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Article

Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions †

by
Young Hoon Lee
1,
Jee Young Kim
2,
Sotaro Kusumoto
3,
Hitomi Ohmagari
4,
Miki Hasegawa
4,
Pierre Thuéry
5,
Jack Harrowfield
6,*,
Shinya Hayami
3 and
Yang Kim
3
1
Department of Chemistry, University of Ulsan, Ulsan 44610, Korea
2
Department of Chemistry & Advanced Materials, Kosin University, 194 Wachiro, Yongdo-Gu, Busan 49104, Korea
3
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
4
Department of Chemistry & Biological Science, College of Science & Engineering, Aoyama Gakuin University, Sagamihara, Kanagawa 252-5258, Japan
5
Université Paris-Saclay, CEA, CNRS, NIMBE, 91191 Gif-sur-Yvette, France
6
ISIS, Université de Strasbourg, 8 allée Gaspard Monge, 67083 Strasbourg, France
*
Author to whom correspondence should be addressed.
†
Dedicated to Professor Christoph Janiak in recognition of his seminal contributions to the study of weak interactions in crystalline coordination complexes.
Chemistry 2021, 3(1), 199-227; https://doi.org/10.3390/chemistry3010016
Submission received: 12 January 2021 / Revised: 25 January 2021 / Accepted: 27 January 2021 / Published: 5 February 2021
(This article belongs to the Special Issue Coordination Polymers and Metal-Organic Frameworks: Structures and Applications—A Themed Issue in Honor of Professor Christoph Janiak on the Occasion of His 60th Birthday)
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Abstract

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.
Keywords: terpyridines; metal complexes; crystal structures; Hirshfeld surfaces; weak interactions terpyridines; metal complexes; crystal structures; Hirshfeld surfaces; weak interactions
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MDPI and ACS Style

Lee, Y.H.; Kim, J.Y.; Kusumoto, S.; Ohmagari, H.; Hasegawa, M.; Thuéry, P.; Harrowfield, J.; Hayami, S.; Kim, Y. Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions. Chemistry 2021, 3, 199-227. https://doi.org/10.3390/chemistry3010016

AMA Style

Lee YH, Kim JY, Kusumoto S, Ohmagari H, Hasegawa M, Thuéry P, Harrowfield J, Hayami S, Kim Y. Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions. Chemistry. 2021; 3(1):199-227. https://doi.org/10.3390/chemistry3010016

Chicago/Turabian Style

Lee, Young Hoon, Jee Young Kim, Sotaro Kusumoto, Hitomi Ohmagari, Miki Hasegawa, Pierre Thuéry, Jack Harrowfield, Shinya Hayami, and Yang Kim. 2021. "Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions" Chemistry 3, no. 1: 199-227. https://doi.org/10.3390/chemistry3010016

APA Style

Lee, Y. H., Kim, J. Y., Kusumoto, S., Ohmagari, H., Hasegawa, M., Thuéry, P., Harrowfield, J., Hayami, S., & Kim, Y. (2021). Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions. Chemistry, 3(1), 199-227. https://doi.org/10.3390/chemistry3010016

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