Search Results (8)

Morphological control of metal-organic frameworks (MOFs) at the micro/nanoscopic scale is critical for optimizing the electrochemical properties of them and their derivatives. In this study, manganese organic phosphate (Mn-MOP) with three distinct two-dimensional (2D) morphologies was synthesized by varying the molar ratio of Mn²⁺ to phenyl phosphonic acid, and one of the morphologies is a unique palm leaf shape. In addition, a series of 2D Mn-MOP derivatives were obtained by calcination in air at different temperatures. Electrochemical studies showed that 2D Mn-MOP derivative calcined at 550 °C and exhibited a superior specific capacitance of 230.9 F g⁻¹ at 0.5 A g⁻¹ in 3 M KOH electrolyte. The aqueous asymmetric supercapacitor and the constructed flexible solid-state device demonstrated excellent rate performance. This performance reveals the promising application of 2D Mn-MOP materials for energy storage. Full article

Carbon materials derived from marine waste have been drawing attention for supercapacitor applications. In this work, chitins from squid and prawn marine wastes were used as carbon precursors for further application as electrodes for energy storage devices. Chitins were obtained through a deproteinization method based on enzymatic hydrolysis as an alternative to chemical hydrolysis as commonly presented in the literature. The obtained porous carbons were characterized using a BET surface area analyzer to determine the specific surface area and pore size, as well as scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), Raman spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), to characterize their morphology, composition, and structure. The electrochemical characterization was performed using a glassy carbon (GC) electrode modified with marine waste-based porous carbons as the working electrode through cyclic voltammetry and galvanostatic charge/discharge using ethaline, a choline chloride-based deep eutectic solvent (DES), as an eco-friendly and sustainable electrolyte. Squid and prawn chitin-based carbons presented a surface area of 149.3 m² g⁻¹ and 85.0 m² g⁻¹, pore volume of 0.053 cm³ g⁻¹ and 0.029 cm³ g⁻¹, and an associated specific capacitance of 20 and 15 F g⁻¹ at 1 A g⁻¹, respectively. Preliminary studies were performed to understand the effect of -OH groups on the chitin-based carbon surface with DES as an electrolyte, as well as the effect of aqueous electrolytes (1 mol L⁻¹ sulphuric acid (H₂SO₄) and 1 mol L⁻¹ potassium hydroxide (KOH)) on the capacitance and retention of the half-cell set up. It is provided, for the first time, the use of chitin-based carbon materials obtained through a one-step carbonization process combined with an eco-friendly DES electrolyte for potential application in energy storage devices. Full article

A high capacitance and widened voltage frames for an aqueous supercapacitor system are challenging to realize simultaneously in an aqueous medium. The severe water splitting seriously restricts the narrow voltage of the aqueous electrolyte beyond 2 V. To overcome this limitation, herein, we proposed the facile wet-chemical synthesis of a new CuSe-TiO₂-GO ternary nanocomposite for hybrid supercapacitors, thus boosting the specific energy up to some maximum extent. The capacitive charge storage mechanism of the CuSe-TiO₂-GO ternary nanocomposite electrode was tested in an aqueous solution with 3 M KOH as the electrolyte in a three-cell mode assembly. The voltammogram analysis manifests good reversibility and a remarkable capacitive response at various currents and sweep rates, with a durable rate capability. At the same time, the discharge/charge platforms realize the most significant capacitance and a capacity of 920 F/g (153 mAh/g), supported by the impedance analysis with minimal resistances, ensuring the supply of electrolyte ion diffusion to the active host electrode interface. The built 2 V CuSe-TiO₂-GO||AC-GO||KOH hybrid supercapacitor accomplished a significant capacitance of 175 F/g, high specific energy of 36 Wh/kg, superior specific power of 4781 W/kg, and extraordinary stability of 91.3% retention relative to the stable cycling performance. These merits pave a new way to build other ternary nanocomposites to achieve superior performance for energy storage devices. Full article

The interaction between cathode and anode materials is critical for developing a high-performance asymmetric supercapacitor (SC). Significant advances have been made for cathode materials, while the anode is comparatively less explored for SC applications. Herein, we proposed a high-performance binder-free anode material composed of two-dimensional ZnFe₂O₄ nanoflakes supported on carbon cloth (ZFO-NF@CC). The electrochemical performance of ZFO-NF@CC as an anode material for supercapacitor application was examined in a KOH solution via a three-electrode configuration. The ZFO-NF@CC electrode demonstrated a specific capacitance of 509 F g⁻¹ at 1.5 A g⁻¹ and was retained 94.2% after 10,000 GCD cycles. The ZFO-NF@CC electrode showed exceptional charge storage properties by attaining high pseudocapacitive-type storage. Furthermore, an asymmetric SC device was fabricated using ZFO-NF@CC as an anode and activated carbon on CC (AC@CC) as a cathode with a KOH-based aqueous electrolyte (ZFO-NF@CC||AC@CC). The ZFO-NF@CC||AC@CC yielded a high specific capacitance of 122.2 F g⁻¹ at a current density of 2 A g⁻¹, a high energy density of 55.044 Wh kg⁻¹ at a power density of 1801.44 W kg⁻¹, with a remarkable retention rate of 96.5% even after 4000 cycles was attained. Thus, our results showed that the enhanced electrochemical performance of ZFO-NF@CC used as an anode in high-performance SC applications can open new research directions for replacing carbon-based anode materials. Full article

Exploring faster, safer, and more efficient energy storage devices will motivate scientists to develop novel energy storage products with high performance. Herein, we report porous NiO nanoparticles have been prepared by a simple hydrothermal method with CTAB and laboratory tissue paper as a template followed by calcination at three different temperatures (300, 500, and 700 °C). The electrochemical characteristics of the prepared materials were examined in a three-electrode cell configuration using aqueous potassium hydroxide (2.0 M KOH) electrolyte. The NiO-300 electrode displayed the supreme capacitance of 568.7 F g⁻¹ at 0.5 A g⁻¹. The fascinating NiO morphology demonstrates a crucial part in offering simple ion transport, shortening electron, and ion passage channels and rich energetic spots for electrochemical reactions. Finally, the asymmetric supercapacitor (ASC), NiO//AC was constructed using positive and negative electrode materials of NiO-300 and activated carbon (AC), respectively. The assembled ASC displayed excellent supercapacitive performance with a high specific energy (52.4 Wh kg⁻¹), specific power (800 W kg⁻¹), and remarkable cycle life. After quick charging (25 s), such supercapacitors in the series will illuminate the light emitting diode for an extended time, suggesting improvements in energy storage, scalable integrated applications, and ensuring business efficacy. This work will lead to a new generation of high-performance ASCs to portable electronic displays and electric automobiles. Full article

Hybrid capacitors have been developed to bridge the gap between batteries and ultracapacitors. These devices combine a capacitive electrode and a battery-like material to achieve high energy-density high power-density devices with good cycling stability. In the quest of improved electrochemical responses, several hybrid devices have been proposed. However, they are usually limited to bench-scale prototypes that would likely face severe challenges during a scaling up process. The present case study reports the production of a hybrid prototype consisting of commercial activated carbon and nickel-cobalt hydroxide, obtained by chemical co-precipitation, separated by means of polyolefin-based paper. Developed to power a 12 W LED light, these materials were assembled and characterized in a coin-cell configuration and stacked to increase device voltage. All the processes have been adapted and constrained to scalable conditions to ensure reliable production of a pre-commercial device. Important challenges and limitations of this process, from geometrical constraints to increased resistance, are reported alongside their impact and optimization on the final performance, stability, and metrics of the assembled prototype. Full article

CoO–ZnO-based composites have attracted considerable attention for the development of energy storage devices because of their multifunctional characterization and ease of integration with existing components. This paper reports the synthesis of CoO@ZnO (CZ) nanostructures on Ni foam by the chemical bath deposition (CBD) method for facile and eco-friendly supercapacitor applications. The formation of a CoO@ZnO electrode functioned with cobalt, zinc, nickel and oxygen groups was confirmed by X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS), low and high-resolution scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analysis. The as-synthesized hierarchical nanocorn skeleton-like structure of a CoO@ZnO-3h (CZ3h) electrode delivered a higher specific capacitance (C_s) of 1136 F/g at 3 A/g with outstanding cycling performance, showing 98.3% capacitance retention over 3000 cycles in an aqueous 2 M KOH electrolyte solution. This retention was significantly better than that of other prepared electrodes, such as CoO, ZnO, CoO@ZnO-1h (CZ1h), and CoO@ZnO-7h (CZ7h) (274 F/g, 383 F/g, 240 F/g and 537 F/g). This outstanding performance was attributed to the excellent surface morphology of CZ3h, which is responsible for the rapid electron/ion transfer between the electrolyte and the electrode surface area. The enhanced features of the CZ3h electrode highlight potential applications in high performance supercapacitors, solar cells, photocatalysis, and electrocatalysis. Full article

As promising candidates for next-generation energy storage devices, aqueous rechargeable batteries are safer and cheaper than organic Li ion batteries. But due to the narrow voltage window of aqueous electrolytes, proper anode materials with low redox potential and high capacity are quite rare. In this work, bismuth electrode film was directly grown by a facile hydrothermal route and tested in LiOH, NaOH and KOH electrolytes. With low redox potential (reduction/oxidation potentials at ca. −0.85/−0.52 V vs. SCE, respectively) and high specific capacity (170 mAh·g⁻¹ at current density of 0.5 A·g⁻¹ in KOH electrolyte), Bi was demonstrated as a suitable anode material for aqueous batteries. Furthermore, by electrochemical impedance spectroscopy (EIS) analysis, we found that with smaller R_s and faster ion diffusion coefficient, Bi electrode film in KOH electrolyte exhibited better electrochemical performance than in LiOH and NaOH electrolytes. Full article