Search Results (10)

The construction of marine ranching is a crucial component of China’s Blue Granary strategy, yet the fragmented knowledge system in marine ranching equipment impedes intelligent management and operational efficiency. This study proposes the first knowledge graph (KG) framework tailored for marine ranching equipment, integrating hybrid ontology design, joint entity–relation extraction, and graph-based knowledge storage: (1) The limitations in existing KG are obtained through targeted questionnaires for diverse users and employees; (2) A domain ontology was constructed through a combination of the top-down and the bottom-up approach, defining seven key concepts and eight semantic relationships; (3) Semi-structured data from enterprises and standards, combined with unstructured data from the literature were systematically collected, cleaned via Scrapy and regular expression, and standardized into JSON format, forming a domain-specific corpus of 1456 annotated sentences; (4) A novel BERT-BiGRU-CRF model was developed, leveraging contextual embeddings from BERT, parameter-efficient sequence modeling via BiGRU (Bidirectional Gated Recurrent Unit), and label dependency optimization using CRF (Conditional Random Field). The TE + SE + R_i + BMESO tagging strategy was introduced to address multi-relation extraction challenges by linking theme entities to secondary entities; (5) The Neo4j-based KG encapsulated 2153 nodes and 3872 edges, enabling scalable visualization and dynamic updates. Experimental results demonstrated superior performance over BiLSTM-CRF and BERT-BiLSTM-CRF, achieving 86.58% precision, 77.82% recall, and 81.97% F1 score. This study not only proposes the first structured KG framework for marine ranching equipment but also offers a transferable methodology for vertical domain knowledge extraction. Full article

This work is devoted to the fabrication of p-type polyvinyl alcohol (PVA)-based flexible thermoelectric composites using multiwall carbon nanotubes-antimony telluride (MWCNT-Sb₂Te₃) hybrid filler, the study of the thermoelectrical and mechanical properties of these composites, and the application of these composites in two types (planar and radial) of thermoelectric generators (TEG) in combination with the previously reported PVA/MWCNT-Bi₂Se₃ flexible thermoelectric composites. While the power factors of PVA/MWCNT-Sb₂Te₃ and PVA/MWCNT-Bi₂Se₃ composites with 15 wt.% filler were found to be similar, the PVA/MWCNT-Sb₂Te₃ composite with 25 wt.% filler showed a ~2 times higher power factor in comparison with the PVA/MWCNT-Bi₂Se₃ composites with 30 wt.% filler, which is attributed to its reduced electrical resistivity. In addition, developed PVA/MWCNT-Sb₂Te₃ composites showed a superior mechanical, electrical, and thermoelectric stability during 100 consequent bending cycles down to a 3 mm radius, with insignificant fluctuations of the resistance within 0.01% of the initial resistance value of the not bent sample. Demonstrated for the first time, 2-leg TEGs composed from p-type PVA/MWCNT-Sb₂Te₃ and n-type PVA/MWCNT-Bi₂Se₃ composites showed a stable performance under different external loads and showed their potential for applications involving low temperature gradients and power requirements in the range of nW. Full article

We investigate the phenomenon of quantum interference in spontaneous emission for a three-level V-type quantum emitter placed between two bismuth-chalcogenide (Bi${}_2$Te${}_3$, Bi${}_2$Se${}_3$) microspheres. In particular, we find that the degree of quantum interference can become as high as 0.994, a value which is attributed to the strong dependence of the spontaneous emission rate on the orientation of an atomic dipole relative to the surfaces of the microspheres, at the excitation frequencies of phonon-polariton states of the bismuth-chalcogenide microspheres (anisotropic Purcell effect). As a consequence of the high degree of quantum interference, we observe the occurrence of strong population trapping in the quantum emitter. To the best of our knowledge, the reported values of the degree of quantum interference are record values and are obtained for a relatively simple geometrical setup such as that of a microparticle dimer. Full article

This paper reports first-principles calculations on PbBi${}_2$Te${}_2$S${}_2$, PbBi${}_2$Te${}_2$Se${}_2$ and PbBi${}_2$Te${}_4$ monolayers. The strain effects on their electronic and thermoelectric properties as well as on their stability have been investigated. Without strain, the PbBi${}_2$Te${}_4$ monolayer exhibits highest Seebeck coefficient with a maximum value of 671 $\mathsf{\mu }$V/K. Under tensile strain the highest power factor are $12.38\times {10}^{11}$ Wm${}^{-1}$K${}^{-2}$s${}^{-1}$, $10.74\times {10}^{11}$ Wm${}^{-1}$K${}^{-2}$s${}^{-1}$ and $6.51\times {10}^{11}$ Wm${}^{-1}$K${}^{-2}$s${}^{-1}$ for PbBi${}_2$Te${}_2$S${}_2$, PbBi${}_2$Te${}_2$Se${}_2$ and PbBi${}_2$Te${}_4$ at 3%, 2% and 1% tensile strains, respectively. These values are 85.9%, 55.0% and 3.3% larger than those of the unstrained structures. Full article

The massive sulfide ores of the Pobeda hydrothermal fields are grouped into five main mineral microfacies: (1) isocubanite-pyrite, (2) pyrite-wurtzite-isocubanite, (3) pyrite with minor isocubanite and wurtzite-sphalerite microinclusions, (4) pyrite-rich with framboidal pyrite, and (5) marcasite-pyrite. This sequence reflects the transition from feeder zone facies to seafloor diffuser facies. Spongy, framboidal, and fine-grained pyrite varieties replaced pyrrhotite, greigite, and mackinawite “precursors”. The later coarse and fine banding oscillatory-zoned pyrite and marcasite crystals are overgrown or replaced by unzoned subhedral and euhedral pyrite. In the microfacies range, the amount of isocubanite, wurtzite, unzoned euhedral pyrite decreases versus an increasing portion of framboidal, fine-grained, and spongy pyrite and also marcasite and its colloform and radial varieties. The trace element characteristics of massive sulfides of Pobeda seafloor massive sulfide (SMS) deposit are subdivided into four associations: (1) high temperature—Cu, Se, Te, Bi, Co, and Ni; (2) mid temperature—Zn, As, Sb, and Sn; (3) low temperature—Pb, Sb, Ag, Bi, Au, Tl, and Mn; and (4) seawater—U, V, Mo, and Ni. The high contents of Cu, Co, Se, Bi, Te, and values of Co/Ni ratios decrease in the range from unzoned euhedral pyrite to oscillatory-zoned and framboidal pyrite, as well as to colloform and crystalline marcasite. The trend of Co/Ni values indicates a change from hydrothermal to hydrothermal-diagenetic crystallization of the pyrite. The concentrations of Zn, As, Sb, Pb, Ag, and Tl, as commonly observed in pyrite formed from mid- and low-temperature fluids, decline with increasing crystal size of pyrite and marcasite. Coarse oscillatory-zoned pyrite crystals contain elevated Mn compared to unzoned euhedral varieties. Framboidal pyrite hosts maximum concentrations of Mo, U, and V probably derived from ocean water mixed with hydrothermal fluids. In the Pobeda SMS deposit, the position of microfacies changes from the black smoker feeder zone at the base of the ore body, to seafloor marcasite-pyrite from diffuser fragments in sulfide breccias. We suggest that the temperatures of mineralization decreased in the same direction and determined the zonal character of deposit. Full article

In the paper, the results of an investigation into trace elements found in slag sulfides from 14 archaeological Bronze Age settlements of the Cis-Urals, Trans-Urals, and North and Central Kazakhstan are presented. The study used Cu-(Fe)-sulfides as indicator minerals. Cu-(Fe)-S minerals in slags are primarily represented by covellite and chalcocite, as well as by rarer bornite and single chalcopyrite grains. Slag sulfides formed relic clasts and neogenic droplets of different shapes and sizes. Supergenic ores in the Bronze Age in Urals and Kazakhstan played a significant role in the mineralogical raw material base. In sulfides, the main indicator elements, Fe, Co, Ni, As, Se, Te, Sb, Ag, Pb, and Bi, are important markers of copper deposit types. Sulfides from olivine Cr-rich spinel containing slags of Ustye, Turganik are characterized by As-Co-Ni high contents and confined to copper deposits in ultramafic rocks. Olivine sulfide-containing slags from Kamenny Ambar, Konoplyanka and Sarlybay 3 are characterized by Co-Se-Te assemblage and confined to mafic rocks. Glassy sulfide-containing slags from Katzbakh 6, Turganik, Ordynsky Ovrag, Ivanovskoe, Tokskoe, Bulanovskoe 2, Kuzminkovskoe 2, Pokrovskoe, Rodnikovoe, and Taldysay are characterized by Ag-Pb-(Ba)-(Bi) assemblage and confined to cupriferous sandstone deposits. High As, Sb, Sn, and Ba contents found in slags can be seen as indicators of alloying or flux components in primary copper smelting. These include samples from Ustye, Katzbakh 6, Rodnikovoe, and Taldysay sites, where high Ba and As slag contents are identified. The compilation of a database with a broad sample of sulfide compositions from Bronze Age slags and mines in the Urals and Kazakhstan will permit the further identification of ore types and raw materials associated with a particular deposit. Full article

The ultramafic-hosted Kairei vent field is located at 25°19′ S, 70°02′ E, towards the Northern end of segment 1 of the Central Indian Ridge (CIR-S1) at a water depth of ~2450 m. This study aims to investigate the distribution of trace elements among sulfide minerals of differing textures and to examine the possible factors controlling the trace element distribution in those minerals using LA-ICP-MS spot and line scan analyses. Our results show that there are distinct systematic differences in trace element distributions throughout the different minerals, as follows: (1) pyrite is divided into three types at Kairei, including early-stage euhedral pyrite (py-I), sub-euhedral pyrite (py-II), and colloform pyrite (py-III). Pyrite is generally enriched with Mo, Au, As, Tl, Mn, and U. Pyrite-I has high contents of Se, Te, Bi, and Ni when compared to the other types; py-II is enriched in Au relative to py-I and py-III, but poor in Ni; py-III is enriched in Mo, Pb, and U but is poor in Se, Te, Bi, and Au relative to py-I and py-II. Variations in the concentrations of Se, Te, and Bi in pyrite are most likely governed by the strong temperature gradient. There is generally a lower concentration of nickel than Co in pyrite, indicating that our samples precipitated at high temperatures, whereas the extreme Co enrichment is likely from a magmatic heat source combined with an influence of serpentinization reactions. (2) Chalcopyrite is characterized by high concentrations of Co, Se, and Te. The abundance of Se and Te in chalcopyrite over the other minerals is interpreted to have been caused by the high solubilities of Se and Te in the chalcopyrite lattice at high temperatures. The concentrations of Sb, As, and Au are relatively low in chalcopyrite from the Kairei vent field. (3) Sphalerite from Zn-rich chimneys is characterized by high concentrations of Sn, Co, Ga, Ge, Ag, Pb, Sb, As, and Cd, but is depleted in Se, Te, Bi, Mo, Au, Ni, Tl, Mn, Ba, V, and U in comparison with the other minerals. The high concentrations of Cd and Co are likely caused by the substitution of Cd²⁺ and Co²⁺ for Zn²⁺ in sphalerite. A high concentration of Pb accompanied by a high Ag concentration in sphalerite indicates that Ag occurs as Pb–Ag sulfosalts. Gold is generally low in sphalerite and strongly correlates with Pb, suggesting its presence in microinclusions of galena. The strong correlation of As with Ge in sphalerite from Kairei suggests that they might precipitate at medium temperatures and under moderately reduced conditions. (4) Bornite–digenite has very low concentrations of most trace elements, except for Co, Se, and Bi. Serpentinization in ultramafic-hosted hydrothermal systems might play an important role in Au enrichment in pyrite with low As contents. Compared to felsic-hosted seafloor massive sulfide deposits, sulfide minerals from ultramafic-hosted deposits show higher concentrations of Se and Te, but lower As, Sb, and Au concentrations, the latter often attributed to the contribution of magmatic volatiles. As with typical ultramafic-hosted seafloor massive sulfide deposits, Se enrichment in chalcopyrite from Kairei indicates that the primary factor that controls the Se enrichment is temperature-controlled mobility in vent fluids. Full article

Two quaternary metal chalcogenides, Ba₂AlSbS₅ and Ba₂GaBiSe₅, were successfully synthesized by solid-state reaction in sealed silica tubes. Both of them crystallize in the same orthorhombic space group Pnma, but they appear with obviously different construction features. For example, Ba₂AlSbS₅ exhibits [SbS₃]³⁻ units and zero-dimensional (0D) [AlSbS₅]⁴⁻ clusters, which is different from those ([BiSe₆]³⁻ units and 1D _∞[GaBiSe₅]⁴⁻ chains) of Ba₂GaBiSe₅. We also systematically investigated the entire series of Ba₂M^IIIM^III’Q₅ (M^III = Al, Ga, In; M^III’ = As, Sb, Bi; Q = S, Se, Te) compounds, and the results showed that the interconnection of M^IIIQ₄ and M^III’Q_n (n = 3, 5, 6) units can form three different structural types, including 0D [M^IIIM^III’Q₅] clusters, single [M^III’Q₃] chains and isolated [M^IIIQ₄] units, or [M^IIIQ₃]_n and [M^III’Q₃]_n double chains, which may be induced by the flexible coordination and on-link modes of M^III’ atoms. Spectral investigation shows that their bandgaps are about 2.57 eV for Ba₂AlSbS₅ and 2.14 eV for Ba₂GaBiSe₅. Theoretical calculation was also used to analyze their structure-property relationships, and the results indicate that the title compounds exhibit larger birefringences (Δn > 0.10), thus having potential as the IR birefringent materials. Full article

The intermetallic compounds formed during the diffusion soldering of a Bi₂Te_2.55Se_0.45 thermoelectric material with a Cu electrode are investigated. For this bonding process, Bi₂Te_2.55Se_0.45 was pre-coated with a 1 μm Sn thin film on the thermoelectric element and pre-heated at 250 °C for 3 min before being electroplated with a Ni barrier layer and a Ag reaction layer. The pre-treated thermoelectric element was bonded with a Ag-coated Cu electrode using a 4 μm Sn interlayer at temperatures between 250 and 325 °C. The results indicated that a multi-layer of Bi–Te–Se/Sn–Te–Se–Bi/Ni₃Sn₄ phases formed at the Bi₂Te_2.55Se_0.45/Ni interface, ensuring sound cohesion between the Bi₂Te_2.55Se_0.45 thermoelectric material and Ni barrier. The molten Sn interlayer reacted rapidly with both Ag reaction layers to form an Ag₃Sn intermetallic layer until it was completely exhausted and the Ag/Sn/Ag sandwich transformed into a Ag/Ag₃Sn/Ag joint. Satisfactory shear strengths ranging from 19.3 and 21.8 MPa were achieved in Bi₂Te_2.55Se_0.45/Cu joints bonded at 250 to 300 °C for 5 to 30 min, dropping to values of about 11 MPa for 60 min, bonding at 275 and 300 °C. In addition, poor strengths of about 7 MPa resulted from bonding at a higher temperature of 325 °C for 5 to 60 min. Full article

Six silver(I) coordination complexes have been prepared and structurally characterised. Mixed chalcogen-donor acenaphthene ligands L1–L3 [Acenap(EPh)(E'Ph)] (Acenap = acenaphthene-5,6-diyl; E/E' = S, Se, Te) were independently treated with silver(I) salts (AgBF₄/AgOTf). In order to keep the number of variables to a minimum, all reactions were carried out using a 1:1 ratio of Ag/L and run in dichloromethane. The nature of the donor atoms, the coordinating ability of the respective counter-anion and the type of solvent used in recrystallisation, all affect the structural architecture of the final silver(I) complex, generating monomeric, silver(I) complexes {[AgBF₄(L)₂] (1 L = L1; 2 L = L2; 3 L = L3), [AgOTf(L)₃] (4 L = L1; 5 L = L3), [AgBF₄(L)₃] (2a L = L1; 3a L = L3)} and a 1D polymeric chain {[AgOTf(L3)]_n 6}. The organic acenaphthene ligands L1-L3 adopt a number of ligation modes (bis-monodentate μ₂-η²-bridging, quasi-chelating combining monodentate and η⁶-E(phenyl)-Ag(I) and classical monodentate coordination) with the central silver atom at the centre of a tetrahedral or trigonal planar coordination geometry in each case. The importance of weak interactions in the formation of metal-organic structures is also highlighted by the number of short non-covalent contacts present within each complex. Full article