Search Results (15)

Recycled Concrete Aggregate (RCA) of the chemical and biological effects must be understood to avoid potential adverse impacts to the bay’s aquatic ecosystem. RCA application as a base material for oyster reefs did not adversely affect oyster spat growth and survival, or the surrounding environment. Evaluated RCA leaching for petroleum byproducts showed that RCA as a base material for oyster reefs did not leach any hydrocarbon chemicals, and no water extractable SVOC were detected. The research found potential RCA application to the Chesapeake Bay watershed as a bottom conditioning material for oyster aquaculture. Overall, the findings support the use of RCA for oyster aquaculture. Full article

Anthropogenic salt inputs have impacted many streams in the U.S. for over a century. Urban stream salinity is often chronically elevated and punctuated by episodic salinization events, which can last hours to days after snowstorms and the application of road salt. Here, we investigated the impacts of freshwater salinization on total dissolved nitrogen (TDN) and NO₃⁻/NO₂⁻ concentrations and fluxes across time in urban watersheds in the Baltimore-Washington D.C. metropolitan area of the Chesapeake Bay region. Episodic salinization from road salt applications and snowmelt quickly mobilized TDN in streams likely through soil ion exchange, hydrologic flushing, and other biogeochemical processes. Previous experimental work from other studies has shown that salinization can mobilize nitrogen from sediments, but less work has investigated this phenomenon with high-frequency sensors and targeted monitoring during road salt events. We found that urban streams exhibited elevated concentrations and fluxes of TDN, NO₃⁻/NO₂⁻, and specific conductance that rapidly peaked during and after winter road salt events, and then rapidly declined afterwards. We observed plateaus in TDN concentrations in the ranges of the highest specific conductance values (between 1000 and 2000 μS/cm) caused by road salt events. Plateaus in TDN concentrations beyond a certain threshold of specific conductance values suggested source limitation of TDN in watersheds (at the highest ranges in chloride concentrations and ranges); salts were likely extracting nitrogen from soils and streams through ion exchange in soils and sediments, ion pairing in soils and waters, and sodium dispersion of soils to a certain threshold level. When watershed transport was compared across land use, including a forested reference watershed, there was a positive relationship between Cl⁻ loads and NO₃⁻/NO₂⁻ loads. This relationship occurred across all sites regardless of land use, which suggests that the mass transport of Cl⁻ and NO₃⁻/NO₂⁻ are likely influenced by similar factors such as soil ion exchange, ion pairing, sodium dispersion of soils, hydrologic flushing, and biogeochemical processes. Freshwater salinization has the potential to alter the magnitude and timing of total dissolved nitrogen delivery to receiving waters during winter months following road salt applications, and further work should investigate the seasonal relationships of N transport with salinization in urban watersheds. Full article

Nonpoint source (NPS) pollution is a pressing issue worldwide, especially in the Chesapeake Bay, where sediment, nitrogen (N), and phosphorus (P) are the most critical water quality concerns. Despite significant efforts by federal, state, and local governments, the improvement in water quality has been limited. Investigating the spatial distribution of NPS hotspots can help understand NPS pollutant output and guide control measures. We hypothesize that as land cover changes from natural (e.g., forestland) and agricultural to suburban and ultra-urban, the distribution of NPS pollution source areas becomes increasingly spatially uniform. To test this hypothesis, we analyzed three real watersheds with varying land cover (Greensboro watershed for agriculture, Watts Branch watershed for suburban, and Watershed 263 for ultra-urban) and three synthetic watersheds developed based on the Watts Branch watershed, which ranged from forested and agricultural to ultra-urban but had the same soil, slope, and weather conditions. The Soil and Water Assessment Tool (SWAT) was selected as a phenomenological model for the analysis, and SWAT-CUP was used for model calibration and validation. The hydrologic responses of the three real and synthetic watersheds were simulated over ten years (1993–2002 or 2002–2011), and calibration and validation results indicated that SWAT could properly predict the export of runoff and three target NPS pollution constituents (sediment, total nitrogen, and total phosphorus). The results showed that the distribution of NPS pollutant outputs becomes increasingly uniform as land cover changes from agriculture to ultra-urban across watersheds. This research suggests that the spatial distribution of NPS pollution source areas is a function of the major land cover category of study watersheds, and control strategies should be adapted accordingly. If NPS pollution is distributed unevenly across a watershed, hotspot areas output a disproportionate amount of pollution and require more targeted and intensive control measures. Conversely, if the distribution of NPS pollution is more uniform across a watershed, the control strategies need to be more widespread and encompass a larger area. Full article

Environmentalists face several challenges when communicating water quality hazards, especially those that are unseen to the naked eye. Grounded in the Extended Parallel Process Model, we analyzed how perceptions of conservation responsibility and the visualization of pollution affected perceived water quality threats, efficacy, and pro-environmental behavior outcomes. We conducted a 2 × 2 between-subjects controlled message-testing experiment with 502 adults from the Chesapeake Bay watershed. Individuals viewed personal or government attribution messages with fear or non-fear visuals to see how messages affected intentions to take part in a river clean-up day, enact environmentally friendly behaviors, and comment on public policy. Messages that promoted government responsibility and those that featured images of polluted water increased response efficacy, threat appraisals, fear, and intentions. Promoting personal responsibility yielded more limited effects. Furthermore, messages were less effective when they featured visuals of clean water. Implications include recommendations for using responsibility attribution messages in practice and engaging the public with information about unseen hazards. Full article

Suspended sediment is an important constituent of freshwater ecosystems that supports biogeochemical, geomorphological, and ecological processes. Current knowledge of suspended sediment is largely based on surface water studies; however, improved understanding of surface and in situ groundwater suspended sediment processes will improve pollutant loading estimates and watershed remediation strategies. A study was conducted in a representative mixed-use, agro-forested catchment of the Chesapeake Bay Watershed of the northeast, USA, utilizing an experimental watershed study design, including eight nested sub-catchments. Stream water and shallow groundwater grab samples were collected monthly from January 2020 to December 2020 (n = 192). Water samples were analyzed for suspended sediment using gravimetric (mg/L) and laser particle diffraction (µm) analytical methods. Results showed that shallow groundwater contained significantly higher (p < 0.001) total suspended solid concentrations and smaller particle sizes, relative to stream water. Differences were attributed to variability between sites in terms of soil composition, land use/land cover, and surficial geology, and also the shallow groundwater sampling method used. Results hold important implications for pollutant transport estimates and biogeochemical modeling in agro-forested watersheds. Continued work is needed to improve shallow groundwater suspended sediment characterization (i.e., mass and particle sizes) and the utility of this information for strategies that are designed to meet water quality goals. Full article

Inequality is an emergent property of complex systems. In catchments, variation in hydroclimatic conditions and biogeochemistry cause streamflow and constituent loads to exhibit strong temporal inequality, with most loads exported during “hot moments”. Achieving water-quality-restoration goals in a cost-effective manner requires targeted implementation of conservation practices in “hot spots” in the landscape and “hot moments” in time. While spatial targeting is commonly included in development of watershed management plans, the need for temporal targeting is often acknowledged, but no common way to address it has been established. Here, we implement a Lorenz Inequality decision-making framework that uses Lorenz Curves and Gini Coefficients to quantify the degree of temporal inequality exhibited by contaminant loads and demonstrate its utility for eight impaired catchments in the Chesapeake Bay watershed. The framework requires a load-reduction goal be set and then links the degree of temporal inequality in annual nutrient loads to the periods of time during which those loads could be targeted. These results are critical in guiding development of site-specific, cost-effective tools that facilitate load-reduction and water-quality goal attainment for individual catchments. The framework provides valuable insight into site-specific potentials for meeting load-reduction goals. Full article

Changes in land cover throughout the Chesapeake Bay watershed, accompanied by variability in climate patterns, can impact runoff and water quality. A study was conducted using the Soil and Water Assessment Tool (SWAT) for the James River watershed in Virginia, the southernmost tributary of the Chesapeake Bay, from 1986 to 2018, in order to evaluate factors that affect water quality in the river. This research focuses on statistical analysis of land use, precipitation, and water quality indicators. Land cover changes derived from satellite imagery and geographic information system (GIS) tools were compared with water quality parameters throughout that timeframe. Marked decreases in forest land cover were observed throughout the watershed, as well as increased residential development. Our findings suggest strong links between land cover modification, such as residential development, and degraded water quality indicators such as nitrogen, phosphorus, and sediment. In addition, we note direct improvements in water quality when forest land areas are preserved throughout the watershed. Full article

Smallmouth bass Micropterus dolomieu is an economically important sportfish and within the Chesapeake Bay watershed has experienced a high prevalence of external lesions, infectious disease, mortality events, reproductive endocrine disruption and population declines. To date, no clear or consistent associations with contaminants measured in fish tissue or surface water have been found. Therefore, plasma samples from two sites in the Potomac River and two in the Susquehanna River drainage basins, differing in land-use characteristics, were utilized to determine if perfluoroalkyl substances were present. Four compounds, perfluorooctane sulphonic acid (PFOS), perfluoroundecanoic acid (PFUnA), perfluorodecanoic acid (PFDA) and perfluorododecanoic acid (PFDoA), were detected in every fish. Two additional compounds, perfluorooctane sulphonamide (PFOSA) and perfluorononanoic acid (PFNA), were less commonly detected at lower concentrations, depending on the site. Concentrations of PFOS (up to 574 ng/mL) were the highest detected and varied significantly among sites. No seasonal differences (spring versus fall) in plasma concentrations were observed. Concentrations of PFOS were not significantly different between the sexes. However, PFUnA and PFDoA concentrations were higher in males than females. Both agricultural and developed land-use appeared to be associated with exposure. Further research is needed to determine if these compounds could be affecting the health of smallmouth bass and identify sources. Full article

This research focuses on the efficiency of recommended heavy use area protection (HUAP) pads installed in poultry houses utilizing the Choptank River, a tributary of the Chesapeake Bay. The Chesapeake Bay watershed is severely affected by crop agriculture and poultry feeding operations. Water quality degradation along with scarcity of water is a significant concern in this area, suggesting a need for changes in both environmental and groundwater management practices. Our objective in this study was to compare the efficiency of HUAP in reducing litter spillage and nutrient runoff between two poultry houses, one of which was constructed in 2005 and the other in 2009. The poultry house constructed in 2005 did not have HUAP pads initially; they were built in 2006. The poultry house built in 2009 had the pads from the starting point. We collected soil and water samples each month and analyzed them for pH, electrical conductivity (EC), nitrate, nitrite, total nitrogen, phosphate, and other soil properties throughout the year. The pH of soil and water samples was in the range of 6.8–8.0 and 6.5–7.2, respectively. We collected six water samples in total in the ditch, from points at retention ponds near the farm ditch to sites in wooded areas on the farm. Water sample B (where ditch water meets retention pond water from the poultry farm) had the highest EC value and nitrate, nitrite, and total nitrogen concentrations compared with other water samples. The subsequent water samples downstream had reduced loads of nutrients. The study results suggest that there was a minimum carryover of nutrients from soil into the runoff water, storm ditches, and adjacent stream. There was also a minimal effect of house cleaning and storm events in raising the concentration of nutrients in soil and water samples at our study sites. The older poultry site had higher total nitrogen and phosphorous surrounding the pads, whereas no elevated levels of nutrients were identified at the newer site. The ability of HUAP pads to hold onto contaminates decreases with age and use. This study also shows that the impacts from poultry activities on surface and groundwater can be minimized by using management practices such as HUAP pads. These practices can reduce pollution in the farm, increase productivity, and save farmers and ranchers time and money in the long run. Full article

Saturated hydraulic conductivity (K_sat) is fundamental to shallow groundwater processes. There is an ongoing need for observed and model validated K_sat values. A study was initiated in a representative catchment of the Chesapeake Bay Watershed in the Northeast USA, to collect observed K_sat and validate five K_sat pedotransfer functions. Soil physical characteristics were quantified for dry bulk density (bdry), porosity, and soil texture, while K_sat was quantified using piezometric slug tests. Average bdry and porosity ranged from 1.03 to 1.30 g/cm³ and 0.51 to 0.61, respectively. Surface soil (0–5 cm) bdry and porosity were significantly (p < 0.05) lower and higher, respectively, than deeper soils (i.e., 25–30 cm; 45–50 cm). bdry and porosity were significantly different with location (p < 0.05). Average soil composition was 92% sand. Average K_sat ranged from 0.29 to 4.76 m/day and significantly differed (p < 0.05) by location. Four models showed that spatial variability in farm-scale K_sat estimates was small (CV < 0.5) and one model performed better when K_sat was 1.5 to 2.5 m/day. The two-parameter model that relied on silt/clay fractions performed best (ME = 0.78 m/day; SSE = 20.68 m²/day²; RMSE = 1.36 m/day). Results validate the use of simple, soil-property-based models to predict K_sat, thereby increasing model applicability and transferability. Full article

Quantifying land-use and land-cover change (LULCC) effects on carbon sources and sinks has been very challenging because of the availability and quality of LULCC data. As the largest estuary in the United States, Chesapeake Bay is a rapidly changing region and is affected by human activities. A new annual land-use and land-cover (LULC) data product developed by the U.S. Geological Survey Land Change Monitoring and Analysis Program (LCMAP) from 2001 to 2011 was analyzed for transitions between agricultural land, developed land, grassland, forest land and wetland. The Land Use and Carbon Scenario Simulator was used to simulate effects of LULCC and ecosystem disturbance in the south of the Chesapeake Bay Watershed (CBW) on carbon storage and fluxes, with carbon parameters derived from the Integrated Biosphere Simulator. We found that during the study period: (1) areas of forest land, disturbed land, agricultural land and wetland decreased by 90, 82, 57, and 65 km², respectively, but developed lands gained 293 km² (29 km² annually); (2) total ecosystem carbon stock in the CBW increased by 13 Tg C from 2001 to 2011, mainly due to carbon sequestration of the forest ecosystem; (3) carbon loss was primarily attributed to urbanization (0.224 Tg C·yr⁻¹) and agricultural expansion (0.046 Tg C·yr⁻¹); and (4) estimated carbon emissions and harvest wood products were greater when estimated with the annual LULC input. We conclude that a dense time series of LULCC, such as that of the LCMAP program, may provide a more accurate accounting of the effects of land use change on ecosystem carbon, which is critical to understanding long-term ecosystem carbon dynamics. Full article

Streamside forests of urbanizing coastal regions lie at the nexus of global changes: rising sea levels, increasing storm surge, expanding urban development, and invasive species. To understand how these combined stressors affect forest conditions, we identified forest patches adjacent to urban land, analyzed adjacent land cover, modeled forest inundation, and sampled 100 sites across the Chesapeake Bay and Delaware Bay watersheds. We found that the majority of forest patches are adjacent to urban land and projected flooding will affect 8–19% of regional forested land. We observed non-native invasive plants in 94% of forest plots. Trees were predominantly native, but over half of shrub stems were invasive species and more than 80% of plots contained invasive woody vines. Disturbance of human origin was correlated with abundance of invasive trees. Signs of deer activity were common. Richness and number of growth forms of invasive plants were related to adjacent agricultural land cover. These data reveal that streamside forests are impacted by the interacting stressors of urbanization, climate change, and invasive species spread. Our results emphasize the importance of protection and restoration of forests in urban regions and point to the need for a social-ecological systems approach to improve their condition. Full article

Riparian forest (CP22) buffers are implemented in the Chesapeake Bay Watershed to trap pollutants in surface runoff thus minimizing the amount of pollutants entering the stream network. For these buffers to function effectively, overland flow must enter the riparian zones as dispersed sheet flow to facilitate slowing, filtering, and infiltrating of surface runoff. The occurrence of concentrated flowpaths, however, is prevalent across the watershed. Concentrated flowpaths limit buffer filtration capacity by channeling overland flow through or around buffers. In this study, two topographic metrics (topographic openness and flow accumulation) were used to evaluate the occurrence of concentrated flowpaths and to derive effective CP22 contributing areas in four Long-Term Agroecosystem Research (LTAR) watersheds within the Chesapeake Bay Watershed. The study watersheds include the Tuckahoe Creek watershed (TCW) located in Maryland, and the Spring Creek (SCW), Conewago Creek (CCW) and Mahantango Creek (MCW) watersheds located in Pennsylvania. Topographic openness identified detailed topographic variation and critical source areas in the lower relief areas while flow accumulation was better at identifying concentrated flowpaths in higher relief areas. Results also indicated that concentrated flowpaths are prevalent across all four watersheds, reducing CP22 effective contributing areas by 78% in the TCW, 54% in the SCW, 38% in the CCW and 22% in the MCW. Thus, to improve surface water quality within the Chesapeake Bay Watershed, the implementation of riparian forest buffers should be done in such a way as to mitigate the effects of concentrated flowpaths that continue to short-circuit these buffers. Full article

Poquoson River is a tidal coastal embayment located along the Western Shore of the Chesapeake Bay about 4 km south of the York River mouth in the City of Poquoson and in York County, Virginia. Its drainage area has diversified land uses, including high densities of residence, agricultural, salt marsh land uses, as well as a National Wildlife Refuge. This embayment experiences elevated bacterial concentration due to excess bacterial inputs from storm water runoff, nonpoint sources, and wash off from marshes due to tide and wind-induced set-up and set-down. Bacteria can also grow in the marsh and small tributaries. It is difficult to use a traditional watershed model to simulate bacterial loading, especially in this low-lying marsh area with abundant wildlife, while runoff is not solely driven by precipitation. An inverse approach is introduced to estimate loading from unknown sources based on observations in the embayment. The estimated loadings were combined with loadings estimated from different sources (human, wildlife, agriculture, pets, etc.) and input to the watershed model. The watershed model simulated long-term flow and bacterial loading and discharged to a three-dimensional transport model driven by tide, wind, and freshwater discharge. The transport model efficiently simulates the transport and fate of the bacterial concentration in the embayment and is capable of determining the loading reduction needed to improve the water quality condition of the embayment. Combining inverse, watershed, and transport models is a sound approach for simulating bacterial transport correctly in the coastal embayment with complex unknown bacterial sources, which are not solely driven by precipitation. Full article

The Chesapeake Bay, the largest estuary in the United States, is rich in natural resources. Its watershed has been impacted by excessive and degraded stormwater runoff from rapid urbanization. We used an empirical approach to investigate how local planning capacity in the Chesapeake Bay watershed affected stream flow. A multiple regression analysis was employed to examine to what extent that the planning factors and other contextual variables were associated with peak runoff. Counterintuitively, we found that sub-basins included in the sample jurisdictions with a relatively high plan quality score tend to generate higher volumes of peak runoff. Results further indicate that specific geographical, basin characteristic, and biophysical factors affected mean annual peak runoff significantly. Overall, our findings highlight the importance of local planning capacity and sustainable stormwater management concepts in mitigating excessive runoff. Full article