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Review

Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)

by
Igor B. Sivaev
A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119334 Moscow, Russia
Chemistry 2023, 5(2), 834-885; https://doi.org/10.3390/chemistry5020059
Submission received: 4 March 2023 / Revised: 7 April 2023 / Accepted: 9 April 2023 / Published: 11 April 2023
(This article belongs to the Special Issue Recent Advances in Modern Inorganic Chemistry: Featured Reviews)
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Abstract

This review is an attempt to bring together the data from the literature on the synthesis and properties of icosahedral carborane derivatives, in which exo-polyhedral three- and four-coordinated boron substituents are attached directly to the carborane cage through boron–carbon or boron–boron bonds. Various classes of compounds are considered, including carboranyl aryl boranes, boronic acids and their derivatives, boroles, diazaboroles, etc. Particular attention is paid to carborane-fused heterocycles containing boron atoms.
Keywords: carborane; boronic acid derivatives; trihydridoborate; arylborane; benzodiazaborole; carborane-fused boron-containing heterocycles; 9-borafluorene; 9,10-diboraanthracene; azoborole; borirane carborane; boronic acid derivatives; trihydridoborate; arylborane; benzodiazaborole; carborane-fused boron-containing heterocycles; 9-borafluorene; 9,10-diboraanthracene; azoborole; borirane

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MDPI and ACS Style

Sivaev, I.B. Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane). Chemistry 2023, 5, 834-885. https://doi.org/10.3390/chemistry5020059

AMA Style

Sivaev IB. Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane). Chemistry. 2023; 5(2):834-885. https://doi.org/10.3390/chemistry5020059

Chicago/Turabian Style

Sivaev, Igor B. 2023. "Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)" Chemistry 5, no. 2: 834-885. https://doi.org/10.3390/chemistry5020059

APA Style

Sivaev, I. B. (2023). Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane). Chemistry, 5(2), 834-885. https://doi.org/10.3390/chemistry5020059

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