Metal-Organic Cages Based on Phosphorescent Organometallics
Abstract
:1. Introduction
2. Metal-Organic Cages Based on Phosphorescent Organometallics
2.1. Phosphorescent MOCs Incorporating d6 Metal Ion
2.2. Phosphorescent MOCs Incorporating d8 Metal Ion
2.3. Phosphorescent MOCs Incorporating d10 Metal Ion
3. Conclusions and Prospect
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Entry | MOCs | (Metallo) Ligand | Node Precursor | λem (nm) a | ΦPL (%) | τPL (ns) | Applications |
---|---|---|---|---|---|---|---|
1 | MOC-Ru-1 [25] [Ru4] (PF6)6 | - | Ru1 | 745 | 1 | 135 | - g |
2 | MOC-Ru-2 [26] [L4 Ru6]Cl12 | 2 | Ru3 | 577 689 b | <0.1 | 2, 790 | - g |
3 | MOC-Ru-3 [27] [Ru8Pd6] (BF4)28 | Ru4 | [Pd(MeCN)4](BF4)2 | 610 c | - g | 484 | Photocatalysis and bio-imaging |
4 | MOC-Ru-4a [28] [Ru4Pd8] (PF6)24 | Ru5 | 640 | - g | 1.21 | - g | |
5 | MOC-Ru-5 [29] [Ru8Pd4] (BF4)24 | Ru7 | [Pd(MeCN)4] (BF4)2 | 710 d | 6.9 | 151 and 700 h | - g |
6 | MOC-Ru-6a [30] [Ru4Pd2] (BF4)12 | Ru8 | [Pd(MeCN)4] (BF4)2 | 638 e | 2.6 | 659 | - g |
7 | MOC-Ru-7b [31] [Ru4Pd2] (BF4)12 | Ru11 | [Pd(MeCN)4] (BF4)2 | 640 c | 66 | - g | - g |
8 | MOC-Ir-8 [32] [L4Ir6] (OTF)6 | 12 | Ir13 | 575 f | 4 | - g | - g |
9 | MOC-Ir-9 [33] [Ir8Pd4] (BF4)16 | Ir14 | [Pd(MeCN)4](BF4)2 | 9a 655, d 9b 569 d | 9a 5, 9b 14 | 9a 202 9b 825 | - g |
10 | MOC-Ir-10 [34] [L2Ir3] (PF6)3 | 15 | Ir16 | 10a 604, d 10b 485 d | 10a 1, 10b 15 | 10a 59 and 129, h 10b 523 and 887 h | - g |
11 | MOC-Ir-11 [35] [Ir8Pd4] (BF4)16 | Ir17 | [Pd(MeCN)4](BF4)2 | 658 c | 3.5 | 141 | Bio-imaging and photodynamic therapy |
12 | MOC-Os-12 [36] [L12(Os)4(Cd)4] (ClO4)16 | OsCl3·3H2O Cd(ClO4)2·6H2O | 625 | 2.5 | 156 and 73 h | - g | |
13 | MOC-Pt-13b [37] [Pt2Pt2] (OTf)4 | Pt18b | 527 | 16.7 | 15,500 | - g | |
14 | MOC-Pt-14 [14] [Pt6Zn4] (PF6)8 | Pt19 | Zn(NO3)2·6H2O | 545 | 10 | 95,000 | - g |
15 | MOC-Pt-16 [38] [Pt6Cd12] (PF6)36 | Pt20 | Cd(NO3)2 | 567 | - g | 218 | - g |
16 | MOC-Au-17 [39] [L4Au6Br] (SbF6)5 | Chloro(tetrahydrothiophene) gold KBr | 485 | - g | 10 | - g |
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Yu, Y.; Wang, X.; Liu, Y.; Zou, C. Metal-Organic Cages Based on Phosphorescent Organometallics. Inorganics 2023, 11, 436. https://doi.org/10.3390/inorganics11110436
Yu Y, Wang X, Liu Y, Zou C. Metal-Organic Cages Based on Phosphorescent Organometallics. Inorganics. 2023; 11(11):436. https://doi.org/10.3390/inorganics11110436
Chicago/Turabian StyleYu, Yunliang, Xiaoxia Wang, Yuliang Liu, and Chao Zou. 2023. "Metal-Organic Cages Based on Phosphorescent Organometallics" Inorganics 11, no. 11: 436. https://doi.org/10.3390/inorganics11110436