Search Results (16)

The durability of steel reinforcement in geopolymer composites is significantly influenced by the chemical characteristics of the alkaline medium in which they are embedded. This research offers detailed insights into the corrosion kinetics and mechanisms of geopolymers derived from various fly ash and alkaline activator formulations, considering their inherent microstructural and chemical heterogeneity. This study investigates the effect of the molarity of sodium hydroxide (NaOH) solution and the ratio of sodium silicate to sodium hydroxide (Na₂SiO₃/NaOH) on the corrosion behavior of steel reinforcement in geopolymer matrix under the action of chloride ions. Corrosion of steel reinforcement embedded in geopolymer binder prepared by alkaline activation of fly ash with alkaline activator prepared with different Na₂SiO₃/NaOH ratios (1:1, 1:2, 2:1) and different molar concentrations of NaOH solution (6 M, 8 M and 10 M) was analyzed in terms of process kinetics using Open Circuit Potential (OCP) and Linear Polarization (LP) and mechanism by Electrochemical Impedance Spectroscopy (EIS). The study demonstrates that a Na₂SiO₃:NaOH ratio of 1:2 and an 8 M NaOH solution yield the most favorable combination of physical and mechanical properties and corrosion resistance, confirmed by the highest apparent density, lowest water absorption, and significantly reduced corrosion current densities (as low as 0.72 μA/cm²), as well as highlighting porosity and pH as key factors influencing steel protection in geopolymer matrices. Full article

This case study focuses on twelve compacted clay soil samples to understand their fundamental physical and thermal properties. For each sample, the density, thermal conductivity, thermal diffusivity, specific heat, and drying shrinkage were assessed. The identification and characterisation of the materials were also carried out by positioning them into the ternary diagram based on the percentage of sand, silt, and clay. These properties are definitive for the performance characteristics of materials used in rammed earth wall construction. The aim is to provide information for better knowledge and prediction regarding the dynamic heat flow in rammed earth walls. Experimental results show a relatively wide range of values for each property, reflecting the diverse properties of the sampled clays. The thermophysical characteristics of the 12 types of earth analysed showed correlations with reports in the literature in terms of density (1490–2150 kg/m³), porosity (23.22–39.99%), specific heat capacity (701–999 J/kgK), and thermal conductivity (0.523–1.209 W/mK), which indicates them as materials suitable for use in the construction of rammed earth walls. Using test data, a dynamic assessment of heat flow through simulated rammed earth walls was performed. For a better understanding of the results obtained, they were compared with results obtained for simulations where the building element would be made of concrete, i.e., a mineral wool core composite. Thus, heat flux at the wall surface and mass flux, respectively, during the 16 years of operation showed similar evolution for all 12 types of clay material analysed, with small variations explained by differences in thermophysical characteristics specific to each type of S1–S12 earth. In the case of walls made from clay material, there is a stabilisation in the evolution of the water content phenomenon by the 5th year of simulation. This contrasts with walls made of concrete, where the characteristic water content appears to evolve continuously over the 16-year period. Therefore, it can be said that in the case of the construction elements of existing buildings, which have already gone through a sufficient period for the maturation of the materials in their construction elements, the rammed earth wall quickly develops a moisture buffer function. In the case of simulating a mineral wool core composite wall, it cannot perform as a temperature or humidity buffer, exhibiting an enthalpy exchange with indoor air that is only 4% of that of the rammed earth walls; consequently, it does not play a significant role in regulating indoor comfort conditions. Overall, there is confirmation of the temperature and moisture buffering capabilities of rammed earth walls during both warm and cold periods of the year, which is consistent with other reports in the literature. The findings of this research provide a better insight into clay as a material for rammed earth walls for more efficient design and construction, offering potential improvements regarding indoor comfort, energy efficiency, and sustainability. The data also provides useful information in the fields of architecture and civil engineering regarding the use of clay as an eco-friendly building material. The results emphasise the importance of thoroughly understanding the thermophysical properties of clay to ensure the efficiency of rammed earth construction. Full article

Worldwide, the need for thermal insulation materials used to increase the energy performance of buildings and ensure indoor thermal comfort is constantly growing. There are several traditional, well-known and frequently used thermal insulation materials on the building materials market, but there is a growing trend towards innovative materials based on agro-industrial waste. This paper analyses the performance of 10 such innovative thermal insulation materials obtained by recycling cellulosic and/or animal waste, using standardised testing methods. More precisely, thermal insulation materials based on the following raw materials were analysed: cellulose acetate, cigarette filter manufacturing waste; cellulose acetate, cigarette filter manufacturing waste and cigarette paper waste; cellulose acetate, waste from cigarette filter manufacturing, waste cigarette paper and waste aluminised paper; cellulose from waste paper (two types made by two independent manufacturers); wood fibres; cellulose from cardboard waste; cellulose from waste cardboard, poor processing, inhomogeneous product; rice husk waste and composite based on sheep wool, recycled PET fibres and cellulosic fibres for the textile industry. The analysis followed the performance in terms of thermal insulating quality, evidenced by the thermal conductivity coefficient (used as a measurable indicator) determined for both dry and conditioned material at 50% RH, in several density variants, simulating the subsidence under its own weight or under various possible stresses arising in use. The results showed in most cases that an increase in material density has beneficial effects by reducing the coefficient of thermal conductivity, but exceptions were also reported. In conjunction with this parameter, the analysis of the 10 types of materials also looked at their moisture sorption/desorption capacity (using as a measurable indicator the amount of water stored by the material), concluding that, although they have a capacity to regulate the humidity of the indoor air, under low RH conditions the water loss is not complete, leaving a residual quantity of material that could favour the development of mould. Therefore, the impact on indoor air quality was also analysed by assessing the risk of mould growth (using as a measurable indicator the class and performance category of the material in terms of nutrient content conducive to the growth of microorganisms) under high humidity conditions but also the resistance to the action of two commonly encountered moulds, Aspergillus niger and Penicillium notatum. The results showed a relative resistance to the action of microbiological factors, indicating however the need for intensified biocidal treatment. Full article

This research investigates the feasibility of developing clay composites using natural materials and incorporating waste by-products suitable for plastering diverse support structures. The study identified a versatile composition suitable for a wide range of support materials and explored the potential of revaluing industrial waste and by-products by reintegrating them into the Circular Economy. The experimental investigation outlines the process of evaluating the influence of different raw materials on the performance of the clay composite. The findings confirm that using limestone sludge and fly ash as additives to clay contributes to reducing axial shrinkage and increasing mechanical strengths, respectively. The optimal percentage of additives for the clay used are identified and provided. Using hydraulic lime as a partial substitute for clay reduces the apparent density of dried clay composites, axial shrinkage, and fissures formation while improving adhesion to the substrate. Introducing dextrin into this mix increases the apparent density of the hardened plaster while keeping axial shrinkage below the maximum threshold indicated by the literature. Mechanical strengths improved, and better compatibility in terms of adhesion to the support was achieved, with composition S3 presenting the best results and a smooth, fissure-free plastered surface after drying. Full article

Fluvial terrace formation is a complex process governed by the interplay of climatic and tectonic forcings. From a climatic perspective, an incision is usually related to climatic transitions, while valley aggradation is attributed to glacial periods. We have reconstructed the formation of Late Pleistocene fluvial terraces along the middle, mountainous section of a temperate zone river (Mureş/Maros) in order to identify the roles of different climatic periods and potential vertical displacement in terrace development. Investigations were based on two profiles representing two different terrace levels. The profiles were subjected to sedimentological and detailed geochronological analyses using optically stimulated luminescence (OSL). The results indicated that the investigated terraces represent different incision events coinciding with climatic transition periods. However, a joint MIS 3 valley aggradation period can be identified at both of them. Thus, the relatively mild but highly variable climate of the MIS 3 facilitated sediment mobilization from upland catchments. On the other hand, there is no evidence of aggradation under the cold and stable climate of MIS 2. However, the tectonic setting favours incision at the site. Based on our results, we concluded that the timing of the main events was controlled primarily by climatic forcing. The terrace formation model recognised might also be applied at other rivers in the region. Full article

Starting from the context of the principles of Sustainable Development and Circular Economy concepts, the paper presents a synthesis of research in the field of the development of materials of interest, such as cementitious composites or alkali-activated geopolymers. Based on the reviewed literature, the influence of compositional or technological factors on the physical-mechanical performance, self-healing capacity and biocidal capacity obtained was analyzed. The inclusion of TiO₂ nanoparticles in the matrix increase the performances of cementitious composites, producing a self-cleaning capacity and an anti-microbial biocidal mechanism. As an alternative, the self-cleaning capacity can be achieved through geopolymerization, which provides a similar biocidal mechanism. The results of the research carried out indicate the real and growing interest for the development of these materials but also the existence of some elements still controversial or insufficiently analyzed, therefore concluding the need for further research in these areas. The scientific contribution of this study consists of bringing together two apparently distinct research directions in order to identify convergent points, to create a favorable framework for the development of an area of research little addressed so far, namely, the development of innovative building materials by combining improved performance with the possibility of reducing environmental impact, awareness and implementation of the concept of a Circular Economy. Full article

This communication study aims to provide evidence on how Sentinel sensors and Copernicus Programme’s contributing missions can support heritage endangered by natural hazards. The recent catastrophic floods of 2022 in Pakistan, mainly in the Indus Valley, threatened one of the most iconic sites within the country; thus, the UNESCO World Heritage Site of Mohenjo-Daro was selected here as a case study. Even if the main area of the site was not directly affected by the floods but rather by the heavy rains, its landscape suffered profound damage. This study aims to report a combined remote-sensing methodology for a rapid assessment of the flooded areas around the site. By using Sentinel-1 radar data in combination with mid-resolution Sentinel-2 data and Planet Lab images, it was possible to accurately map the affected areas near the site. This approach can be used to better understand the extent of the affected areas and build a better recovery strategy. A near-real-time satellite-based investigation and observations combining various sensors and resolutions (Sentinel 1 and 2 images, as well as Planet Lab images) can provide valuable insights for local heritage managers. Full article

This paper summarizes the results of a recent geophysical investigation carried out at Porolissum, which is considered to be one of the most significant Roman sites in Romania. The geophysical survey was carried out within the latus dextrum of the fort, which is the same location that had been the subject of earlier geophysical surveys as well as older archaeological excavations (1970s) that had uncovered a multiroom building. A cesium vapor total field magnetometer and a multi-electrode resistivity meter for a dense Electrical Resistivity Tomography (ERT) survey were used. Eighty parallel ERT profiles in combination with the emerging total field magnetic data and an antecedent magnetic survey allowed us to complete a more precise interpretation regarding the building that once existed on the left side of Porolissum’s Principia (the commander’s house). In contrast to the magnetic survey, which only reveals a part of the building’s architecture, the ERT survey provides a comprehensive view of the structure’s layout. More than 20 rooms could be positively identified, and the existence of further rooms might be deduced from the data. The ERT scan revealed the existence of the building’s northern external wall as well, which is not reflected on the magnetic map. Because some parts of the building are not visible on the magnetic map, we can assume that the building was constructed with at least two types of rocks (magmatic and sedimentary). In addition to the archaeological interpretation of the geophysical anomalies, a number of discussions concerning the connection between our survey and the geology of the area were held. The complementarity of the magnetic and resistivity results prompted us to conceive a preliminary 3D reconstruction of the building. Even if the building function is unknown in the absence of reliable archaeological data, it could have been a storage building, a second praetorium, a valetudinarium (hospital), or an armamentarium (weapons storage building). The illustrative reconstruction was completed taking into consideration that the building was a Roman military hospital, which, based on the available data, may be considered a credible assumption. Full article

This study aims to investigate potential archaeological proxies at a large Bronze Age fortification in Hungary, namely the Csanádpalota–Juhász T. tanya site, using open-access satellite data. Available Sentinel-2 images acquired between April 2017 and September 2022 were used. More than 700 images (727) were initially processed and filtered, accounting at the end of more than 400 (412) available calibrated Level 2A Sentinel images over the case study area. Sentinel-2 images were processed through image analysis. Based on pan-sharpened data, the visibility of crop marks was improved and enhanced by implementing orthogonal equations. Several crop marks, some still unknown, were revealed in this study. In addition, multi-temporal phenological observations were recorded on three archaeological proxies (crop marks) within the case study area, while an additional area was selected for calibration purposes (agricultural field). Phenological observations were performed for at least four complete phenological cycles throughout the study period. Statistical comparisons between the selected archaeological proxies were applied using a range of vegetation indices. The overall results indicated that phenological observations could be used as archaeological proxies for detecting the formation of crop marks. Full article

The use of waste from industrial activities is of particular importance for environmental protection. Fly ash has a high potential in the production of construction materials. In the present study, the use of fly ash in the production of geopolymer paste and the effect of Fe₂O₃, MgO and molarity of NaOH solution on the mechanical strength of geopolymer paste are presented. Samples resulting from the heat treatment of the geopolymer paste were subjected to mechanical tests and SEM, EDS and XRD analyses. Samples were obtained using 6 molar and 8 molar NaOH solution with and without the addition of Fe₂O₃ and MgO. Samples obtained using a 6 molar NaOH solution where Fe₂O₃ and MgO were added had higher mechanical strengths compared to the other samples. Full article

Changing weather patterns, increasing frequency and intensity of natural hazards, and rising sea levels associated with global climate change have the potential to threaten cultural heritage sites worldwide. This is especially the case for maritime heritage sites located in the low-lying coastal and delta regions of Asia. Maritime heritage can reflect both highly localized cultural products based on the coupling of people and maritime environments and the historic footprints of complex maritime networks that connect people, ideas, and material over vast distances, creating unique cultural spheres. Furthermore, maritime heritage sites potentially serve as or contain records of how past societies have been impacted by and adapted to past environmental stress. Therefore, their degradation threatens local/regional/global cultural patrimony as well as evidence of human resilience and fragility in the face of environmental change. This makes a strong case for urgent preservation. However, the possible damage caused by climate change and the scale of vulnerable maritime heritage pose seemingly insurmountable challenges. In this paper, we present the ways in which maritime heritage sites across Asia are vulnerable to environmental stresses, such as changing sea levels, coastal erosion, flooding, and storm surges. Our objective is to draw upon our experience documenting endangered cultural heritage across South and Southeast Asia to illustrate that there are unique conceptual and practical characteristics of maritime heritage that complicate effective management and conservation efforts on the scale required to prevent massive loss by climate change. We conclude by stressing the need to reconceptualize debates about the custody and stewardship of maritime heritage and the urgency of employing a wide range of innovative preservation solutions to ensure maritime patrimony is not lost to the rising tides. Full article

Crystalline admixtures embedded in concrete may react in the presence of water and generate thin crystals able to fill pores, capillaries and micro-cracks. Once the concrete has dried, the crystalline chemicals sit dormant until another dose of water starts the crystallization again. The research aims to analyses the early age self-sealing effect of a crystalline admixture at a dosage rate of 1–3% of the cement mass. Specimens made with two types of gravel were pre-loaded with three-point bending to up to 90% of the ultimate capacity, and conditioned through wet–dry cycles. Micro-crack closure was measured with a microscope after pre-loading, and after 1 day, 4 days, 8 days, 14 days and 20 days of wet–dry exposure. The results show that an admixture content of 3% achieves the best early self-sealing performance. These results are also confirmed by probabilistic analyses, which also emphasize the self-sealing potential of lower ICW contents. Full article

A geophysical investigation was carried across the M3 burial mound from Silvașu de Jos —Dealu Țapului, a tumuli necropolis in western Romania, where the presence of the Yamnaya people was certified archaeologically. For characterizing the inner structure of the mound, two conventional geophysical methods have been used: a geomagnetic survey and electrical resistivity tomography (ERT). The results allowed the mapping of the central features of the mound and the establishment of the relative stratigraphy of the mantle, which indicated at least two chronological phases. Archaeological excavations performed in the central part of the mound accurately validated the non-invasive geophysical survey and offered a valuable chronological record of the long-forgotten archaeological monument. Geophysical approaches proved to be an invaluable instrument for the exploration of the monument and suggest a fast constructive tool for the investigation of the entire necropolis which currently has a number of distinct mounds. Full article

The presence of TiO₂ nanoparticles in a cementitious matrix induces self-cleaning capacity in the presence of UV radiation by combining two mechanisms: surface hydrophilicity and degradation of the stain agent molecules. Experimental results indicate an increase in surface water absorption and, indirectly, in the degree of hydrophilicity, with the increase in the concentration of TiO₂ nanoparticles in the matrix. Degradation of organic molecules, rhodamine B, is dependent on the duration of action and intensity of UV rays and the concentration of nanoparticles in the cementitious matrix. An addition of 3–6% TiO₂ is effective and sufficient for a good self-cleaning capacity of cementitious surfaces. Full article

All industries produce wastes or byproducts, and if those are not properly managed, they will cause adverse effects on the environment. As the need for steel increases globally, waste from steel processing will also increase. Hazardous waste from steel processing is produced in the form of a coarse, dense aggregate, called steel slag. The aim of this paper is to present the possibility of using steel slag/blast furnace slag in the production of geopolymer concrete and to present the relevant results regarding the influence of this industrial byproduct on the mechanical properties of Geopolymer materials. Full article