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Inorganics 2017, 5(4), 67; https://doi.org/10.3390/inorganics5040067

Optimization of Electrochemical Performance of LiFePO4/C by Indium Doping and High Temperature Annealing

1
Department of Physics and Astronomy, Wayne State University, Detroit, MI 48202, USA
2
Indian Institute of Technology, Jodhpur 342011, India
3
Universidade de Brasilia, Instituto de Fisica, Brasilia, DF 70919-970, Brazil
4
Department of Physics, Kettering University, Flint, MI 48504, USA
5
Department of Natural Sciences, University of Michigan-Dearborn, Dearborn, MI 48128, USA
6
Electrical and Computer Engineering, Wayne State University, Detroit, MI 48202, USA
*
Author to whom correspondence should be addressed.
Received: 11 August 2017 / Revised: 16 September 2017 / Accepted: 2 October 2017 / Published: 10 October 2017
(This article belongs to the Special Issue Novel Lithium Battery Electrode Materials)
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Abstract

We have prepared nano-structured In-doped (1 mol %) LiFePO4/C samples by sol–gel method followed by a selective high temperature (600 and 700 °C) annealing in a reducing environment of flowing Ar/H2 atmosphere. The crystal structure, particle size, morphology, and magnetic properties of nano-composites were characterized by X-ray diffraction (XRD), scanning electron microsopy (SEM), transmission electron microscopy (TEM), and 57Fe Mössbauer spectroscopy. The Rietveld refinement of XRD patterns of the nano-composites were indexed to the olivine crystal structure of LiFePO4 with space group Pnma, showing minor impurities of Fe2P and Li3PO4 due to decomposition of LiFePO4. We found that the doping of In in LiFePO4/C nanocomposites affects the amount of decomposed products, when compared to the un-doped ones treated under similar conditions. An optimum amount of Fe2P present in the In-doped samples enhances the electronic conductivity to achieve a much improved electrochemical performance. The galvanostatic charge/discharge curves show a significant improvement in the electrochemical performance of 700 °C annealed In-doped-LiFePO4/C sample with a discharge capacity of 142 mAh·g−1 at 1 C rate, better rate capability (~128 mAh·g−1 at 10 C rate, ~75% of the theoretical capacity) and excellent cyclic stability (96% retention after 250 cycles) compared to other samples. This enhancement in electrochemical performance is consistent with the results of our electrochemical impedance spectroscopy measurements showing decreased charge-transfer resistance and high exchange current density. View Full-Text
Keywords: Lithium iron phosphate; conductive Fe2P; indium doping Lithium iron phosphate; conductive Fe2P; indium doping
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Kumar, A.; Bashiri, P.; Mandal, B.P.; Dhindsa, K.S.; Bazzi, K.; Dixit, A.; Nazri, M.; Zhou, Z.; Garg, V.K.; Oliveira, A.C.; Vaishnava, P.P.; Naik, V.M.; Nazri, G.-A.; Naik, R. Optimization of Electrochemical Performance of LiFePO4/C by Indium Doping and High Temperature Annealing. Inorganics 2017, 5, 67.

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