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Article

Energy Levels, Lifetimes, and Transition Properties for N iiiv

1
School of Electronic Information and Electrical Engineering, Huizhou University, Huizhou 516007, China
2
State Key Laboratory of Solar Activity and Space Weather, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100190, China
*
Author to whom correspondence should be addressed.
Atoms 2025, 13(6), 49; https://doi.org/10.3390/atoms13060049
Submission received: 8 May 2025 / Revised: 24 May 2025 / Accepted: 1 June 2025 / Published: 6 June 2025
(This article belongs to the Special Issue Atomic and Molecular Data and Their Applications: ICAMDATA 2024)

Abstract

We present excitation energies, transition wavelengths, electric dipole (E1) transition rates, oscillator strengths, line strengths, and lifetimes for the 86 lowest states up to and including 1s22s27f in N iii, the 125 lowest states up to and including 1s22s7f in N iv, and the 53 lowest states up to 1s28g in N v using the multiconfiguration Dirac–Hartree–Fock (MCDHF) and relativistic configuration interaction (RCI) methods. The computed results are then compared with data from the Atomic Spectra Database of the National Institute of Standards and Technology (NIST-ASD), experimental results, and other theoretical studies. For all levels in N iiiv, the root mean square energy differences from the NIST values are 130, 103, and 6 cm1, respectively. Compared to previous multiconfiguration Hartree–Fock and the Breit–Pauli (MCHF-BP) calculations, 89.3%, 98.5%, and 100% of the log(gf) values for N iiiv agree within 5%, respectively.
Keywords: atomic data; transition probabilities; oscillator strength; lifetime atomic data; transition probabilities; oscillator strength; lifetime

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MDPI and ACS Style

Li, M.; Du, J.; Huang, K.; Li, W. Energy Levels, Lifetimes, and Transition Properties for N iiiv. Atoms 2025, 13, 49. https://doi.org/10.3390/atoms13060049

AMA Style

Li M, Du J, Huang K, Li W. Energy Levels, Lifetimes, and Transition Properties for N iiiv. Atoms. 2025; 13(6):49. https://doi.org/10.3390/atoms13060049

Chicago/Turabian Style

Li, Meichun, Juan Du, Kaijian Huang, and Wenxian Li. 2025. "Energy Levels, Lifetimes, and Transition Properties for N iiiv" Atoms 13, no. 6: 49. https://doi.org/10.3390/atoms13060049

APA Style

Li, M., Du, J., Huang, K., & Li, W. (2025). Energy Levels, Lifetimes, and Transition Properties for N iiiv. Atoms, 13(6), 49. https://doi.org/10.3390/atoms13060049

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