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Keywords = Carboniferous strata

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22 pages, 30259 KiB  
Article
Controlling Effects of Complex Fault Systems on the Oil and Gas System of Buried Hills: A Case Study of Beibuwan Basin, China
by Anran Li, Fanghao Xu, Guosheng Xu, Caiwei Fan, Ming Li, Fan Jiang, Xiaojun Xiong, Xichun Zhang and Bing Xie
J. Mar. Sci. Eng. 2025, 13(8), 1472; https://doi.org/10.3390/jmse13081472 - 31 Jul 2025
Viewed by 176
Abstract
Traps are central to petroleum exploration, where hydrocarbons accumulate during migration. Reservoirs are likewise an essential petroleum system element and serve as the primary medium for hydrocarbon storage. The buried hill is a geological formation highly favorable for reservoir development. However, the factors [...] Read more.
Traps are central to petroleum exploration, where hydrocarbons accumulate during migration. Reservoirs are likewise an essential petroleum system element and serve as the primary medium for hydrocarbon storage. The buried hill is a geological formation highly favorable for reservoir development. However, the factors influencing hydrocarbon accumulation in buried hill reservoirs are highly diverse, especially in areas with complex, active fault systems. Fault systems play a dual role, both in the formation of reservoirs and in the migration of hydrocarbons. Therefore, understanding the impact of complex fault systems helps enhance the exploration success rate of buried hill traps and guide drilling deployment. In the Beibuwan Basin in the South China Sea, buried hill traps are key targets for deep-buried hydrocarbon exploration in this faulted basin. The low level of exploration and research in buried hills globally limits the understanding of hydrocarbon accumulation conditions, thereby hindering large-scale hydrocarbon exploration. By using drilling data, logging data, and seismic data, stress fields and tectonic faults were restored. There are two types of buried hills developed in the Beibuwan Basin, which were formed during the Late Ordovician-Silurian period and Permian-Triassic period, respectively. The tectonic genesis of the Late Ordovician-Silurian period buried hills belongs to magma diapirism activity, while the tectonic genesis of the Permian-Triassic period buried hills belongs to reverse thrust activity. The fault systems formed by two periods of tectonic activity were respectively altered into basement buried hills and limestone buried hills. The negative structural inversion controls the distribution and interior stratigraphic framework of the deformed Carboniferous strata in the limestone buried hill. The faults and derived fractures of the Late Ordovician-Silurian period and Permian-Triassic period promoted the diagenesis and erosion of these buried hills. The faults formed after the Permian-Triassic period are not conducive to calcite cementation, thus facilitating the preservation of the reservoir space formed earlier. The control of hydrocarbon accumulation by the fault system is reflected in two aspects: on the one hand, the early to mid-Eocene extensional faulting activity directly controlled the depositional process of lacustrine source rocks; on the other hand, the Late Eocene-Oligocene, which is closest to the hydrocarbon expulsion period, is the most effective fault activity period for connecting Eocene source rocks and buried hill reservoirs. This study contributes to understanding of the role of complex fault activity in the formation of buried hill traps within hydrocarbon-bearing basins. Full article
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24 pages, 28055 KiB  
Article
Sequence Stratigraphic and Geochemical Records of Paleo-Sea Level Changes in Upper Carboniferous Mixed Clastic–Carbonate Successions in the Eastern Qaidam Basin
by Yifan Li, Xiaojie Wei, Kui Liu and Kening Qi
J. Mar. Sci. Eng. 2025, 13(7), 1299; https://doi.org/10.3390/jmse13071299 - 2 Jul 2025
Viewed by 307
Abstract
The Upper Carboniferous strata in the eastern Qaidam Basin, comprising several hundred meters of thick, mixed clastic–carbonate successions that have been little reported or explained, provide an excellent geological record of paleoenvironmental and paleo-sea level changes during the Late Carboniferous icehouse period. This [...] Read more.
The Upper Carboniferous strata in the eastern Qaidam Basin, comprising several hundred meters of thick, mixed clastic–carbonate successions that have been little reported or explained, provide an excellent geological record of paleoenvironmental and paleo-sea level changes during the Late Carboniferous icehouse period. This tropical carbonate–clastic system offers critical constraints for correlating equatorial sea level responses with high-latitude glacial cycles during the Late Paleozoic Ice Age. Based on detailed outcrop observations and interpretations, five facies assemblages, including fluvial channel, tide-dominated estuary, wave-dominated shoreface, tide-influenced delta, and carbonate-dominated marine, have been identified and organized into cyclical stacking patterns. Correspondingly, four third-order sequences were recognized, each composed of lowstand, transgressive, and highstand system tracts (LST, TST, and HST). LST is generally dominated by fluvial channels as a result of river juvenation when the sea level falls. The TST is characterized by tide-dominated estuaries, followed by retrogradational, carbonated-dominated marine deposits formed during a period of sea level rise. The HST is dominated by aggradational marine deposits, wave-dominated shoreface environments, or tide-influenced deltas, caused by subsequent sea level falls and increased debris supply. The sequence stratigraphic evolution and geochemical records, based on carbon and oxygen isotopes and trace elements, suggest that during the Late Carboniferous period, the eastern Qaidam Basin experienced at least four significant sea level fluctuation events, and an overall long-term sea level rise. These were primarily driven by the Gondwana glacio-eustasy and regionally ascribed to the Paleo-Tethys Ocean expansion induced by the late Hercynian movement. Assessing the history of glacio-eustasy-driven sea level changes in the eastern Qaidam Basin is useful for predicting the distribution and evolution of mixed cyclic succession in and around the Tibetan Plateau. Full article
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16 pages, 3653 KiB  
Article
The Origin and Mixed-Source Proportion of Natural Gas in the Dixin Area of the Junggar Basin: Geochemical Insights from Molecular and Isotopic Composition
by Sizhe Deng, Dujie Hou and Wenli Ma
Appl. Sci. 2025, 15(13), 7130; https://doi.org/10.3390/app15137130 - 25 Jun 2025
Viewed by 226
Abstract
The Dixi area of the Junggar Basin has favorable petroleum geological conditions, with the Cretaceous system representing one of the principal hydrocarbon-bearing strata. However, the genetic origin and mixing characteristics of natural gas across different tectonic zones remain insufficiently understood. In this study, [...] Read more.
The Dixi area of the Junggar Basin has favorable petroleum geological conditions, with the Cretaceous system representing one of the principal hydrocarbon-bearing strata. However, the genetic origin and mixing characteristics of natural gas across different tectonic zones remain insufficiently understood. In this study, a total of 65 natural gas samples were analyzed using molecular composition and stable carbon isotopic data to determine gas origins and quantify the contributions of different source rocks. A novel multivariate mathematical analysis method was developed and applied to convert compositional and isotopic data into quantitative parameters, enabling the accurate estimation of end-member mixing ratios in natural gas. This methodological innovation addresses the challenge of interpreting multi-source gas systems under complex geological conditions. The results show that the Cretaceous natural gas in the Dixi area is derived from three main sources, comprising both oil-type gas from Permian lacustrine source rocks and coal-type gas from Carboniferous coal-measure source rocks. The calculated mixing proportions exhibit significant spatial variation: in the northern Dixi area, coal-type gas dominates (67.8–84.3%), while the southern zone presents a broader mixture (25.6–68.4% coal-type gas). In the Dongdaohaizi Depression, oil-type gas is predominant, accounting for 89.4–97.7%. This study not only clarifies the genetic classification and mixing dynamics of natural gas in the Dixi area but also provides a quantitative framework for evaluating accumulation processes and source contributions in multi-source gas reservoirs. The proposed method offers valuable guidance for assessing resources and optimizing exploration strategies in the Junggar Basin and other similar basins. Full article
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15 pages, 5879 KiB  
Article
The Mineralization Mechanism of the Axi Gold Deposit in West Tianshan, NW China: Insights from Fluid Inclusion and Multi-Isotope Analyses
by Fang Xia, Chuan Chen and Weidong Sun
Minerals 2025, 15(5), 536; https://doi.org/10.3390/min15050536 - 18 May 2025
Viewed by 467
Abstract
The Axi gold deposit, which is located in the Tulasu Basin of the West Tianshan orogenic belt in Northwest China, features vein-type ore bodies hosted in radial structural fractures formed due to volcanic activity. The deposit experienced three distinct mineralization stages: Stage I, [...] Read more.
The Axi gold deposit, which is located in the Tulasu Basin of the West Tianshan orogenic belt in Northwest China, features vein-type ore bodies hosted in radial structural fractures formed due to volcanic activity. The deposit experienced three distinct mineralization stages: Stage I, characterized by the microcrystalline quartz–pyrite crust; Stage II, characterized by quartz–sulfide–native gold veins; and Stage III, characterized by quartz–carbonate veins. Fluid inclusion studies have identified four types of inclusions: pure vapor, vapor-rich, liquid-rich, and pure liquid. The number of vapor-rich inclusions decreases when moving from Stage I to Stage III, whereas the number of liquid-rich inclusions increases. The fluid temperature gradually decreases from 178–225 °C in Stage I to 151–193 °C in Stage II and further to 123–161 °C in Stage III, whereas the fluid salinity decreases slightly from 2.1%–5.1% wt.% NaCl eqv to 1.4%–4.6% wt.% NaCl eqv and finally to 0.5%–3.7% wt.% NaCl eqv. As suggested by the results of the oxygen, hydrogen, and carbon isotope analyses, the ore-forming fluids were primarily meteoric water. Sulfur isotopic compositions indicate a single deep mantle source. The lead isotopic compositions closely resemble those of Dahalajunshan Formation volcanic rocks, indicating that these rocks were the primary source of the ore-forming material. In addition, gold mineralization formed in a Devonian–Early Carboniferous volcanic arc environment. Element enrichment was mainly caused by the circulation of heated meteoric water through the volcanic strata, while fluid boiling and water–rock interactions were the main mechanisms driving element precipitation. The integrated model developed in this study underscores the intricate interplay between volcanic processes and meteoric fluids during the formation of the Axi gold deposit, offering a robust framework for an understanding of the formation processes and enhancing the predictive exploration models in analogous geological settings. Full article
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17 pages, 3398 KiB  
Article
Multilayer Gas-Bearing System and Productivity Characteristics in Carboniferous–Permian Tight Sandstones: Taking the Daning–Jixian Block, Eastern Ordos Basin, as an Example
by Ming Chen, Bo Wang, Haonian Tian, Junyi Sun, Lei Liu, Xing Liang, Benliang Chen, Baoshi Yu and Zhuo Zhang
Energies 2025, 18(9), 2398; https://doi.org/10.3390/en18092398 - 7 May 2025
Viewed by 414
Abstract
The Carboniferous–Permian strata in the Daning–Jixian Block, located on the eastern edge of the Ordos Basin, host multiple sets of tight gas reservoirs. However, systematic research on the characteristics and gas production differences of multilayer tight sandstone gas-bearing systems remains limited. Based on [...] Read more.
The Carboniferous–Permian strata in the Daning–Jixian Block, located on the eastern edge of the Ordos Basin, host multiple sets of tight gas reservoirs. However, systematic research on the characteristics and gas production differences of multilayer tight sandstone gas-bearing systems remains limited. Based on geochemical signatures, reservoir pressure coefficients, and sequence stratigraphy, the tight sandstone gas systems are subdivided into upper and lower systems, separated by regionally extensive Taiyuan Formation limestone. The upper system is further partitioned into four subsystems. Depositional variability from the Benxi Formation to the He 8 Member has generated diverse litho-mineralogical characteristics. The Shan 1 and He 8 Members, deposited in low-energy delta-front subaqueous distributary channels with gentle topography, exhibit lower quartz content (predominantly feldspar lithic sandstone and lithic quartz sand-stone) and elevated lithic fragments, matrix, and clay minerals (particularly chlorite). These factors increase displacement and median pressures, resulting in inferior reservoir quality. By comparing and evaluating the gas production effects under different extraction methods, targeted optimization recommendations are provided to offer both theoretical support and practical guidance for the efficient development of this block. Full article
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20 pages, 7195 KiB  
Article
Bitumen Characteristics, Genesis, and Hydrocarbon Significance in Paleozoic Reservoirs: A Case Study in the Kongxi Slope Zone, Dagang Oilfield, Huanghua Depression
by Da Lou, Yingchang Cao and Xueyu Han
Minerals 2025, 15(5), 443; https://doi.org/10.3390/min15050443 - 25 Apr 2025
Viewed by 267
Abstract
The Paleozoic strata in the Kongxi slope zone of the Dagang oilfield, Huanghua depression, exhibit significant hydrocarbon exploration potential. Although bitumen is widely present in the Paleozoic reservoirs, its formation process and genetic mechanism remain poorly understood. This study systematically investigates the occurrence, [...] Read more.
The Paleozoic strata in the Kongxi slope zone of the Dagang oilfield, Huanghua depression, exhibit significant hydrocarbon exploration potential. Although bitumen is widely present in the Paleozoic reservoirs, its formation process and genetic mechanism remain poorly understood. This study systematically investigates the occurrence, maturity, origin, and evolutionary processes of Paleozoic reservoir bitumen in the Kongxi zone through core observations, microscopic analyses, geochemical testing, and thermal simulation experiments. The results reveal that reservoir bitumen in the Kongxi slope zone is characteristically black with medium to medium-high maturity. In core samples, bitumen occurs as bands, veins, lines, and dispersions within partially filled fractures and breccia pores. Petrographic analysis shows bitumen partially occupying intergranular pores and intergranular pores of Lower Paleozoic carbonate rocks and Upper Paleozoic sandstones, either as complete or partial pore fills. Additional bitumen occurrences include strip-like deposits along microfractures and as bitumen inclusions. Dark brown bitumen fractions were also identified in crude oil separates. The formation and evolution of Paleozoic reservoir bitumen in the Kongxi slope zone occurred in two main stages. The first-stage bitumen originated from Ordovician marine hydrocarbon source rocks, subsequently undergoing oxidative water washing and biodegradation during tectonic uplift stage. This bitumen retains compositional affinity with crude oils from Lower Paleozoic carbonate rocks. Second-stage bitumen formed through the thermal evolution of Carboniferous crude oil during deeper burial, showing compositional similarities with Carboniferous source rocks and their oil. This two-stage bitumen evolution indicates charging events in the Paleozoic reservoirs. While early uplift and exposure destroyed some paleo-reservoirs, unexposed areas within the Dagang oilfield may still contain preserved primary accumulations. Furthermore, second-stage hydrocarbon, dominated condensates derived from Carboniferous coal-bearing sequences since the Eocene, experienced limited thermal evolution to form some bitumen. These condensate accumulations remain the primary exploration target in the Paleozoic Formations. Full article
(This article belongs to the Special Issue Organic Petrology and Geochemistry: Exploring the Organic-Rich Facies)
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30 pages, 9041 KiB  
Article
Pore–Fracture Structure and Fractal Features of Carboniferous Taiyuan Formation Hydrocarbon Source Rocks as Investigated Using MICP, LFNMR, and FESEM
by Dun Wu, Liu Zhao, Guangqing Hu and Wenyong Zhang
Fractal Fract. 2025, 9(4), 263; https://doi.org/10.3390/fractalfract9040263 - 20 Apr 2025
Viewed by 456
Abstract
The pore structure of reservoir rocks was a crucial factor affecting hydrocarbon production. Accurately characterized the micropore structure of different types of rock reservoirs was of great significance for unconventional natural gas exploration. In this study, multiple observation methods (field emission scanning electron [...] Read more.
The pore structure of reservoir rocks was a crucial factor affecting hydrocarbon production. Accurately characterized the micropore structure of different types of rock reservoirs was of great significance for unconventional natural gas exploration. In this study, multiple observation methods (field emission scanning electron microscope (FESEM) and low-field nuclear magnetic resonance (LFNMR)) and physical tests (mercury injection capillary pressure (MICP)) were employed, and double logarithmic plots for fractal fitting were illustrated. The fractal dimension of 15 samples was calculated using fractal theory to systematically investigate the pore–fracture structure and fractal characteristics of hydrocarbon source rock (limestone, mudstone, and sandstone) samples from the Late Carboniferous Taiyuan Formation in the Huainan coalfield. MICP experiments revealed that sandstone reservoirs had larger and more uniformly distributed pore throats compared to mudstone and limestone, exhibiting superior connectivity and permeability. The T2 spectrum characteristic maps obtained using LFNMR were also consistent with the pore distribution patterns derived from MICP experiments, particularly showed that sandstone types exhibited excellent signal intensity across different relaxation time periods and had a broader T2 spectrum width, which fully indicated that sandstone types possess superior pore structures and higher connectivity. FESEM experiments demonstrated that sandstone pores were highly developed and uniform, with sandstone fractures dominated by large fractures above the micrometer scale. Meanwhile, the FESEM fractal dimension results indicated that sandstone exhibits good fractal characteristics, validating its certain oil storage capacity. Furthermore, the FESEM fractal dimension exhibited a good correlation with the porosity and permeability of the hydrocarbon source rock reservoirs, suggesting that the FESEM fractal dimension can serve as an important parameter for evaluating the physical properties of hydrocarbon source rock reservoirs. This study enriched the basic geological theories for unconventional natural gas exploration in deep coal-bearing strata in the Huainan coalfield. Full article
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23 pages, 5902 KiB  
Article
Combining Fourier Transform Infrared and Raman Spectroscopy to Characterize Kerogen Molecular Structures: Insights into Their Thermal Maturity
by Dun Wu, Chenglong Wang, Wenxu Liang and Xia Gao
Int. J. Mol. Sci. 2025, 26(6), 2696; https://doi.org/10.3390/ijms26062696 - 17 Mar 2025
Cited by 1 | Viewed by 703
Abstract
This study systematically analyzed the composition of organic functional groups and changes in the carbon structure of kerogen at different stages of thermal maturity using Fourier Transform Infrared (FTIR) spectroscopy and Laser Raman spectroscopy techniques. The research selected oil shale samples from the [...] Read more.
This study systematically analyzed the composition of organic functional groups and changes in the carbon structure of kerogen at different stages of thermal maturity using Fourier Transform Infrared (FTIR) spectroscopy and Laser Raman spectroscopy techniques. The research selected oil shale samples from the Late Carboniferous deep coal strata in the southern part of the Huainan coalfield. Kerogen was extracted through acid treatment, pyrite removal, and heavy liquid separation processes. Utilizing FTIR and Raman spectroscopy, the study delved into the quantitative and qualitative characteristics of functional groups such as hydroxyl, carboxyl, and methyl in the kerogen, as well as the variations in the ratio between aliphatic and aromatic carbon. The research found that as thermal maturity increased, aromatic structural parameters in the kerogen significantly rose, while aliphatic structural parameters exhibited a downward trend. Specifically, FTIR spectroscopy was used to identify the characteristic absorption wavenumber ranges of different functional groups and calculate key parameters such as the aromaticity of the kerogen and the ratio of aliphatic to aromatic functional groups using relevant formulas. Meanwhile, Raman spectroscopy analysis revealed changes in the orderliness of carbon atoms and the degree of graphitization in the kerogen as a function of thermal maturity, with the intensity ratio of the G band to the D1 band (AD1/AG) emerging as an important indicator for assessing thermal maturity. Additionally, this study further validated the correlation between thermal maturity and parameters such as reflectance (R0) and the H/C ratio by calculating the metamorphic temperature of the kerogen. Combining the results of FTIR and Raman spectroscopy analyses, this study unveiled a close relationship between the thermal maturity of kerogen and its organic functional group composition and carbon structure. As thermal maturity increased, the degree of aromatization in the kerogen rose, aliphatic chain lengths shortened, and the degree of graphitization improved. These findings not only enhance the understanding of the thermal evolution process of kerogen but also provide crucial scientific insights for oil and gas exploration and development. Full article
(This article belongs to the Section Physical Chemistry and Chemical Physics)
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28 pages, 2517 KiB  
Article
Petrography and Geochemistry of Lower Jurassic Sandstones in the Eastern Junggar Basin: Implications for Provenance and Tectonic Setting
by Furong Li, Zhi Zhang, Can Zhao, Jinqi Han, Jiaye Liu, Yaoyun Guo, Xinyu Tang, Chang Su, Xu Chang and Tong Wu
Minerals 2025, 15(3), 279; https://doi.org/10.3390/min15030279 - 9 Mar 2025
Viewed by 1145
Abstract
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of [...] Read more.
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of the Lower Jurassic Badaowan Formation sandstones in the Dongdaohaizi Depression, located in the eastern Junggar Basin. The results reveal a progressive decrease in lithic fragment content and an increase in quartz content from older to younger strata within the Badaowan Formation, indicating an increase in compositional maturity. Provenance analysis indicates that the sandstones are predominantly derived from tuffaceous rocks, granites, basalts, and minor metamorphic rocks. Heavy mineral assemblages, including zircon, chromian spinel, tourmaline, and garnet, suggest parent rocks consisting primarily of intermediate to acidic igneous rocks, mafic igneous rocks, and metamorphic rocks. Integrated petrographic and geochemical data from the surrounding areas of the Dongdaohaizi Depression confirm that the Badaowan Formation sandstones are primarily sourced from the eastern Kelameili Mountain. The continued uplift and migration of the Kelameili Mountain during the Early Jurassic played a dominant role in shaping the sedimentary provenance. LA-ICP-MS analyses reveal that the rare earth element (REE) concentrations in the Lower Jurassic sandstones are slightly lower than the average REE content of the upper continental crust. The sandstones exhibit weak differentiation between light and heavy REEs, reflecting a depositional environment characterized by anoxic reducing conditions. Geochemical results indicate a tectonic setting dominated by a passive continental margin and continental island arc in the source area. Synthesizing these findings with related studies, we propose that the Kelameili Ocean, as part of the Paleo-Asian Ocean, underwent a complex evolution involving multiple oceanic basins and microcontinental subduction–collision systems. From the Middle Ordovician to Late Silurian, the Kelameili region evolved as a passive continental margin. With the onset of subduction during the Middle Devonian to Early Carboniferous, the eastern Junggar Basin transitioned into a continental island arc system. This tectonic transition was likely driven by episodic or bidirectional subduction of the Kelameili Ocean. Full article
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21 pages, 3815 KiB  
Article
Paleoenvironmental Controls and Economic Potential of Li-REY Enrichment in the Upper Carboniferous Coal-Bearing “Si–Al–Fe” Strata, Northeastern Qinshui Basin
by Ning Wang, Jun Zhao, Yingxia Xu, Mangen Mu, Shangqing Zhang, Libo Jing, Guoshu Huang, Liang Liu and Pengfei Tian
Minerals 2025, 15(3), 269; https://doi.org/10.3390/min15030269 - 5 Mar 2025
Viewed by 709
Abstract
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, [...] Read more.
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, and rare earth elements and Y (REY or REE + Y), have been discovered, with notable mineralization anomalies observed across northern, central, and southern Shanxi Province. However, despite the widespread occurrence of outcrops of the “Si–Al–Fe” strata in the northeastern Qinshui Basin of eastern Shanxi, there has been no prior report on the critical metal content in this region. Traditionally, the “Si–Al–Fe” strata have been regarded as a primary source of clastic material for the surrounding coal seams of the Carboniferous–Permian Taiyuan and Shanxi Formations, which are known to display critical metal anomalies (e.g., Li and Ga). Given these observations, it is hypothesized that the “Si–Al–Fe” strata in the northeastern Qinshui Basin may also contain critical metal mineralization. To evaluate this hypothesis, new outcrop samples from the “Si–Al–Fe” strata of the Benxi Formation in the Yangquan area of the northeastern Qinshui Basin were collected. Detailed studies on critical metal enrichment were assessed using petrographic observations, mineralogy (XRD, X-ray diffractometer), and geochemistry (XRF, X-ray fluorescence spectrometer, and ICP-MS, inductively coupled plasma mass spectrometer). The results indicate that the siliceous, ferruginous, and aluminous rocks within the study strata exhibit varying degrees of critical metal mineralization, mainly consisting of Li and REY, with minor associated Nb, Zr, and Ga. The Al2O3/TiO2, Nb/Y vs. Zr/TiO2, and Nb/Yb vs. Al2O3/TiO2 diagrams suggest that these critical metal-enriched layers likely have a mixed origin, comprising both intermediate–felsic magmatic rocks and metamorphic rocks derived from the NCC, as well as alkaline volcaniclastics associated with the Tarim Large Igneous Province (TLIP). Furthermore, combined geochemical parameters, such as the CIA (chemical index of alteration), Sr/Cu vs. Ga/Rb, Th/U, and Ni/Co vs. V/(V + Ni), indicate that the “Si–Al–Fe” strata in the northeastern Qinshui Basin were deposited under warm-to-hot, humid climate conditions, likely in suboxic-to-anoxic environments. Additionally, an economic evaluation suggests that the “Si–Al–Fe” strata in the northeastern Qinshui Basin hold considerable potential as a resource for the industrial extraction of Li, REY, Nb, Zr, and Ga. Full article
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26 pages, 20446 KiB  
Article
Gas Content and Geological Control of Deep Jurassic Coalbed Methane in Baijiahai Uplift, Junggar Basin
by Bing Luo, Haichao Wang, Bin Sun, Zheyuan Ouyang, Mengmeng Yang, Yan Wang and Xiang Zhou
Processes 2024, 12(12), 2671; https://doi.org/10.3390/pr12122671 - 27 Nov 2024
Cited by 1 | Viewed by 1088
Abstract
Deep coalbed methane (CBM) resources are abundant in China, and in the last few years, the country’s search for and extraction of CBM have intensified, progressively moving from shallow to deep strata and from high-rank coal to medium- and low-rank coal. On the [...] Read more.
Deep coalbed methane (CBM) resources are abundant in China, and in the last few years, the country’s search for and extraction of CBM have intensified, progressively moving from shallow to deep strata and from high-rank coal to medium- and low-rank coal. On the other hand, little is known about the gas content features of deep coal reservoirs in the eastern Junggar Basin, especially with regard to the gas content and the factors that affect it. Based on data from CBM drilling, logging, and seismic surveys, this study focuses on the gas content of Baijiahai Uplift’s primary Jurassic coal seams through experiments on the microscopic components of coal, industrial analysis, isothermal adsorption, low-temperature CO2, low-temperature N2, and high-pressure mercury injection. A systematic investigation of the controlling factors, including the depth, thickness, and quality of the coal seam and pore structure; tectonics; and lithology and thickness of the roof, was conducted. The results indicate that the Xishanyao Formation in the Baijiahai Uplift usually has a larger gas content than that in the Badaowan Formation, with the Xishanyao Formation showing that free gas and adsorbed gas coexist, while the Badaowan Formation primarily consists of adsorbed gas. The coal seams in the Baijiahai Uplift are generally deep and thick, and the coal samples from the Xishanyao and Badawan formations have a high vitrinite content, which contributes to their strong gas generation capacity. Additionally, low moisture and ash contents enhance the adsorption capacity of the coal seams, facilitating the storage of CBM. The pore-specific surface area of the coal samples is primarily provided by micropores, which is beneficial for CBM adsorption. Furthermore, a fault connecting the Carboniferous and Permian systems (C-P) developed in the northeastern part of the Baijiahai Uplift allows gas to migrate into the Xishanyao and Badaowan formations, resulting in a higher gas content in the coal seams. The roof lithology is predominantly mudstone with significant thickness, effectively reducing the dissipation of coalbed methane and promoting its accumulation. Full article
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26 pages, 4220 KiB  
Review
Review of the Fossil Heritage Potential of Shenzhen (Guangdong, China): A Promising Area for Palaeontological Research
by David Marius Kroeck, Yanxin Gong, He Chen, Lan Li and Tong Bao
Geosciences 2024, 14(12), 316; https://doi.org/10.3390/geosciences14120316 - 22 Nov 2024
Viewed by 1102
Abstract
The area of the city of Shenzhen at the Pearl River Delta in Guangdong Province, China, comprises rocks that preserve, with few interruptions, around 1.8 billion years of geological history. However, to date, only few scientific studies within a palaeontological context have been [...] Read more.
The area of the city of Shenzhen at the Pearl River Delta in Guangdong Province, China, comprises rocks that preserve, with few interruptions, around 1.8 billion years of geological history. However, to date, only few scientific studies within a palaeontological context have been conducted on the sediment rocks in Shenzhen. Herein, the fossil record and heritage potential of Shenzhen is reviewed. The few existing previous investigations revealed a rich terrestrial and marine fossil record and show the great potential of this area for future palaeontological research, particularly on the upper Palaeozoic and Mesozoic strata: Carboniferous successions show plant remains and a diverse benthic marine fauna; fossils from Upper Triassic–Middle Jurassic sediment rocks provide important data for terrestrial and marine palaeoecosystems of this time; and the discovery of dinosaur nests in the Upper Cretaceous strata complements the previously known distribution of dinosaurs in South China. Additionally, micropalaeontological and palynological data from the upper Palaeozoic as well as Cenozoic successions in Shenzhen reveal diverse assemblages of foraminifera, ostracods, diatoms, and sporomorphs. Moreover, fossil finds in equivalent rocks in adjacent areas indicate great potential for the units in the Shenzhen area, in which, so far, no fossils have been found. Full article
(This article belongs to the Section Geoheritage, Geoparks and Geotourism)
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20 pages, 4913 KiB  
Article
Provenance and Paleo-Environment of the Late Carboniferous Bauxite Formations in Southern Shanxi
by Dongna Liu, Wenjie Jia, Fenghua Zhao, Rongrong Li, Shangqing Zhang, Jun Zhao and Ning Li
Appl. Sci. 2024, 14(22), 10358; https://doi.org/10.3390/app142210358 - 11 Nov 2024
Viewed by 1246
Abstract
The Carboniferous Benxi Formation in southern Shanxi of North China has significant bauxite resource potential; however, the source of its metallogenic material and its sedimentary environment remain unclear. The microscopy, X-ray diffraction, X-ray fluorescence spectroscopy, and inductively coupled plasma mass spectrometry methods were [...] Read more.
The Carboniferous Benxi Formation in southern Shanxi of North China has significant bauxite resource potential; however, the source of its metallogenic material and its sedimentary environment remain unclear. The microscopy, X-ray diffraction, X-ray fluorescence spectroscopy, and inductively coupled plasma mass spectrometry methods were applied in this study to examine the mineralogical, petrographic, and geochemical characteristics. Geochemical proxies of La/Y, Sr/Ba, Al2O3/TiO2, Zr/Sc, Th/Sc, La/Sc, and Th/Co were analyzed to investigate the paleo-depositional environment and provenance of the aluminum-bearing strata. The findings indicate that diaspores are the primary ore minerals in bauxite, while kaolinite and rutile are the predominant gangue minerals. Both the bauxite and claystone/aluminous rocks exhibit high enrichment in Li, Bi, and U, with relative enrichment in In, Sb, Th, Nb, and Ta. Li is notably concentrated in the claystone/aluminous rocks, reaching up to 1994.00 μg/g, primarily occurring in cookeite and boehmite, while U is highly concentrated in the bauxite. The aluminum-bearing strata were primarily formed under alkaline-reducing conditions, with changes in acidity and alkalinity of the environment during the sedimentary diagenetic process. Marine transgressions significantly impacted the sedimentary environment of the aluminum-bearing strata, and the paleoclimate was characterized as hot and humid. The principal factors contributing to enrichment of aluminum in the sedimentary basin were the in situ weathering of aluminum-rich source rocks and the transport of clastic materials from high-aluminum source rocks. The source rocks were closely associated with intermediate-acidic magmatic rocks and potentially related to the weathering of Ordovician carbonates. Full article
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22 pages, 26818 KiB  
Article
Depositional Environment and Ecological Response of Bioconstructions: A Case Study of Southern China (Guizhou Province) in Moscovian–Gzhelian
by Xiao Li, Enpu Gong, Yongli Zhang, Changqing Guan and Wentao Huang
Life 2024, 14(9), 1150; https://doi.org/10.3390/life14091150 - 11 Sep 2024
Viewed by 1056
Abstract
From the late Carboniferous to the early Permian, multiple pulses of glaciation and deglaciation have been caused by the LPIA. The Pennsylvanian period experienced phases of recovery, proliferation, and decline, ultimately forming a reef system distinctly different from that of the Mississippian period. [...] Read more.
From the late Carboniferous to the early Permian, multiple pulses of glaciation and deglaciation have been caused by the LPIA. The Pennsylvanian period experienced phases of recovery, proliferation, and decline, ultimately forming a reef system distinctly different from that of the Mississippian period. During the late Bashkirian to Moscovian, the metazoan reef experienced a limited resurgence, with reef predominantly formed by chaetetid developing in the United States, northern China, and Japan. During the Kasimovian to Gzhelian, the phylloid algal reef dominated the global reef systems. In the late Pennsylvanian, bioconstruction cases and paleoenvironmental proxies in southern Guizhou Province were studied to investigate the composition, recovery, and evolutionary processes of the bioconstructions as well as their response to environmental variations during this period. Several bioconstructions have been reported in the Lumazhai section of Houchang Town, Guizhou Province, southern China, from the Moscovian to the Gzhelian. The upper Carboniferous strata are well-preserved and continuously exposed. The continuous strata, abundant fossils, and diverse bioconstructions provide excellent research materials for exploring the mutual constraints between organisms and their environment. This study identified ten microfacies, whose vertical evolution indicated significant changes in the depositional environment related to relative sea-level fluctuations. Skeletal grains are widely present in these facies. Among them, foraminifera, algae, bryozoans, crinoids, and Tubiphytes are the most common and exhibit distinct distribution characteristics in various environments. Quantitative statistics, CCA and theoretical ecospace have been utilized to examine and interpret environmental impact factors. Quantitative analysis of their relative abundance and distribution patterns provides insights into the complex interactions between organisms and environmental factors. The relative abundances of different organisms and factors controlling their bioconstructions are influenced by relative sea-level changes. CCA analysis reveal that hydrodynamic conditions are the primary influencing factor. Variation trends in average tiering and motility reveal the characteristics of biological communities during environmental changes in phylloid algae and microbial bioconstructions. These bioconstructions are not directly correlated with changes in environmental factors, and the biological communities in phylloid algae mounds and biostromes exhibit similar organism compositions and ecological niches across different environments. Full article
(This article belongs to the Section Paleobiology)
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26 pages, 17778 KiB  
Article
Occurrence and Favorable Enrichment Environment of Lithium in Gaoping Coal Measures: Evidence from Mineralogy and Geochemistry
by Peiliang Han, Fenghua Zhao, Dongna Liu, Qi Zhang, Qinqin Zhang and Shaheed Ullah
Appl. Sci. 2024, 14(16), 7298; https://doi.org/10.3390/app14167298 - 19 Aug 2024
Cited by 3 | Viewed by 1100
Abstract
The Carboniferous-Permian coal measure strata in the Qinshui Basin exhibit highly lithium (Li) enrichment, with substantial exploitation potential. To further explore the enrichment mechanism of lithium in coal measure strata, the No. 15 coal of the Taiyuan Formation from the Gaoping mine is [...] Read more.
The Carboniferous-Permian coal measure strata in the Qinshui Basin exhibit highly lithium (Li) enrichment, with substantial exploitation potential. To further explore the enrichment mechanism of lithium in coal measure strata, the No. 15 coal of the Taiyuan Formation from the Gaoping mine is taken as the research object, and its mineralogical and geochemistry characteristics are evaluated using optical microscopy, X-ray diffraction, scanning electron microscopy, inductively coupled plasma mass spectrometry, X-ray fluorescence, and infrared spectral. The results show that the No. 15 coal is semi-anthracite coal with low moisture, low ash, low volatility, and high sulfur. Organic macerals are primarily vitrinite, followed by inertinite, and liptinite is rare; the inorganic macerals (ash) are dominated by clay minerals (predominantly kaolinite, cookeite, illite, and NH4-illite), calcite, pyrite, quartz, siderite, gypsum, and zircon. The average Li content in the coal is 66.59 μg/g, with higher content in the coal parting (566.00 μg/g) and floor (396.00 μg/g). Lithium in coal occurs primarily in kaolinite, illite, cookeite, and is closely related to titanium-bearing minerals. In addition, Li in organic maceral may occur in liptinite. The No. 15 coal was formed in the coastal depositional system, and the deposition palaeoenvironment is primarily a wet–shallow water covered environment in open swamp facies; the plant tissue preservation index is poor, and aquatic or herbaceous plants dominate the plant type. The reducing environment with more terrestrial detritus, an arid climate, and strong hydrodynamic effects is favorable for Li enrichment in coal. The results have important theoretical significance for exploring the enrichment and metallogenic mechanisms of Li in coal. Full article
(This article belongs to the Section Earth Sciences)
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