Search Results (6)

Oil sand tailings from bitumen extraction contain various contaminants, including polycyclic aromatic hydrocarbons, BTEX, and naphthenic acids, which can leak into surrounding environments, threatening aquatic ecosystems and human health. These tailings also contribute to environmental issues such as habitat disruption and greenhouse gas emissions. Despite these challenges, oil sand tailings hold significant potential for waste-to-resource recovery as they contain valuable minerals like rare earth elements (REEs), titanium, nickel, and vanadium. Traditional metal extraction methods are environmentally damaging, requiring high energy inputs and generating dust and harmful emissions. Furthermore, the coating of hydrocarbons on mineral surfaces presents an additional challenge, as it can inhibit the efficiency of metal extraction processes by blocking access to the minerals. This highlights the need for alternative, eco-friendly approaches. Bioleaching, which uses microorganisms to extract metals, emerges as a sustainable solution to unlock the valuable metals within oil sand tailings. This review discusses the minerals found in oil sand tailings, the challenges associated with their extraction, methods from hydrocarbon removal from minerals, and bioleaching as a potential metal recovery method. Full article

The mineralization of benzene, toluene, ethylbenzene, and xylene (BTEX) into inorganic substances by microorganisms may affect the water–rock interaction. However, few studies have quantitatively analyzed the processes. To quantitatively reveal this mechanism, in this study, nitrate and toluene were taken as the typical electron acceptor and BTEX, respectively. Based on hydro-geochemical theory, the mechanism and mathematical model were established. In addition, the model was verified with a toluene mineralization experiment. The mechanism model demonstrated that H⁺ was the main factor in the dissolution or precipitation of CaCO₃. The mathematical model derived the equations quantitatively between the amount of toluene mineralization, CaCO₃, and some biogeochemical indicators, including temperature, microbial consumption, and other major ions in groundwater. According to the model, the amount of dissolved CaCO₃ increased with the increasing proportion of completely reduced nitrate. For a complete reaction, the greater the microorganisms’ consumption of toluene was, the smaller the precipitation of CaCO₃. CaCO₃ dissolution was a nonmonotonic function that varied with temperature and the milligram equivalent of other ions. Furthermore, the validation experiments agreed well with the mathematical model, indicating its practicality. The established model provides a tool for assessing the biodegradation of toluene by monitoring the concentration of groundwater ions. Full article

A new type of organobentonite foundry binder composed of a composite of bentonite (SN) and poly(acrylic acid) (PAA) was analyzed using thermal analysis (TG-DTG-DSC) and pyrolysis gas chromatography mass spectrometry (Py-GC/MS). The temperature range in which the composite retains its binding properties was identified using thermal analysis of the composite and its components. Results showed that the thermal decomposition process is complex and involves physicochemical transformations that are mainly reversible at temperatures in the ranges of 20–100 °C (related to evaporation of solvent water) and 100–230 °C (related to intermolecular dehydration). The decomposition of PAA chains occurs between 230 and 300 °C, while complete decomposition of PAA and formation of organic decomposition products takes place at 300–500 °C. Dehydroxylation of montmorillonite (MMT) in bentonite begins at about 500 °C, which leads to a drastic structural transformation. An endothermic effect associated with the remodeling of the mineral structure was observed on the DSC curve in the range of 500–750 °C. The produced SN/PAA composite was found to be thermostable during degradation in both oxidative and inert atmosphere, similar to the starting bentonite, and even maintained over a relatively higher and wider temperature range compared to organic binding materials used. At the given temperatures of 300 °C and 800 °C, only CO₂ emissions occur from all the examined SN/PAA samples. There is no emission of compounds from the BTEX group. This means that the proposed binding material in the form of the MMT-PAA composite will not pose a threat to the environment and the workplace. Full article

Many free-living saprobic fungi are nature recruited organisms for the degradation of wastes, ranging from lignocellulose biomass to organic/inorganic chemicals, aided by their production of enzymes. In this study, fungal strains were isolated from contaminated crude-oil fields in Nigeria. The dominant fungi were selected from each site and identified as Aspergillus oryzae and Mucor irregularis based on morphological and molecular characterization, with site percentage incidences of 56.67% and 66.70%, respectively. Selected strains response/tolerance to complex hydrocarbon (used engine oil) was studied by growing them on Bushnell Haas (BH) mineral agar supplemented with the hydrocarbon at different concentrations, i.e., 5%, 10%, 15%, and 20%, with a control having dextrose. Hydrocarbon degradation potentials of these fungi were confirmed in BH broth culture filtrates pre-supplemented with 1% engine oil after 15 days of incubation using GC/MS. In addition, the presence of putative enzymes, laccase (Lac), manganese peroxidase (MnP), and lignin peroxidase (LiP) was confirmed in culture filtrates using appropriate substrates. The analyzed fungi grew in hydrocarbon supplemented medium with no other carbon source and exhibited 39.40% and 45.85% dose inhibition response (DIR) respectively at 20% hydrocarbon concentration. An enzyme activity test revealed that these two fungi produced more Lac than MnP and LiP. It was also observed through the GC/MS analyses that while A. oryzae acted on all hydrocarbon components in the used engine oil, M. irregularis only degraded the long-chain hydrocarbons and BTEX. This study confirms that A. oryzae and M. irregularis have the potential to be exploited in the bio-treatment and removal of hydrocarbons from polluted soils. Full article

Ash from poultry feather gasification was investigated as an adsorbent for Cd removal from synthetic wastewater under a range of operational conditions: initial pH (2–8) and salinity (8–38 mS/cm) of wastewater, ash dosage (2.5–50 g/L), Cd concentration (25–800 mg/L) and contact time (5–720 min). The ash was highly alkaline and had low surface area and micropores averaging 1.12 nm in diameter. Chemical/mineralogical analysis revealed a high content of P₂O₅ (39.9 wt %) and CaO (35.5 wt %), and the presence of calcium phosphate, hydroxyapatite and calcium. It contained only trace amounts of heavy metals, BTEX, PAHs and PCBs, making it a safe mineral by-product. Cd adsorption was described best with Langmuir and pseudo-second order models. At pH 5, an ash dosage of 5 g/L, 40 min contact time and 100 mg Cd/L, 99% of Cd was removed from wastewater. The salinity did not affect Cd sorption. The maximum adsorption capacity of Cd was very high (126.6 mg/g). Surface precipitation was the main mechanism of Cd removal, possibly accompanied by ion exchange between Cd and Ca, coprecipitation of Cd with Ca-mineral components and Cd complexation with phosphate surface sites. Poultry ash effectively removes high concentrations of toxic Cd from wastewater. Full article

Environmental pollution with petroleum products has become a major problem worldwide, and is a consequence of industrial growth. The development of sustainable methods for the removal of petroleum substances and their derivatives from aquatic and terrestrial environments and from air has therefore become extremely important today. Advanced technologies and materials dedicated to this purpose are relatively expensive; sorption methods involving mineral sorbents are therefore popular and are widely described in the scientific literature. Mineral materials are easily available, low-cost, universal adsorbents and have a number of properties that make them suitable for the removal of petroleum substances. This review describes recent works on the use of natural, synthetic and modified mineral adsorbents for the removal of petroleum substances and their derivatives from roads, water and air. Full article