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Organics, Volume 5, Issue 1

March 2024 - 2 articles

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Article

1 Citations

2,240 Views

20 Pages

Synthesis and Butyllithium-Induced Cyclisation of 2-Benzyloxyphenylphosphonamidates Giving 2,3-Dihydrobenzo[d][1,3]oxaphospholes

R. Alan Aitken,
Khadija Ait Moulay,
David B. Cordes,
Ryan A. Inwood,
Fraser G. Jamieson,
Alexander J. B. Nelson and
Aidan P. McKay

Organics2024, 5(1), 12-31;https://doi.org/10.3390/org5010002

1 February 2024

A series of fourteen O-ethyl-N-butylphenylphosphonamidates with benzyl ether substituents at the ortho position was prepared and fully characterised. Upon treatment with n-butyllithium in THF at RT, they underwent cyclisation in eight cases to give t...

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1,796 Views

11 Pages

How an Internal Supramolecular Interaction Determines the Stereochemistry of a Metal Center

Maxime Steinmetz,
Christophe Gourlaouen and
David Sémeril

Organics2024, 5(1), 1-11;https://doi.org/10.3390/org5010001

4 January 2024

The chloro-P,N-{diphenylphosphanyl-[(5-phenyl-1,3,4-oxadiazol-2-ylamino)phenyl-me- thyl]}(p-cymene)ruthenium(II) hexafluorophosphate complex (4) was obtained in two steps from diphenylphosphanyl-[(5-phenyl-1,3,4-oxadiazol-2-ylamino)phenyl-methyl] bor...

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