Search Results (6)

This study presents the structure and optoelectronic properties of a perovskite-like (PEA)₂PbBr₃Cl material on an AlN/sapphire substrate heterostructure prepared using spin coating. The AlN/sapphire substrate comprised a 2 μm thick AlN epilayer on a sapphire wafer deposited via metal–organic chemical vapor deposition (MOCVD). The peak position of (PEA)₂PbBr₃Cl photoluminescence (PL) on the AlN/sapphire substrate heterostructure was 372 nm. The emission wavelength ranges of traditional lead halide perovskite light-emitting diodes are typically 410 to 780 nm, corresponding to the range of purple to deep red as the ratio of halide in the perovskite material changes. This indicates the potential for application as a UV perovskite light-emitting diode. In this study, we investigated the contact characteristics between Ag metal and the (PEA)₂PbBr₃Cl layer on an AlN/sapphire substrate heterostructure, which improved after annealing in an air environment due to the tunneling effect of the thermionic-field emission (TFE) mechanism. Full article

Stimuli-responsive luminescent materials have received great attention for their potential application in anti-counterfeiting and information encryption. Manganese halide hybrids have been considered an efficient stimuli-responsive luminescent material due to their low price and adjustable photoluminescence (PL). However, the photoluminescence quantum yield (PLQY) of PEA₂MnBr₄ is relatively low. Herein, Zn²⁺- and Pb²⁺-doped PEA₂MnBr₄ samples are synthesized, and show an intense green emission and orange emission, respectively. After doping with Zn²⁺, the PLQY of PEA₂MnBr₄ is elevated from 9% to 40%. We have found that green emitting Zn²⁺-doped PEA₂MnBr₄ could transform to a pink color after being exposed to air for several seconds and the reversible transformation from pink to green was achieved by using heating treatment. Benefiting from this property, an anti-counterfeiting label is fabricated, which exhibits excellent “pink-green-pink” cycle capability. Pb²⁺-doped PEA₂Mn_0.88Zn_0.12Br₄ is acquired by cation exchange reaction, which shows intense orange emission with a high QY of 85%. The PL of Pb²⁺-doped PEA₂Mn_0.88Zn_0.12Br₄ decreases with increasing temperature. Hence, the encrypted multilayer composite film is fabricated relying on the different thermal responses of Zn²⁺- and Pb²⁺-doped PEA₂MnBr₄, whereby the encrypted information can be read out by thermal treatment. Full article

Wheat is grown in an area totalling 31.1 million hectares in India. The North-western Indo-Gangetic Plains (IGP) constitutes the major share of area and production of wheat in India and is known as the wheat belt of India. However, sustaining wheat production under declining/lower resource-use efficiency in the existing rice–wheat cropping system has led to considerations about diversifying this system with a pigeon pea–wheat system (PWS) in the IGP of India. However, little or no information is available on the impact of CA-based PWS on weed dynamics, productivity, profitability, and resource-use efficiencies. Therefore, we studied these aspects in wheat under a long-term (~12 years) conservation agriculture (CA)-based PWS. Treatments were conventional till flatbed (CT), ZT permanent narrow beds (PNBR & PNB), broad beds (PBBR & PBB), and flat beds (PFBR & PFB) with and without residue (R) retention and different N levels (75% and 100% of the recommended N). The results showed that the Shannon–Weiner index and the Simpson dominance index were higher under the CA system in 2021–2022 than in 2010–2011 and 2015–2016, indicating a change in weed diversity over the period. Furthermore, the Sorensen similarity index showed that there was not much difference in weed diversity for 2010–2011. However, in 2015–2016 and 2021–2022 respectively, only 89% (0.89) and 62% (0.62) of weed species were common to both CT and CA systems, indicating a shift in weed species in the long-term CA system in 2021–2022. Residue retention and N dose decreased weed density at 30 days after sowing (DAS). All the CA-based (PFBR100N, PBBR100N, PNBR100N, PFBR75N, PBBR75N, and PNBR75N) treatments reduced the weed density and dry weight compared to CT at 30 DAS. Wheat grain yield and net returns increased by 11.6–14.9% and 19.4–23.8% over CT in CA treatments, of which PFBR100N and PBBR100N were superior. The PBBR100N and PBBR75N systems had water productivity significantly higher than CT. Residue retention in ZT permanent beds reduced energy productivity in CA than CT and no residue treatments. In the 12th year, CA with 75% N (PFBR75N, PBBR75N, PNBR75N) resulted in a higher partial factor productivity of N and total NPK applied. Contrast analysis showed that 75% N was comparable with 100% N on crop, water, and energy productivities and 75% N was superior to 100% N on partial factor productivity of N and total NPK. Thus, the permanent broad bed with residue and 100% N in the initial years and 75% N in later years can be adopted in the north-western IGP for better weed suppression, higher yield, profitability, and resource-use efficiency. Full article

Two-dimensional (2D) perovskite have been widely researched for solar cells, light-emitting diodes, photodetectors because of their excellent environmental stability and optoelectronic properties in comparison to three-dimensional (3D) perovskite. In this study, we demonstrate the high response of 2D-(PEA)₂PbBr₄ perovskite of the horizontal vapor sensor was outstandingly more superior than 3D-MAPbBr₃ perovskite. 2D transverse perovskite layer have the large surface-to-volume ratio and reactive surface, with the charge transfer mechanism, which was suitable for vapor sensing and trapping. Thus, 2D perovskite vapor sensors demonstrate the champion current response ratio R of 107.32 under the ethanol vapors, which was much faster than 3D perovskite (R = 2.92). Full article

Light-emitting diodes (LEDs) based on perovskite materials are a new group of devices that are currently undergoing rapid development. A significant fraction of these devices is based on quasi-2D perovskites fabricated with large organic cations. In this work, we describe the ultrafast scale dynamics in a quasi-2D PEA₂(Rb_0.6Cs_0.4)₂Pb₃Br₁₀ perovskite material with an excess of RbBr, which was previously used to fabricate blue-emitting perovskite LEDs. The results obtained using transient absorption spectroscopy are consistent with the assumption that the carrier dynamics in this material are dominated by excitons, most of which decay by exciton–exciton annihilation when high-intensity excitation is used. Furthermore, a slow energy transfer between different quasi-2D domains taking place within 50 ps was observed. The content of the RbBr did not show any strong influence on the observed dynamics. Our results show that the exciton–exciton annihilation proceeds much faster in thin (n = 2) quasi-2D domains than in thick (n ≥ 4) domains. This finding implies that perovskites with high-n, quasi-2D domains are preferable for efficient perovskite lasers and bright perovskite LEDs. Full article

Lead (Pb)-polluted soils pose a serious threat to human health, particularly by transmitting this heavy metal to the food chain via the crops grown on them. The application of novel amendments in Pb-polluted soils can significantly reduce this problem. In this research, we report the effects of various organic and inorganic amendments i.e., bentonite (BN), biochar (BR), lignin (LN), magnesium potassium phosphate cement (CM) and iron hydroxyl phosphate (FeHP), on the Pb bioavailability in Pb-polluted soil, upon Pb distribution in shoots, roots, grain, the translocation factor (TF) and the bioconcentration factor (BCF) of Pb in pea (Pisum sativum L.) grain. Furthermore, effects of the said amendments on the plant parameters, as well as grain biochemistry and nutritional quality, were also assessed. Lead pollution significantly elevated Pb concentrations in roots, shoots and grain, as well as the grain TF and BCF of Pb, while reducing the nutritional quality and biochemistry of grain, plant height, relative water content (RWC), chlorophyll contents (chl a and chl b) and the dry weight (DW) of shoot, root and grain. The lowest Pb distribution in shoots, roots and grain were found with BN, FeHP and CM, compared to our control. Likewise, the BN, FeHP and CM significantly lowered the TF and BCF values of Pb in the order FeHP > CM > BN. Similarly, the highest increase in plant height, shoot, root and grain DW, RWC, chl a and chl b contents, grain biochemistry and the micronutrient concentrations, were recorded with BR amendment. Biochar also reduced grain polyphenols as well as plant oxidative stress. Given that the BR and BN amendments gave the best results, we propose to explore their potential synergistic effect to reduce Pb toxicity by using them together in future research. Full article