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Inorganics 2018, 6(1), 6; https://doi.org/10.3390/inorganics6010006

Synthesis of a α-Chlorosilyl Functionalized Donor-Stabilized Chlorogermylene

1
Tata Institute for Fundamental Research Hyderabad Gopanpally, Hyderabad-500107, Telangana, India
2
Krupp-Chair of General and Inorganic Chemistry, Saarland University, 66123 Saarbrücken, Germany
*
Authors to whom correspondence should be addressed.
Received: 8 December 2017 / Revised: 23 December 2017 / Accepted: 25 December 2017 / Published: 29 December 2017
(This article belongs to the Special Issue Coordination Chemistry of Silicon)
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Abstract

Peripherally functionalized low-valent main group species allow for the introduction/interconversion of functional groups without increasing the formal oxidation state of the main group center. Herein, we report a straightforward method for the incorporation of a α-chlorosilyl moiety adjacent to the NHC-coordinated germanium(II) center. View Full-Text
Keywords: silylene; germylene; N-heterocyclic carbene; oxidative addition silylene; germylene; N-heterocyclic carbene; oxidative addition
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Dhara, D.; Huch, V.; Scheschkewitz, D.; Jana, A. Synthesis of a α-Chlorosilyl Functionalized Donor-Stabilized Chlorogermylene. Inorganics 2018, 6, 6.

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