Search Results (10)

The rapid adoption of electric vehicles (EVs) has increased the demand for efficient methods to assess the state of health (SoH) of lithium-ion batteries (LIBs). Accurate and prompt evaluations are essential for safety, battery life extension, and performance optimization. While traditional techniques such as electrochemical impedance spectroscopy (EIS) are commonly used to monitor battery degradation, acoustic emission (AE) analysis is emerging as a promising complementary method. AE’s sensitivity to mechanical changes within the battery structure offers significant advantages, including speed and non-destructive assessment, enabling evaluations without disassembly. This capability is particularly beneficial for diagnosing second-life batteries and streamlining decision-making regarding the management of used batteries. Moreover, AE enhances diagnostics by facilitating early detection of potential issues, optimizing maintenance, and improving the reliability and longevity of battery systems. Importantly, AE is a non-destructive technique and belongs to the passive method category, as it does not introduce any external energy into the system but instead detects naturally occurring acoustic signals during the battery’s operation. Integrating AE with other analytical techniques can create a comprehensive tool for continuous battery condition monitoring and predictive maintenance, which is crucial in applications where battery reliability is vital, such as in EVs and energy storage systems. This review not only examines the potential of AE techniques in battery health monitoring but also underscores the need for further research and adoption of these techniques, encouraging the academic community and industry professionals to explore and implement these methods. Full article

Lithium-ion batteries are commonly employed in electric vehicles due to their efficient energy storage and conversion capabilities. Nevertheless, to ensure reliable and cost-effective operation, their internal states must be continuously monitored. Electrochemical impedance spectroscopy (EIS) is an effective tool for assessing the battery’s state. Different frequency ranges of EIS correspond to various electrochemical reaction processes. In this study, EIS measurements were conducted at seven temperatures, ranging from −20 °C to 10 °C, and across 21 states of charge (SOCs), spanning from 0% to 100%. A regression model was utilized to examine the unidirectional factorial characteristic impedance relative to temperature and SOC. An analysis of variance (ANOVA) table was created with temperature and SOC as independent variables and the impedance value as the dependent variable. These models accurately capture the behavior of lithium-ion batteries under different conditions. Based on this research, the battery electrochemical processes are better understood. This paper establishes a mathematical expression for a temperature–SOC-based impedance model at specific frequencies, i.e., 1 Hz, 20 Hz, and 3100 Hz. When comparing the models at these three frequencies, it was found that the model fitting accuracy is highest at 20 Hz, making it applicable across a wide range of temperatures and SOCs. Consequently, the accuracy of the impedance model can be enhanced at a specific frequency, simplifying the impedance model and facilitating the development of advanced battery state estimation methods. Full article

The significant deployment of lithium-ion batteries (LIBs) within a wide application field covering small consumer electronics, light and heavy means of transport, such as e-bikes, e-scooters, and electric vehicles (EVs), or energy storage stationary systems will inevitably lead to generating notable amounts of spent batteries in the coming years. Considering the environmental perspective, material resource sustainability, and terms of the circular economy, recycling represents a highly prospective strategy for LIB end-of-life (EOL) management. In contrast with traditional, large-scale, implemented recycling methods, such as pyrometallurgy or hydrometallurgy, direct recycling technology constitutes a promising solution for LIB EOL treatment with outstanding environmental benefits, including reduction of energy consumption and emission footprint, and weighty economic viability. This work comprehensively assesses the limitations and challenges of state-of-the-art, implemented direct recycling methods for spent LIB cathode and anode material treatment. The introduced approaches include solid-state sintering, electrochemical relithiation in organic and aqueous electrolytes, and ionothermal, solution, and eutectic relithiation methods. Since most direct recycling techniques are still being developed and implemented primarily on a laboratory scale, this review identifies and discusses potential areas for optimization to facilitate forthcoming large-scale industrial implementation. Full article

The last decade has seen a significant increase in electromobility. With this trend, it will be necessary to start dealing with the subsequent recycling and disposal of electric vehicles, including the batteries. Currently, the battery is one of the most expensive components of an electric vehicle, which in part hinders their sufficient competitiveness with the internal combustion engine. Furthermore, the lifetime of a battery for use in an electric vehicle is assumed to be 8–10 years/160,000 km, after which the battery capacity drops to 80% of the initial capacity. However, it transpires that a battery at the end of its life in an electric vehicle does not need to be disposed of immediately, but can be used in other applications wherein the emphasis is not so strictly on an excellent power and capacity capability related to its volume or weight. Thus, reusing batteries can help reduce their cost for use in electric vehicles, increase their utility value, and reduce the environmental impact of batteries. This paper discusses methods for researching battery aging in electric vehicles, testing methods for batteries during the transition from first life to second life, and prospective battery second-life use and its specifics. The main contribution of this perspective article is to provide a comprehensive view of the current state of second-life batteries and an overview of the challenges that need to be overcome in order to use them on a large industrial scale. Full article

Environmental concerns push for a reduction in greenhouse gas emissions and technologies with a low carbon footprint. In the transportation sector, this drives the transition toward electric vehicles (EVs), which are nowadays mainly based on lithium-ion batteries (LIBs). As the number of produced EVs is rapidly growing, a large amount of waste batteries is expected in the future. Recycling seems to be one of the most promising end-of-life (EOL) methods; it reduces raw material consumption in battery production and the environmental burden. Thus, this work introduces a comprehensive pre-recycling material characterization of waste nickel-manganese-cobalt (NMC) LIB cells from a fully electric battery electric vehicle (BEV), which represents a basis for cost-effective and environmentally friendly recycling focusing on the efficiency of the implemented technique. The composition of the NCM 622 battery cell was determined; it included a LiNi_0.6Co_0.2Mn_0.2O₂ spinel on a 15 μm Al-based current collector (cathode), a graphite layer on 60 μm copper foil (anode), 25 μm PE/PVDF polymer separator, and a LiPF₆ salt electrolyte with a 1:3 ratio in primary solvents DMC and DEC. The performed research was based on a series of X-ray, infrared (IR) measurements, gas chromatography–mass spectrometry (GC-MS), and inductively coupled plasma–optical emission spectrometry (ICP-OES) characterization of an aqueous solution with dissolved electrolytes. These results will be used in subsequent works devoted to optimizing the most suitable recycling technique considering the environmental and economic perspectives. Full article

Lithium-ion batteries (LIBs) are crucial for consumer electronics, complex energy storage systems, space applications, and the automotive industry. The increasing requirements for decarbonization and CO₂ emissions reduction affect the composition of new production. Thus, the entire automotive sector experiences its turning point; the production capacities of new internal combustion engine vehicles are limited, and the demand for electric vehicles (EVs) has continuously increased over the past years. The growing number of new EVs leads to an increasing amount of automotive waste, namely spent LIBs. Recycling appears to be the most suitable solution for lowering EV prices and reducing environmental impacts; however, it is still not a well-established process. This work is the second part of the review collection based on the performed literature survey, where more than 250 publications about “Recycling of Lithium-ion Batteries from Electric Vehicles” were divided into five sections: Recycling Processes, Battery Composition, Environmental Impact, Economic Evaluation, and Recycling and Rest. This paper reviews and summarizes 162 publications dedicated to recycling procedures and their environmental or economic perspective. Both reviews cover the techno-environmental economic impacts of recycling spent LIBs from EVs published until 2021. Full article

During recent years, emissions reduction has been tightened worldwide. Therefore, there is an increasing demand for electric vehicles (EVs) that can meet emission requirements. The growing number of new EVs increases the consumption of raw materials during production. Simultaneously, the number of used EVs and subsequently retired lithium-ion batteries (LIBs) that need to be disposed of is also increasing. According to the current approaches, the recycling process technology appears to be one of the most promising solutions for the End-of-Life (EOL) LIBs—recycling and reusing of waste materials would reduce raw materials production and environmental burden. According to this performed literature review, 263 publications about “Recycling of Lithium-ion Batteries from Electric Vehicles” were classified into five sections: Recycling Processes, Battery Composition, Environmental Impact, Economic Evaluation, and Recycling & Rest. The whole work reviews the current-state of publications dedicated to recycling LIBs from EVs in the techno-environmental-economic summary. This paper covers the first part of the review work; it is devoted to the recycling technology processes and points out the main study fields in recycling that were found during this work. Full article

Much attention has been paid to rechargeable lithium-sulfur batteries (Li–SBs) due to their high theoretical specific capacity, high theoretical energy density, and affordable cost. However, their rapid c fading capacity has been one of the key defects in their commercialization. It is believed that sulfuric cathode degradation is driven mainly by passivation of the cathode surface by Li₂S at discharge, polysulfide shuttle (reducing the amount of active sulfur at the cathode, passivation of anode surface), and volume changes in the sulfuric cathode. These degradation mechanisms are significant during cycling, and the polysulfide shuttle is strongly present during storage at a high state-of-charge (SOC). Thus, storage at 50% SOC is used to evaluate the effect of the remaining degradation processes on the cell’s performance. In this work, unlike most of the other previous observations that were performed at small-scale cells (coin cells), 3.4 Ah pouch Li–SBs were tested using cycling and calendar aging protocols, and their performance indicators were analyzed. As expected, the fade capacity of the cycling aging cells was greater than that of the calendar aging cells. Additionally, the measurements for the calendar aging cells indicate that, contrary to the expectation of stopping the solubility of long-chain polysulfides and not attending the shuttle effect, these phenomena occur continuously under open-circuit conditions. Full article

CubeSats and small satellite solutions are increasing in popularity as they enable a fast, cheap, and agile way for satellite applications. An essential component of nearly every satellite is the energy storage device, which is practically equal to a battery. Consequently, an overview of past, present, and future battery technologies for CubeSats is presented. CubeSats use typically commercial off-the-shelf (COTS) batteries. They are not primarily dedicated to space, so their suitability to the space environment needs to be evaluated. Batteries are also considered as potentially dangerous goods. Thus, there are guidelines and standards that specify safety criteria and tests for the batteries in order to be allowed for transportation and launch. Furthermore, the character of satellites’ missions determines their demand on batteries in terms of current rates, depth-of-discharge, and lifetime. Thus, these expectations are discussed. A market survey was also carried out to identify currently available commercial battery solutions and their parameters. This work summarizes the status, requirements, and the market situation of batteries for CubeSats. Full article

Lithium-sulfur (Li-S) batteries are an emerging energy storage technology with higher performance than lithium-ion batteries in terms of specific capacity and energy density. However, several scientific and technological gaps need to be filled before Li-S batteries will penetrate the market at a large scale. One such gap, which is tackled in this paper, is represented by the estimation of state-of-health (SOH). Li-S batteries exhibit a complex behaviour due to their inherent mechanisms, which requires a special tailoring of the already literature-available state-of-charge (SOC) and SOH estimation algorithms. In this work, a model of SOH based on capacity fade and power fade has been proposed and incorporated in a state estimator using dual extended Kalman filters has been used to simultaneously estimate Li-S SOC and SOH. The dual extended Kalman filter’s internal estimates of equivalent circuit network parameters have also been used to the estimate maximum available power of the battery at any specified instant. The proposed estimators have been successfully applied to both fresh and aged Li-S pouch cells, showing that they can accurately track accurately the battery SOC, SOH, and power, providing that initial conditions are suitable. However, the estimation of the Li-S battery cells’ capacity fade is shown to be more complex, because the practical available capacity varies highly with the applied current rates and the dynamics of the mission profile. Full article