Search Results (8)

The conventional iron and steel industry (ISI), driven by coal utilization as its predominant feedstock, constitutes a substantial source of greenhouse gas emissions. Hydrogen metallurgy presents the opportunity to mitigate carbon emissions in ISI from the origin. Among hydrogen metallurgical approaches, the hydrogen-based direct reduction iron (H-DRI) process stands out for its substantial carbon reduction capabilities and established technological maturity. The present paper provides a comprehensive review of the development and application surrounding the H-DRI process. Firstly, the main chemical reactions of H-DRI and the relevant important parameters are introduced. Subsequently, an overview is provided of several prominent H-DRI processes, including HYL, Midrex, Midrex-H₂^®, HYL-III, HYL-ZR, BL, and Finmet, elucidating their characteristics through comparative analysis. Moreover, some research results of H-DRI process optimization are summarized. Leveraging insights garnered from globally representative projects exemplifying the industrial deployment of H-DRI technology in recent years, the trajectory of and prospective trends for industrial development in the field of H-DRI processes are explored. Further, prevailing challenges and impediments encountered in the adoption of H-DRI processes are identified, culminating in strategic recommendations tailored towards fostering future advancements. In the long term, the H-DRI process is expected to become a key path to achieve ISI cleaner production. Full article

The replacement of the blast furnace—basic oxygen furnace (BF-BOF) steelmaking route with the direct reduced iron—electric arc furnace (DRI-EAF) route reduces the direct CO₂ emissions from steelmaking by up to 68%; however, the DRI shaft furnace is one of the largest remaining point source emitters in steelmaking. The capital and operating expenses of two potential nearly carbon-neutral DRI process configurations were investigated as a modification to a standard Midrex DRI facility. First, amine-based post-combustion capture with a 95% capture rate was considered as the benchmark, as it is currently commercially available. A second, novel configuration integrated the Midrex process with pressurized chemical looping—direct reduced iron (PCL-DRI) production. The capital expenditures were 71% and 28% higher than the standard Midrex process for a Midrex + amine capture plant, and a PCL-DRI plant, respectively. There was an incremental variable operating cost of USD 103 and USD 44 per tonne of CO₂ for DRI production using amine capture and PCL-DRI, respectively. The amine capture configuration is most sensitive to the cost of steam generation, while PCL-DRI is more sensitive to the cost of electricity and the makeup oxygen carrier. An iron-based natural ore is recommended for PCL-DRI due to the low cost and availability. Based on the lower costs compared to amine-based post-combustion capture, PCL-DRI is an attractive means of eliminating CO₂ emissions from DRI production. Full article

This article presents a new graphical tool for direct reduction shaft processes inspired by the Rist diagram developed for blast furnaces. The tool represents gas flows using vectors, with specific consumption and specific oxidation as components to indicate gas/iron ratios. Key features include consideration of gas chemical composition for vector directions, easy visual representation of gas mixtures, as well as reduction and carburization rates of direct reduced iron (DRI). The tool also includes thermodynamic conditions for reduction from the Chaudron diagram, analogous to the Rist diagram. Several practical applications are presented, including quantifying gas moisture, evaluating the measurement consistency of flowmeters and gas analyzers in top gas recycling, and evaluating instantaneous DRI production by analyzing reducing gas at the inlet and outlet of the shaft. This graphical tool could be useful for production teams to monitor and optimize process flows and promote understanding among students, engineers, technicians, and operators. Its potential for online use further enhances its practical value. As a result, the tool is of significant academic and industrial interest in improving process efficiency and optimization. Full article

The direct reduction process has been developed and investigated in recent years due to less pollution than other methods. In this work, the first direct reduction iron oxide (DRI) modeling has been developed using artificial neural networks (ANN) algorithms such as the multilayer perceptron (MLP) and radial basis function (RBF) models. A DRI operation takes place inside the shaft furnace. A shaft furnace reactor is a gas-solid reactor that transforms iron oxide particles into sponge iron. Because of its low environmental pollution, the MIDREX process, one of the DRI procedures, has received much attention in recent years. The main purpose of the shaft furnace is to achieve the desired percentage of solid conversion output from the furnace. The network parameters were optimized, and an algorithm was developed to achieve an optimum NN model. The results showed that the MLP network has a minimum squared error (MSE) of 8.95 × 10⁻⁶, which is the lowest error compared to the RBF network model. The purpose of the study was to identify the shaft furnace solid conversion using machine learning methods without solving nonlinear equations. Another advantage of this research is that the running speed is 3.5 times the speed of mathematical modeling. Full article

To achieve net-zero iron and steel production by 2050, many iron and steel producers are turning to direct reduced iron (DRI)—electric arc furnace (EAF) steel production as an opportunity to achieve significant CO₂ emissions reductions relative to current levels. However, additional innovations are required to close the gap between DRI and net-zero steel. Pressurized chemical looping-DRI (PCL-DRI) is a novel technology explored to meet this target, in which the reformer firebox and fired process gas heaters are replaced with PCL combustion units. Captured CO₂ is conditioned and compressed for pipeline transportation and storage/utilization. The performance of two different PCL-DRI configurations relative to traditional DRI processes was explored via process simulation: a Midrex-type process and an Energiron-type process. The PCL-DRI processes were shown to have equivalent or lesser total fuel consumption (8% reduction) compared to the base cases, and greater process water production (170–260% increase), with minimal or no loss in thermal efficiency. PCL-DRI is a strong competitor to alternative methods of reaching net-zero DRI due to lower energy penalties for carbon capture, no required changes to stream chemistry in or out of the EAF, and no requirement for hydrogen infrastructure. Full article

The blast-furnace operating diagram proposed by Rist was revised to direct reduction and was specifically applied to the Midrex NG^TM process. The use of this graphical tool in the study of an industrial process highlighted the staggered nature of the reduction in the shaft furnace with, in particular, the existence of a prereduction zone in the upper part where metallization is thermodynamically impossible. A sensitivity study also showed the impact of the in situ reforming rate on the ability of the gas to completely reduce iron oxides. Finally, we graphically defined the minimum quality required for the top gas to produce direct-reduced iron. Full article

A dual fluidized bed (DFB) gasification process is proposed to produce sustainable reducing gas for the direct reduction (DR) of iron ore. This novel steelmaking route is compared with the established process for DR, which is based on natural gas, and with the emerging DR technology using electrolysis-generated hydrogen as the reducing gas. The DFB-DR route is found to produce reducing gas that meets the requirement of the DR reactor, based on existing MIDREX plants, and which is produced with an energetic efficiency comparable with the natural gas route. The DFB-DR path is the only route considered that allows negative CO₂ emissions, enabling a 145% decrease in emissions relative to the traditional blast furnace–basic oxygen furnace (BF–BOF) route. A reducing gas cost between 45–60 EUR/MWh is obtained, which makes it competitive with the hydrogen route, but not the natural gas route. The cost estimation for liquid steel production shows that, in Sweden, the DFB-DR route cannot compete with the natural gas and BF–BOF routes without a cost associated with carbon emissions and a revenue attributed to negative emissions. When the cost and revenue are set as equal, the DFB-DR route becomes the most competitive for a carbon price >60 EUR/tCO₂. Full article

The results of the full-scale testing of the Extruded Briquettes (BREX) as the charge components of the industrial Midrex reactor are discussed. The influence of the type of binder on the degree of metallization of BREX is analyzed. Magnesium sulfate-based binder helps to reach highest metallization degree of BREX. Mineralogical study shows the difference in the iron-silicate phase’s development as well as in the porosity change during metallization depending on the binder used. Full article