Search Results (114)

Geological storage of CO₂ in offshore deep saline aquifers is widely recognized as an effective strategy for large-scale carbon emission reduction. This study aims to assess the mechanical integrity and storage efficiency of reservoirs using a multi-layer CO₂ injection method in the Enping 15-1 Oilfield CO₂ storage project which is the China’s first offshore carbon capture, utilization, and storage (CCUS) demonstration. A coupled Hydro–Mechanical (H–M) model is constructed using the TOUGH-FLAC simulator to simulate a 10-year CO₂ injection scenario, incorporating six vertically distributed reservoir layers. A sensitivity analysis of 14 key geological and geomechanical parameters is performed to identify the dominant factors influencing injection safety and storage capacity. The results show that a total injection rate of 30 kg/s can be sustained over a 10-year period without exceeding mechanical failure thresholds. Reservoirs 3 and 4 exhibit the greatest lateral CO₂ migration distances over the 10-year injection period, indicating that they are the most suitable target layers for CO₂ storage. The sensitivity analysis further reveals that the permeability of the reservoirs and the friction angle of the reservoirs and caprocks are the most critical parameters governing injection performance and mechanical stability. Full article

In protected areas of the Brazilian savannas (Cerrado), Land Surface Phenology (LSP) is influenced by both precipitation and fire, but the nature of these relationships remains unexplored. Here, we assessed the impacts of precipitation and fire on LSP metrics derived from the Normalized Difference Vegetation Index (NDVI) at Emas National Park (ENP). Using TIMESAT, along with the 250-m Moderate Resolution Imaging Spectroradiometer (MODIS) MOD13Q1 and 30-m Harmonized Landsat Sentinel (HLS) products, we investigated these effects in both grassland and woodland areas. To evaluate the effects of precipitation, we identified the driest and wettest seasonal cycles between 2002 and 2023 and analyzed the relationships between accumulated rainfall during the rainy season and each of the 13 TIMESAT metrics. To assess the effects of fire, three major events were examined: 1 September 2005 (affecting 45% of the park’s area), 12 August 2010 (90%), and 10 July 2021 (21%). The burned grassland area and the subsequent vegetation recovery following the 2021 event were analyzed in detail using a non-burned control site and LSP metrics extracted from the HLS product, covering both pre- and post-disturbance cycles. The results indicated that the metrics most positively correlated to precipitation were Amplitude (AMP), End of Season (EOS), Large and Small Seasonal Integrals (LSI and SSI), and Rate of Increase at the Beginning of the Season (RIBS). The highest correlation coefficients were found in woodland areas, which were less affected by fire disturbance than grassland areas. Similar trends were observed in the behavior of AMP, EOS, and SSI in response to both precipitation and fire, with fire exerting a stronger influence. By decoupling the fire effects from rainfall influence using the control site, we identified Base Level (BL), SSI, EOS, AMP, and Values at the End and Start of the Season (VES and VSS), as the metrics most sensitive to fire and subsequent vegetation recovery in burned areas. The effects of fire were evident for most metrics, both during the disturbance cycle and in the post-fire cycle. Our study underscores the importance of combining MODIS and HLS time series to understand vegetation phenology in the Cerrado. Full article

This study focuses on the upper section of the Zhujiang Formation in the Enping Sag of the Zhujiangkou Basin in the South China Sea, investigating the mechanisms by which astronomical orbital cycles drive paleoclimate, sea-level fluctuations, and sedimentary development. In this study, a cyclic stratigraphic analysis was performed using natural gamma-ray logging data and geochemical proxies (Chemical Index of Alteration (CIA); Al₂O₃ content) in combination with depositional noise modeling (DYNOT Dynamic Orbital Tuning Model and ρ1 noise factor). High-resolution time series analysis revealed three key findings: (1) a 15.98–19.09 Ma astronomical timescale was established through the identification of Milankovitch cycles including 405 kyr eccentricity, 100 kyr eccentricity, 40 kyr obliquity, and 20 kyr precession; (2) sea-level changes exhibited 405 kyr eccentricity-driven cyclicity, with high-eccentricity phases corresponding to warm-humid climates and transgressive mudstone deposition, and low-eccentricity phases reflecting arid conditions and regressive sandstone development; and (3) orbital-scale precession modulation regulated sediment source-to-sink processes through climate–sea level coupling. This work provides a quantitative framework for predicting astronomical cycle-controlled reservoirs, offering critical insights for deepwater hydrocarbon exploration in the Zhujiangkou Basin. Full article

Paleoenvironmental knowledge holds significant scientific value for elucidating the evolutionary history of Earth’s crust and for guiding the exploration of oil and gas resources. This study presents a comprehensive analysis of sporopollen–algae fossils from Well DW-2, located in the Zhu II Depression of the eastern South China Sea. The sampled strata of the well were from 0 to 3230 m in depth, with a substantial number of sporopollen–algae fossils identified within the Enping and Zhuhai Formations spanning from 2501 to 3227 m. Two distinct sporopollen–algae assemblages were delineated from bottom to top. The sporopollen characteristics reveal a transition from tropical and subtropical to subtropical and temperate plant communities, reflecting the warm and humid climate during the formation of the Enping Formation and the relatively cool and dry climate during the formation of the Zhuhai Formation. A significant number of marine dinoflagellate fossils were identified, and the observed changes in algal characteristics suggest that the Enping Formation was accumulated in a shallow marine environment, while the Zhuhai Formation was predominantly formed in a transitional setting between marine and terrestrial conditions at the shelf margin. These findings not only enhance our understanding of the paleoenvironmental conditions in the South China Sea region but also have broader implications for reconstructing global paleoclimates and identifying potential hydrocarbon reservoirs in similar sedimentary basins. Full article

Litter serves as a crucial source of soil nutrients in sandy land ecosystems. Soil enzyme activities and their stoichiometric ratios act as essential “bridges” linking microbial metabolism with nutrient cycling, thereby reflecting the availability of soil nutrients and the sensitivity to microbial substrate limitations. To investigate the effects of litter quality changes on soil nutrients, enzyme activities, and stoichiometric ratios in sandy land, leaf litter and surface soil were collected from four sand-fixing forests in the Mu Us Sandy Land, including YC (Corethrodendron fruticosum), NT (Caragana korshinskii), ZSH (Amorpha fruticose), and SL (Salix cheilophila). These samples were then used for indoor cultivation. Experiments with these four leaf litter types were carried out; one treatment with no litter added served as the control. Our aim was to systematically study the changing characteristics of enzyme activities related to soil carbon, nitrogen, and phosphorus with different litter inputs. The results indicate the following: (1) Compared to the control treatment with no litter added (CK), the addition of all four types of litter significantly increased soil organic carbon, total nitrogen, and alkaline nitrogen contents. The addition of NT and YC litter significantly increased dissolved organic carbon, microbial biomass carbon (MBC), and microbial biomass nitrogen (MBN). (2) The addition of the four types of litter had different effects on the soil enzyme activity, showing increasing trends overall. A chemical analysis of the enzyme activity revealed that the soil was limited in nitrogen and phosphorus. After the addition of the ZSH, NT, and YC litter, the enzymatic C/P acquisition ratio (E_C/P) and enzymatic N/P acquisition ratio (E_N/P) decreased significantly, alleviating the limitation of phosphorus. After the addition of the NT litter, the enzymatic C/N acquisition ratio (E_C/N) increased significantly, alleviating the limitation of soil nitrogen. (3) A correlation analysis showed that the soil nutrients had varying degrees of correlation with enzyme activity and their stoichiometric ratio. The redundancy analysis results show that MBN, TN, MBC/MBN, organic carbon, and available nitrogen were key factors influencing soil enzyme activity and stoichiometric ratios. These results provide a reference for nutrient cycling during sandy soil restoration, and they provide essential data support for the development of fragile ecosystem models in the context of global change. Full article

The overuse of inorganic phosphate fertilizers in soils has led to the transfer of inorganic phosphorus (Pi) to aquatic ecosystems, resulting in eutrophication. Adsorption–desorption studies in batch systems were used to evaluate the effect of adding 1% zinc oxide (ZnO) engineered nanoparticles (ENPs) on Pi retention in Ultisol, and Mollisol soils. The 1% ZnO–ENPs showed increased chemical properties such as pH, electrical conductivity, and organic matter content, and reduce nutrient bioavailability (P, N, and Zn), and physical properties such as surface area and pore size of the two soils. The kinetic data of Pi adsorption on Ultisol, Mollisol, Ultisol + 1% ZnO–ENP, and Mollisol + 1% ZnO–ENP systems fitted well to the pseudo-second-order model (r² ≥ 0.942, and χ² ≤ 61), and the Elovich model (r² ≥ 0.951, and χ² ≤ 32). Pi adsorption isotherms for the Ultisol soil adequately fitted to the Freundlich model (r² = 0.976, and χ² = 16), and for the Mollisol soil, the Langmuir model (r² = 0.991, and χ² = 3) had a better fit to the data. With 1% ZnO–ENPs, the linear, Langmuir, and Freundlich models correctly described the Pi adsorption data. Pi desorption was reduced in the Ultisol compared to the Mollisol soil, and with 1% ZnO–ENPs further decreased Pi desorption in both soils. Therefore, ENPs can be used as a new alternative material for Pi fixation in agricultural soils and contribute to mitigating eutrophication issues of aqueous systems. Full article

The Gurney flap (GF) is a simple flat plate frequently mounted at the airfoil rear. Several investigations have been devoted to studying the effect of a rigid or even movable GF on the aerodynamic behavior of several devices such as flapping airfoils and vertical or horizontal axis turbines. The present paper proposes a new concept of a deformable Gurney flap (DGF) to improve the output power of a flapping airfoil in vertical mode. The advantage of this model is the full control of the effect on the GF during the flapping movement. The DGF is expandable and contractible which allows for monitoring and adjusting the pressure distribution at the appropriate time and position. By using a 2D transient simulation with a specific dynamic mesh design, an extended numerical analysis has been provided. It was found that this model is able to increase the output power by 19.5%. Furthermore, the concept of the DGF is applied on flapping turbines in hybrid modes such as swing arm mode and D-shaped mode. These modes are investigated to clarify the studied model’s advantage and to demonstrate the possibility of applying this strategy to control the different flapping movements. Full article

Background/Objectives: Vaccination remains the most effective means of preventing influenza virus infections. However, the continuous antigenic drift and shift of influenza viruses lead to a reduced efficacy of the existing vaccines, necessitating vaccines capable of broad protection. Methods: To address this, we developed a modular vaccine strategy pairing a clinical-stage adjuvanted recombinant hemagglutinin (HA) vaccine (SCVC101) with OMN, a heptameric nanoparticle displaying conserved influenza A virus T-cell epitopes from nucleoprotein (NP) and matrix 2 ectodomain (M2e). Results: OMN induced cross-reactive M2e-specific antibodies, binding to diverse influenza A subtypes. Critically, the co-administration of OMN with SCVC101 enhanced cellular immunity and cross-protection without diminishing HA-induced humoral responses. Conclusions: This dual-antigen delivery system enables annual HA component updates, aligned with WHO recommendations, while the conserved OMN nanoparticle acts as a universal booster, leveraging existing production infrastructure. This approach offers a promising strategy for improving the influenza vaccine’s efficacy against emerging viral variants. Full article

Vaccination remains the most effective strategy for preventing infectious diseases. Subunit vaccines, which consist of antigenic components derived from pathogens, offer significant advantages in terms of biosafety, ease of preparation, and scalability. However, subunit vaccines often exhibit lower immunogenicity than whole-pathogen vaccines do. To address this limitation, coupling antigens with nanoparticles has emerged as a promising strategy for enhancing immune responses by mimicking pathogen structures and improving antigen presentation. This study evaluated the stability of ferritin (F-nps) and encapsulin (E-nps) nanoparticles and their efficient uptake by bone-marrow-derived dendritic cells (BMDCs) in vitro. In vivo studies demonstrated their effective targeting of lymph nodes. The African swine fever virus C129R protein was conjugated to ferritin and encapsulin nanoparticles to assess its ability to enhance antigen-specific immune responses. In murine models, both F-nps and E-nps significantly increased the immunogenicity of the C129R antigen, highlighting their potential as effective vaccine delivery systems. These findings underscore the promise of ferritin and encapsulin nanoparticles as delivery platforms for enhancing antigen immunogenicity and pave the way for the development of nanoparticle-based vaccines. Full article

Multifractal analysis has been used in the exploration of soil grain size distributions (GSDs) in environmental and agricultural research. However, multifractal studies regarding the GSDs of sediments in braided delta-front are currently scarce. Open-source software designed for the realization of this technique has not yet been programmed. In this paper, the multifractal parameters of 61 GSDs from braided delta-front in the Paleogene Enping Formation in Huilu Low Uplift, Pearl River Mouth basin, are calculated and compared with traditional parameters. Multifractal generalized dimension spectrum curves are sigmoidal and decrease monotonically. Multifractal singularity spectrum curves are asymmetric, convex, and right-hook unimodal. The entropy dimension and singularity spectrum width ranges of silt-mudstones and gravelly sandstones are wider than those of fine and medium-coarse sandstones. The symmetry degree scopes from different lithologies are concentrated in distinguishing intervals. With the increase of grain sizes, the symmetry degree decreases overall. Both the symmetry degree and mean of GSDs are effective to distinguish the different lithologies from various depositional environments. A flexible and easy-to-use MATLAB (2021b)^® GUI (graphic user interface) package, MfGSD (Multifractal of GSD, V1.0), is provided to perform multifractal analysis on sediment GSDs. After raw GSDs imported into MfGSD, multifractal parameters are batch calculated and graphed in the interface. Then, all multifractal parameters can be exported to an Excel file, including entropy dimension, singularity spectrum, correlation dimension, symmetry degree of multifractal spectrum, etc. MfGSD is effective, and the multifractal parameters outputted from MfGSD are helpful to distinguish depositional environments of GSDs. MfGSD is open-source software that can be used to explore GSDs from various kinds of depositional environments, including water or wind deposits. Full article

There are two sets of hydrocarbon source rock formations developed in the Paleogene of the Zhu-1 Depression: the Wenchang Formation of semi deep lacustrine facies and the Enping Formation of lacustrine facies. Their basic geochemical characteristics, chemical structures, kerogen components, sedimentary paleoenvironments, etc., are not the same. High quality hydrocarbon source rocks are the basic conditions for oil and gas generation. This article comprehensively evaluates the key depression Paleogene hydrocarbon source rocks in the Zhu-1 Depression, and studies the development mechanism and controlling factors of hydrocarbon source rocks in this area, which is of great significance for understanding the development conditions, quality, and predicting potential high-quality hydrocarbon source rocks. After conducting rock pyrolysis, major and trace element analysis, and infrared spectroscopy experiments on the samples, it was found that the main source rock type of the Wenchang Formation is type II₁, which has a high HI value; the Enping Formation is mainly composed of II₂-III types with low HI values (with a small number of II₁ types), and the source rocks of the Wenchang Formation have a strong hydrocarbon producing aliphatic structure, with the sapropelic and shell formations being larger than the Enping Formation source rocks. By using methods such as CIA values, C values, and Mo-U covariant models, it can be concluded that during the Wenchang to Enping periods, the climate changed from warm and dry to cool and humid, and the overall environment was characterized by freshwater, weak oxidation weak reduction, and gradually decreasing paleo-productivity. At the same time, it was analyzed that the formation of organic rich sediments in the source rocks of the Zhu-1 Depression played an important role in the relative oxygen phase. The ratio of V/(V + Ni) to V/Cr can better indicate the redox environment of the water body and show a good correlation with TOC. Two sets of development models of source rocks controlled by paleooxygen phase were initially established, providing sufficient scientific basis for oil and gas exploration in the area. Full article

Phytosphingosine-based 1-O-acylceramide (CerENP) from the human stratum corneum has not been reported on. High-resolution mass spectrometry was used to identify CerENP from skin samples. A vehicle-controlled human study was performed to investigate the physiological interaction between ceramide NP (CerNP) and CerENP with respect to skin hydration, cohesion, and TEWL, all of which were measured. Twenty volunteers were treated with test creams containing CerENP together with CerNP, which significantly improved skin barrier parameters after four weeks of application: 1. Skin hydration was increased by 26% compared to when CerNP was used alone, and moisture retention was better than it was with the CerNP control. 2. Stratum corneum (SC) cohesion was strengthened significantly only when using the test cream formulated with CerENP. The results suggested the boosting effects of CerENP on the skin barrier functions exerted by CerNP since only a small amount is required, as low as one-tenth of CerNP. This is the first report on the identification of CerENP in the human SC and its skin barrier activities in human skin. In conclusion, the combinatorial use of CerENP and CerNP at an appropriate relative ratio could be a new normal in developing an ideal moisturizer for dry and atopic skin. Full article

The diversity of the species-rich copepod family Laophontidae T. Scott, 1905, is rarely investigated in China. Based on the recent collections from the coasts of the Yellow Sea in Shandong, two species of the genus Quinquelaophonte Wells, Hicks and Coull, 1982 were first reported from China, with one identified as new. The new species, Quinquelaophonte xinzhengi sp. nov., differs from other congeners by the following characteristics: female caudal ramus about 3.2 times as long as maximum width; P1 enp-2 bearing one claw and one minute seta; female P3 exp-3 with two inner setae, male P3 exp-3 with one inner seta; P4 exp-3 with one inner seta; and female P5 exopod bearing six setae. The COI genetic divergences between the new species and three closely related congeneric species all exceed 20% (21.5–22.3%), supporting their separate species status. Our samples of Q. enormis Kim, Nam and Lee, 2020, which are first found in China, show subtle differences with the original description of the type specimens from Korea on basis of maxilliped and P2 enp-1 with cuticular bulge subapically, female P3 and P4 without conspicuous morphological variation. This is also the first report of Quinquelaophonte from the China Seas. Full article

As internal combustion engines (ICEs) develop towards higher explosion pressures and lower weights, their structures need to be more compact; thus, the wall thickness of their cylinder liners is reducing. However, intense vibrations in the cylinder liner can lead to coolant cavitation and, in severe cases, penetration of the liner, posing a significant reliability issue for ICEs. Therefore, research on cylinder liner cavitation has attracted increasing interest. Gray cast iron is widely used in cylinder liners for its hardness and wear resistance; however, additional surface plating is necessary to improve cavitation resistance. This study developed a novel surface-modification technology using electroless Ni-P plating combined with high-temperature heat treatment to create cylinder liners with refined grains, low weight loss rate, and high hardness. The heat-treatment temperature ranged from 100 to 600 °C. An ultrasonic cavitation tester was used to simulate severe cavitation conditions, and we analyzed and compared Ni-P-plated and heat-treated Ni-P-plated surfaces. The findings showed that the combination of Ni-P plating with high-temperature heat treatment led to smoother, more refined surface grains and the formation of cellular granular structures. After heat treatment, the plating structure converted from amorphous to crystalline. From 100 to 600 °C, the weight loss of specimens was within the range of 0.162% to 0.573%, and the weight loss (80.2% lower than the plated surface) and weight loss rate at 600 °C were the smallest. Additionally, cavitation resistance improved by 80.1%. The microhardness of the heat-treated plated surface reached 895 HV at 600 °C, constituting a 306 HV (65.8%) increase compared with that of the unplated surface, and a 560 HV increase compared with that of the maximum hardness of the plated surface without heat treatment of 335 HV, with an enhancement rate of 62.6%. Full article

Non-target organisms are not well studied. The objective of this work was to evaluate the effect of seven essential oils, two fixed oils, d-limonene and eugenol on the mortality, behavior and infectivity of entomopathogenic nematodes (ENPs). The oils were diluted at 1% (v/v) in water with Tween^® 80 PS at 0.05% (v/v), and water with Tween^® alone was used as the control treatment. In the mortality test, 2 mL of solution containing 50 µL of the nematode suspension, 20 µL of oil/compounds solution isolated with Tween 80, and 1930 µL of water were placed in plastic containers. After four days, the number of dead juveniles was counted. In the bioassay of the behavior of the EPNs, the frequency of lateral body beats of the infective juveniles in liquid medium was analyzed after exposure to the solutions. In the infectivity test, after contact of the EPNs with oils and essential oil chemical compounds, the juveniles were washed and applied to second-instar Spodoptera eridania larvae. All oils and isolated compounds caused mortality in H. amazonensis and S. rarum, with Ocimum canum and the isolated compound eugenol showing the highest efficacy against H. amazonensis and O. canum, Eucalyptus citriodora, Zingiber officinale, Salvia sclarea and the isolated compound eugenol being the most effective against S. rarum. There was a reduction in the number of lateral beats of H. amazonensis and S. rarum for all treatments, with the exception of Cymbopogon winterianus in H. amazonensis and Annona muricata in S. rarum. The infectivity of H. amazonenis and S. rarum on S. eridania was reduced when exposed to the solutions, with the exception of the isolated compound d-limonene in both species, soursop for H. amazonenis and rosemary for S. rarum, which were classified as non-toxic to the species tested. The results obtained in this study may be useful for the choice of oils and essential oil chemical compounds with potential use in integrated pest management programs. Full article