Parametric Evaluation of Thermal Behavior for Different Li-Ion Battery Chemistries
Abstract
:1. Introduction
2. Materials and Methods
Experimental Procedure
3. Results and Discussions
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Parameters | KeepPower | Panasonic | Samsung |
---|---|---|---|
Chemistry | LCO | NCA | NMC |
Size | 18650 | 18650 | 21700 |
Anode active material | Graphite | Graphite | Graphite |
Cathode active material | LiMn2O4 | LiNi0.8Co0.15Al0.05O2 | Li(NiMnCo)O2 |
Anode electrode thickness | 126 μm | 126 μm | 126 μm |
Cathode electrode thickness | 125 μm | 125 μm | 125 μm |
Anode current collector foil thicknesses (copper) | 10 μm | 10 μm | 10 μm |
Cathode current collector foil thicknesses (aluminum) | 20 μm | 20 μm | 20 μm |
Electrolyte | Lithium Hexafluorophosphate (LiPF6) | ||
Separator (polypropylene (PP)) | 20 μm | 20 μm | 22 μm |
Nominal voltage [V] | 3.7 | 3.6 | 3.6 |
Nominal capacity [Ah] | 2.6 | 3.1 | 4 |
Maximum discharge current [A] | 15 | 10 | 45 |
Discharge Rate | Battery’s Chemistry | Location of Measurement | Polynomial Equations’ Coefficients | R-Square | ||
---|---|---|---|---|---|---|
a | b | c | ||||
1C | NCA | Positive terminal | 1.14 × 10−9 | 5.95 × 10−6 | 1.13 × 10−2 | 0.9714 |
Middle | 1.25 × 10−9 | 6.46 × 10−6 | 1.20 × 10−2 | 0.9828 | ||
Negative terminal | 1.23 × 10−9 | 6.37 × 10−6 | 1.18 × 10−2 | 0.9854 | ||
All data | 1.21 × 10−9 | 6.26 × 10−6 | 1.17 × 10−2 | 0.9774 | ||
NMC | Positive terminal | 4.60 × 10−10 | 2.10 × 10−6 | 4.73 × 10−3 | 0.9626 | |
Middle | 4.68 × 10−10 | 2.11 × 10−6 | 4.84 × 10−3 | 0.9686 | ||
Negative terminal | 4.62 × 10−10 | 2.11 × 10−6 | 4.88 × 10−3 | 0.97 | ||
All data | 4.63 × 10−10 | 2.11 × 10−6 | 4.82 × 10−3 | 0.9644 | ||
LCO | Positive terminal | 4.90 × 10−10 | 2.54 × 10−6 | 5.24 × 10−3 | 0.9763 | |
Middle | 5.37 × 10−10 | 2.75 × 10−6 | 5.61 × 10−3 | 0.9625 | ||
Negative terminal | 5.50 × 10−10 | 2.86 × 10−6 | 5.80 × 10−3 | 0.959 | ||
All data | 5.26 × 10−10 | 2.72 × 10−6 | 5.55 × 10−3 | 0.9581 | ||
2C | NCA | Positive terminal | 9.86 × 10−9 | 3.19 × 10−5 | 4.26 × 10−2 | 0.9786 |
Middle | 1.10 × 10−8 | 3.42 × 10−5 | 4.42 × 10−2 | 0.9915 | ||
Negative terminal | 1.15 × 10−8 | 3.60 × 10−5 | 4.58 × 10−2 | 0.996 | ||
All data | 1.08 × 10−8 | 3.40 × 10−5 | 4.42 × 10−2 | 0.9863 | ||
NMC | Positive terminal | 3.17 × 10−9 | 9.68 × 10−6 | 1.80 × 10−2 | 0.9901 | |
Middle | 2.68 × 10−9 | 8.44 × 10−6 | 1.79 × 10−2 | 0.9864 | ||
Negative terminal | 3.23 × 10−9 | 9.90 × 10−6 | 1.90 × 10−2 | 0.9926 | ||
All data | 3.02 × 10−9 | 9.33 × 10−6 | 1.83 × 10−2 | 0.9841 | ||
LCO | Positive terminal | 3.68 × 10−9 | 1.23 × 10−5 | 2.02 × 10−2 | 0.934 | |
Middle | 4.08 × 10−9 | 1.35 × 10−5 | 2.22 × 10−2 | 0.98 | ||
Negative terminal | 4.73 × 10−9 | 1.55 × 10−5 | 2.36 × 10−2 | 0.9638 | ||
All data | 3.91 × 10−9 | 1.31 × 10−5 | 2.15 × 10−2 | 0.9481 | ||
3C | NCA | Positive terminal | 3.43 × 10−8 | 8.40 × 10−5 | 9.11 × 10−2 | 0.9838 |
Middle | 3.80 × 10−8 | 9.14 × 10−5 | 9.71 × 10−2 | 0.9977 | ||
Negative terminal | 4.27 × 10−8 | 9.91 × 10−5 | 0.1 | 0.9971 | ||
All data | 3.83 × 10−8 | 9.15 × 10−5 | 9.61 × 10−2 | 0.9887 | ||
NMC | Positive terminal | 6.03 × 10−9 | 2.17 × 10−5 | 4.02 × 10−2 | 0.9885 | |
Middle | 3.68 × 10−9 | 1.66 × 10−5 | 3.98 × 10−2 | 0.9938 | ||
Negative terminal | 8.40 × 10−9 | 2.39 × 10−5 | 4.26 × 10−2 | 0.9948 | ||
All data | 6.04 × 10−9 | 2.07 × 10−5 | 4.08 × 10−2 | 0.9858 | ||
LCO | Positive terminal | 9.28 × 10−9 | 2.80 × 10−5 | 4.51 × 10−2 | 0.9959 | |
Middle | 9.47 × 10−9 | 2.86 × 10−5 | 4.63 × 10−2 | 0.9953 | ||
Negative terminal | 1.46 × 10−8 | 3.91 × ·10−5 | 5.20 × 10−2 | 0.9924 | ||
All data | 1.11 × 10−8 | 3.19 × 10−5 | 4.78 × 10−2 | 0.9911 |
Parameters | Panasonic NCA | Samsung NMC | KeepPower LCO |
---|---|---|---|
B coefficient | 4.697 | 1.26 | 2.786 |
R-square | 0.993 | 0.991 | 0.993 |
RMSE | 1.04 | 0.662 | 0.632 |
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Buidin, T.I.C.; Mariasiu, F. Parametric Evaluation of Thermal Behavior for Different Li-Ion Battery Chemistries. Batteries 2022, 8, 291. https://doi.org/10.3390/batteries8120291
Buidin TIC, Mariasiu F. Parametric Evaluation of Thermal Behavior for Different Li-Ion Battery Chemistries. Batteries. 2022; 8(12):291. https://doi.org/10.3390/batteries8120291
Chicago/Turabian StyleBuidin, Thomas Imre Cyrille, and Florin Mariasiu. 2022. "Parametric Evaluation of Thermal Behavior for Different Li-Ion Battery Chemistries" Batteries 8, no. 12: 291. https://doi.org/10.3390/batteries8120291