Influence of Ceria Addition on Crystallization Behavior and Properties of Mesoporous Bioactive Glasses in the SiO2–CaO–P2O5–CeO2 System
Abstract
:1. Introduction
2. Results and Discussion
2.1. Phase Evaluation in the G(0/1/5)Ce Gels
2.2. DTA/DTG/TG Analysis of the G(0/1/5)Ce Gels
2.3. Phase Identification in the Devitrified Ce-Containing MBGs
2.4. Crystallization Behavior of the Stabilized Ce-Containing MBGs
2.5. Bioactivity of the MBG5Ce_T
3. Conclusions
4. Materials and Methods
4.1. Materials
4.2. Sol–Gel Preparation Methods
4.3. Bioactivity of the Devitrified Glasses
4.4. Characterization
4.4.1. Thermal Characterization
4.4.2. Structural Characterization
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Gel Code | Stage No | ΔT/°C | Mass/% | Assignment | Total Loss/% |
---|---|---|---|---|---|
0Ce | 1 | 25–132 | 6.30 | Physically absorbed water [34,35] | 59.91 |
2 | 132–234 | 16.16 | Chemisorbed water and organic oxidation [13] | ||
3 | 234–301 | 18.05 | |||
4 | 301–497 | 18.93 | Pluronic and nitrate decomposition [26,35] | ||
1Ce | 1 | 25–134 | 7.14 | Physically absorbed water | 58.39 |
2 | 134–236 | 16.63 | Chemisorbed water and organic oxidation | ||
3 | 236–298 | 12.94 | |||
4 | 298–390 | 13.85 | Pluronic and nitrate decomposition | ||
5 | 390–640 | 6.96 | |||
5Ce | 1 | 25–106 | 3.39 | Physically absorbed water | 60.85 |
2 | 106–227 | 20.17 | Chemisorbed water and organic oxidation | ||
3 | 227–293 | 16.11 | |||
4 | 293–620 | 20.04 | Pluronic and nitrate decomposition |
MBG Code | Tc1 (°C/Phases) | Tc2 (°C/Phases) | Tc3 (°C/Phases) |
---|---|---|---|
0Ce | 878/ | 951/ | 1012/ |
A (68.01%), W (20.72%) PW (11.27%) | A (68.34%), W (10.04%), PW (21.62%) | A (70.98), W (17.69%), PW (11.33%) | |
1Ce | 865/ | 900/ | - |
A (90.10%), W (9.90%) | A (85.88%), W (15.12%) | ||
5Ce | 830/ | 876/ | 906/ |
A (38.21%), C (14.10%), PW (47.68) | A (54.15%, C (13.41%) | A (59.05%), C (7.80%), PW (33.14%) | |
PW (32.44%) |
Sample | Intercept | Slope | Ea | n | R2 |
---|---|---|---|---|---|
MBG0Ce | 64.5969 | 87.8985 ± 5.22 | 730.82 ± 43.40 | 1.5979 | 0.9860 |
MBG1Ce | 64.9096 | 87.2713 ± 3.23 | 725.61 ± 26.85 | 1.8879 | 0.9959 |
MBG5Ce | −44.7813 | 62.2325 ± 3.17 | 517.43 ± 26.35 | 1.1871 | 0.9922 |
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Anghel, E.M.; Petrescu, S.; Mocioiu, O.C.; Cusu, J.P.; Atkinson, I. Influence of Ceria Addition on Crystallization Behavior and Properties of Mesoporous Bioactive Glasses in the SiO2–CaO–P2O5–CeO2 System. Gels 2022, 8, 344. https://doi.org/10.3390/gels8060344
Anghel EM, Petrescu S, Mocioiu OC, Cusu JP, Atkinson I. Influence of Ceria Addition on Crystallization Behavior and Properties of Mesoporous Bioactive Glasses in the SiO2–CaO–P2O5–CeO2 System. Gels. 2022; 8(6):344. https://doi.org/10.3390/gels8060344
Chicago/Turabian StyleAnghel, Elena Maria, Simona Petrescu, Oana Catalina Mocioiu, Jeanina Pandele Cusu, and Irina Atkinson. 2022. "Influence of Ceria Addition on Crystallization Behavior and Properties of Mesoporous Bioactive Glasses in the SiO2–CaO–P2O5–CeO2 System" Gels 8, no. 6: 344. https://doi.org/10.3390/gels8060344