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Keywords = borirane

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52 pages, 37229 KiB  
Review
Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)
by Igor B. Sivaev
Chemistry 2023, 5(2), 834-885; https://doi.org/10.3390/chemistry5020059 - 11 Apr 2023
Cited by 3 | Viewed by 3108
Abstract
This review is an attempt to bring together the data from the literature on the synthesis and properties of icosahedral carborane derivatives, in which exo-polyhedral three- and four-coordinated boron substituents are attached directly to the carborane cage through boron–carbon or boron–boron bonds. [...] Read more.
This review is an attempt to bring together the data from the literature on the synthesis and properties of icosahedral carborane derivatives, in which exo-polyhedral three- and four-coordinated boron substituents are attached directly to the carborane cage through boron–carbon or boron–boron bonds. Various classes of compounds are considered, including carboranyl aryl boranes, boronic acids and their derivatives, boroles, diazaboroles, etc. Particular attention is paid to carborane-fused heterocycles containing boron atoms. Full article
(This article belongs to the Special Issue Recent Advances in Modern Inorganic Chemistry: Featured Reviews)
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