, and 50%), fill patterns at five levels (Grid, Triangle, Tri-Hexagonal, Cubic-Subdivision, and Lines), and layer thickness at five levels (0.1, 0.2, 0.3, 0.4, and 0.5 mm). Also, the optimal factor values were obtained. The findings highlight that layer thickness and infill percentage significantly influence the weight of the samples, with an observed increase as these parameters are raised. Additionally, an increase in layer thickness and infill percentage corresponds to a higher maximum failure load in the specimens. The peak maximum failure load (230 N) is achieved at a 0.5 mm layer thickness and Tri-Hexagonal pattern. As the infill percentage changes from 10% to 50%, the percentage of elongation at break decreases. The maximum percentage of elongation at break is attained with a 20% infill percentage, 0.2 mm layer thickness, and 0.5 Cubic-Subdivision pattern. Using a multi-objective response optimization, the layer thickness of 0.152 mm, an infill percentage of 32.909%, and a Grid infill pattern was found to be the best configuration. Full article
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18 pages, 16377 KiB  
Article
Compressive Properties of Additively Manufactured Metal-Reinforced PLA and ABS Composites
by Meelad Ranaiefar, Mrityunjay Singh, Jonathan A. Salem and Michael C. Halbig
Polymers 2024, 16(14), 2008; https://doi.org/10.3390/polym16142008 - 13 Jul 2024
Cited by 1 | Viewed by 1396
Abstract
The development of multi-material filaments has enabled fused filament fabrication-based additive manufacturing to address demand for high-performance lightweight multifunctional components. In this study, polylactic acid (PLA) and acrylonitrile butadiene styrene based filaments with metallic reinforcements of magnetic iron (MI), stainless steel (SS), bronze [...] Read more.
The development of multi-material filaments has enabled fused filament fabrication-based additive manufacturing to address demand for high-performance lightweight multifunctional components. In this study, polylactic acid (PLA) and acrylonitrile butadiene styrene based filaments with metallic reinforcements of magnetic iron (MI), stainless steel (SS), bronze (Br), copper (Cu), Bismuth (Bi), and Tungsten (W) were investigated to elucidate their complex processing–structure–property relationships. The microstructure of 3D-printed materials were characterized by microscopy and analyzed to determine the metal cross-sectional area percentage and the relationship between metal reinforcement, the polymer matrix, and porosity. Compression testing was conducted in directions parallel and perpendicular to the build direction in order to evaluate the effect of orientation and metal reinforcement on the mechanical properties. 3D-printed specimens experienced either fracture through print layers or layer-wise interfacial rupture for loads applied perpendicular and parallel to the print layers, respectively. A dependence of yield strength on loading orientation was observed for Br-PLA, Cu-PLA, SS-PLA, Bi-ABS, and W-ABS; however, MI-PLA and pure ABS specimens did not exhibit this sensitivity. Metal reinforcement also influenced the magnitude of compressive yield strength, with MI-PLA and SS-PLA demonstrating increased strength over Br-PLA and Cu-PLA, while ABS demonstrated increased strength over Bi-ABS and W-ABS. These results demonstrate the importance of considering orientation in printing and applications, the trade-off between various metallic reinforcements for added multifunctionality, and the potential of these tailored polymer composites for novel 3D-printed structures. Full article
(This article belongs to the Special Issue Mechanical Behaviors and Properties of Polymer Materials)
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11 pages, 9905 KiB  
Article
Material Extrusion 3D Printing of Micro-Porous Copper-Based Structure for Water Filters
by Nikola Kotorčević, Strahinja Milenković, Fatima Živić, Branka Jordović, Dragan Adamović, Petar Todorović and Nenad Grujović
Machines 2024, 12(7), 470; https://doi.org/10.3390/machines12070470 - 12 Jul 2024
Cited by 1 | Viewed by 1479
Abstract
This paper presents 3D-printed micro-porous structures made of a Cu/PLA composite by using material extrusion 3D printing technology. A metallic filament made of 80% copper and 20% polylactic acid (PLA) was used for the 3D printing of the porous samples. We varied printing [...] Read more.
This paper presents 3D-printed micro-porous structures made of a Cu/PLA composite by using material extrusion 3D printing technology. A metallic filament made of 80% copper and 20% polylactic acid (PLA) was used for the 3D printing of the porous samples. We varied printing parameters, aiming to obtain a micro-range porosity that can serve as a water-filtering structure. The produced samples were analyzed from the aspects of dimensional accuracy, level of porosity, and capacity for water flow. Several samples were fabricated, and the water flow was exhibited for the samples with an approximate 100 µm size of the interconnected open porosity. The application of material extrusion 3D printing, as a cost-effective, widely available technology for producing micro-range porous structures, is still challenging, especially for interconnected predefined porosity with metal-based filaments. Our research showed that the optimization of 3D printing parameters can enable the fabrication of copper-based micro-porous structures, but further research is still needed. Full article
(This article belongs to the Special Issue Recent Advances in 3D Printing in Industry 4.0)
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4 pages, 2088 KiB  
Proceeding Paper
Enhancing Strength and Surface Quality of 3D-Printed Metal-Infused Filaments in Fused Deposition Modelling
by Rama Seshu K. V. Ganga, Ramu Inala, Chandra Sekhar Jowdula, Praveen Matti and Battina N. Malleswararao
Eng. Proc. 2024, 66(1), 5; https://doi.org/10.3390/engproc2024066005 - 27 Jun 2024
Viewed by 968
Abstract
Fused deposition modelling (FDM) is a widely used 3D printing technique known for its versatility across industries. However, achieving optimal strength, crucial for applications like the automotive and aerospace industries, remains a challenge. This study demonstrates the efficacy of metal-infused filaments in enhancing [...] Read more.
Fused deposition modelling (FDM) is a widely used 3D printing technique known for its versatility across industries. However, achieving optimal strength, crucial for applications like the automotive and aerospace industries, remains a challenge. This study demonstrates the efficacy of metal-infused filaments in enhancing FDM’s strength and quality. By incorporating metal particles into polymer matrices, their mechanical properties are notably improved. PLA and metal-infill PLA (copper, silver) are tested, with silver PLA showing notably higher tensile strength and hardness. Considerations such as infill density and pattern are discussed for optimizing object strength. This work underscores the potential of metal-infused FDM printing for advancing manufacturing capabilities, especially for intricate, high-strength metal components. Full article
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12 pages, 5484 KiB  
Article
Fusedly Deposited Frequency-Selective Composites Fabricated by a Dual-Nozzle 3D Printing as Microwave Filter
by Jae-Yeon Cho, Young-Chan Oh, Seung-Cheol Shin, Sun-Kon Lee, Hyoung-Seock Seo and Sang-Eui Lee
Polymers 2024, 16(6), 786; https://doi.org/10.3390/polym16060786 - 12 Mar 2024
Cited by 4 | Viewed by 1954
Abstract
We report a fusedly deposited frequency-selective composite (FD-FSCs), fabricated with a dual-nozzle 3D printer using a conductive carbon black (CB) polylactic acid (PLA) composite filament and a pure PLA polymer filament. The square frequency-selective pattern was constructed by the conductive CB/PLA nanocomposite, and [...] Read more.
We report a fusedly deposited frequency-selective composite (FD-FSCs), fabricated with a dual-nozzle 3D printer using a conductive carbon black (CB) polylactic acid (PLA) composite filament and a pure PLA polymer filament. The square frequency-selective pattern was constructed by the conductive CB/PLA nanocomposite, and the apertures of the pattern were filled with the pure dielectric PLA material, which allows the FD-FSC to maintain one single plane, even under bending, and also affects the resonating frequency due to the characteristic impedance of PLA (εr′ ≈ 2.0). The number of the deposition layer and the printing direction were observed to affect electrical conductivity, complex permittivity, and the frequency selectivity of the FD-FSCs. In addition, the FD-FSCs designed for an X-band showed partial transmission around the resonant frequency and was observed to, quite uniformly, transmit microwaves in the decibel level of −2.17~−2.83 dB in the whole X-band, unlike a metallic frequency selective surface with full transmission at the resonance frequency. FD-FSCs embedded radar absorbing structure (RAS) demonstrates an excellent microwave absorption and a wide effective bandwidth. At a thickness of 4.3 mm, the 10 dB bandwidth covered the entire X-band (8.2~12.4 GHz) range of 4.2 GHz. Therefore, the proposed FD-FSCs fabricated by dual-nozzle 3D printing can be an impedance modifier to expand the design space and the application of radar absorbing materials and structures. Full article
(This article belongs to the Special Issue Advances in Functional Polymer Matrix Composites)
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19 pages, 39787 KiB  
Review
Fabrication and Performance of Continuous 316 Stainless Steel Fibre-Reinforced 3D-Printed PLA Composites
by Alison J. Clarke, Andrew Dickson and Denis P. Dowling
Polymers 2024, 16(1), 63; https://doi.org/10.3390/polym16010063 - 24 Dec 2023
Cited by 14 | Viewed by 2850
Abstract
This study investigates the feasibility of 3D printing continuous stainless steel fibre-reinforced polymer composites. The printing study was carried out using 316L stainless steel fibre (SSF) bundles with an approximate diameter of 0.15 mm. This bundle was composed of 90 fibres with a [...] Read more.
This study investigates the feasibility of 3D printing continuous stainless steel fibre-reinforced polymer composites. The printing study was carried out using 316L stainless steel fibre (SSF) bundles with an approximate diameter of 0.15 mm. This bundle was composed of 90 fibres with a 14 μm diameter. This fibre bundle was first coated with polylactic acid (PLA) in order to produce a polymer-coated continuous stainless steel filament, with diameters tailored in the range from 0.5 to 0.9 mm. These filaments were then used to print composite parts using the material extrusion (MEX) technique. The SSF’s volume fraction (Vf) was controlled in the printed composite structures in the range from 4 to 30 Vf%. This was facilitated by incorporating a novel polymer pressure vent into the printer nozzle, which allowed the removal of excess polymer. This thus enabled the control of the metal fibre content within the printed composites as the print layer height was varied in the range from 0.22 to 0.48 mm. It was demonstrated that a lower layer height yielded a more homogeneous distribution of steel fibres within the PLA polymer matrix. The PLA-SSF composites were assessed to evaluate their mechanical performance, volume fraction, morphology and porosity. Composite porosities in the range of 2–21% were obtained. Mechanical testing demonstrated that the stainless steel composites exhibited a twofold increase in interlaminar shear strength (ILSS) and a fourfold increase in its tensile strength compared with the PLA-only polymer prints. When comparing the 4 and 30 Vf% composites, the latter exhibited a significant increase in both the tensile strength and modulus. The ILSS values obtained for the steel composites were up to 28.5 MPa, which is significantly higher than the approximately 13.8 MPa reported for glass fibre-reinforced PLA composites. Full article
(This article belongs to the Special Issue Polymeric Materials and Their Application in 3D Printing)
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16 pages, 4174 KiB  
Article
Comparative Life Cycle Assessment of SLS and mFFF Additive Manufacturing Techniques for the Production of a Metal Specimen
by Andrea Presciutti, Elisa Gebennini, Federica Liberti, Francesca Nanni and Mario Bragaglia
Materials 2024, 17(1), 78; https://doi.org/10.3390/ma17010078 - 23 Dec 2023
Cited by 7 | Viewed by 2147
Abstract
This work is part of a research project aimed at developing a bio-based binder, composed mainly of polylactic acid (PLA), to produce Ti6Al4V feedstock suitable for use in MAM (Metal Additive Manufacturing) via mFFF (metal Fused Filament Fabrication), in order to manufacture a [...] Read more.
This work is part of a research project aimed at developing a bio-based binder, composed mainly of polylactic acid (PLA), to produce Ti6Al4V feedstock suitable for use in MAM (Metal Additive Manufacturing) via mFFF (metal Fused Filament Fabrication), in order to manufacture a titanium alloy specimen. While in Bragaglia et al. the mechanical characteristics of this sample were analyzed, the aim used of this study is to compare the mentioned mFFF process with one of the most used MAM processes in aerospace applications, known as Selective Laser Sintering (SLS), based on the Life Cycle Assessment (LCA) method. Despite the excellent properties of the products manufactured via SLS, this 3D printing technology involves high upfront capital costs while mFFF is a cheaper process. Moreover, the mFFF process has the advantage of potentially being exported for production in microgravity or weightless environments for in-space use. Nevertheless, most scientific literature shows comparisons of the Fused Filament Fabrication (FFF) printing stage with other AM technologies, and there are no comparative LCA “Candle to Gate” studies with mFFF processes to manufacture the same metal sample. Therefore, both MAM processes are analyzed with the LCA “Candle to Gate” method, from the extraction of raw materials to the production of the finished titanium alloy sample. The main results demonstrate a higher impact (+50%) process for mFFF and higher electrical energy consumption (7.31 kWh) compared to SLS (0.32 kWh). After power consumption, the use of titanium becomes the main contributor of Global Warming Potential (GWP) and Abiotic Depletion Potential (ADP) for both processes. Finally, an alternative scenario is evaluated in which the electrical energy is exclusively generated through photovoltaics. In this case, the results show how the mFFF process develops a more sustainable outcome than SLS. Full article
(This article belongs to the Special Issue 3D-Printed Composite Structures: Design, Properties and Application)
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