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Open AccessArticle

The Tribocorrosion and Corrosion Properties of Thermally Oxidized Ti6Al4V Alloy in 0.9 wt.% NaCl Physiological Saline

by 1, 1,*, 1,2 and 3
School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266033, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Author to whom correspondence should be addressed.
Coatings 2018, 8(8), 285;
Received: 13 June 2018 / Revised: 9 August 2018 / Accepted: 12 August 2018 / Published: 16 August 2018
(This article belongs to the Special Issue Nanocomposite Coatings)
Thermal oxidation of Ti6Al4V was carried out at 700 °C for 5 h in air atmosphere. The characteristics of morphology and structure, micro-hardness, and tribocorrosion behavior in 0.9 wt.% NaCl solution of thermally oxidized Ti6Al4V alloys were investigated and compared with those of the untreated one. The scanning electron microscope (SEM) and glow discharge spectrometer (GDS) results reveal that the oxide layer is completely coated on the substrate, which is a bilayer structure consisted of oxide film and oxygen diffusion zone (ODZ). X-ray diffraction (XRD) and Raman measurements reveal the rutile phase as the dominant phase. The micro-hardness and surface roughness (Ra) increase about 1.63 and 4 times than those of the untreated one. Thermally oxidized sample obtains corrosion and tribocorrosion resistance property in 0.9 wt.% NaCl solution. The corrosion potential has a more than 500 mV anodic shift, the corrosion current density decreases about 80%. The total material loss volume is reduced by almost an order of magnitude under tribocorrosion behavior, which is due to the improvement of the micro-hardness of the oxide layer and ODZ that reduce the corrosion and the synergistic effect of corrosion and wear. View Full-Text
Keywords: Ti6Al4V; thermal oxidation; tribocorrosion; corrosion; wear Ti6Al4V; thermal oxidation; tribocorrosion; corrosion; wear
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Cao, L.; Wan, Y.; Yang, S.; Pu, J. The Tribocorrosion and Corrosion Properties of Thermally Oxidized Ti6Al4V Alloy in 0.9 wt.% NaCl Physiological Saline. Coatings 2018, 8, 285.

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