Influence of Zn+2 Doping on Ni-Based Nanoferrites; (Ni1−x ZnxFe2O4)
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. XRD Analysis
3.2. FT-IR Spectroscopy Analysis
3.3. Thermal Stability
3.4. BET Surface Area Analysis
3.5. Electrical Properties
3.5.1. Dielectric Constant
3.5.2. Dielectric Loss Tangent
3.5.3. AC Conductivity (Ϭac)
3.5.4. Impedance Spectroscopy
3.5.5. Complex Impedance Spectrum Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Zinc Concentration | Crystallite Size, D (nm) | Lattice Constant, (Å) | Lattice Strain% | Px g/cm3 | Px g/cm3 | Porosity % |
---|---|---|---|---|---|---|
0 | 21.3 | 8.32 | 0.631 | 5.40 | 3.76 | 31 |
0.25 | 30 | 8.40 | 0.377 | 6.71 | 3.79 | 44 |
0.5 | 35.5 | 8.42 | 0.416 | 6.67 | 3.81 | 43 |
0.75 | 53.1 | 8.44 | 0.215 | 6.62 | 3.77 | 44 |
1 | 70.6 | 8.45 | 0.162 | 5.30 | 3.86 | 27 |
X | 0 | 0.25 | 0.5 | 0.75 | 1 |
---|---|---|---|---|---|
Tetrahedral band | 586.99 | 587.08 | 586.48 | 556.89 | 580.30 |
Octahedral band | 374.33 | 381.11 | 372.90 | 383.24 | 364.77 |
Sr. No | Ni1−xZnxFe2O4 | BET Surface Area m2/g | Specific Surface Area SBET (m2/g) | DBET |
---|---|---|---|---|
1 | NiFe2O4 | 46.4871 | 52.1 | 21.32 |
2 | Ni0.75Zn0.25 Fe2O4 | 28.2980 | 29.80 | 30.41 |
3 | Ni0.5Zn0.5Fe2O4 | 19.5481 | 25.33 | 36 |
4 | Ni0.25Zn0.75Fe2O4 | 17.4112 | 17.06 | 52.41 |
5 | ZnFe2O4 | 17.3383 | 16.03 | 66 |
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Khan, S.B.; Irfan, S.; Lee, S.-L. Influence of Zn+2 Doping on Ni-Based Nanoferrites; (Ni1−x ZnxFe2O4). Nanomaterials 2019, 9, 1024. https://doi.org/10.3390/nano9071024
Khan SB, Irfan S, Lee S-L. Influence of Zn+2 Doping on Ni-Based Nanoferrites; (Ni1−x ZnxFe2O4). Nanomaterials. 2019; 9(7):1024. https://doi.org/10.3390/nano9071024
Chicago/Turabian StyleKhan, Sadaf Bashir, Syed Irfan, and Shern-Long Lee. 2019. "Influence of Zn+2 Doping on Ni-Based Nanoferrites; (Ni1−x ZnxFe2O4)" Nanomaterials 9, no. 7: 1024. https://doi.org/10.3390/nano9071024