Next Article in Journal
Enhanced Visible-Light Photocatalytic Activity of Ag QDs Anchored on CeO2 Nanosheets with a Carbon Coating
Previous Article in Journal
Antireflection Enhancement by Composite Nanoporous Zeolite 3A–Carbon Thin Film
Open AccessCommunication

Methane-Mediated Vapor Transport Growth of Monolayer WSe2 Crystals

School of Advanced Materials Science and Engineering and SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University (SKKU), 2066, Seobu-Ro, Jangan-Gu, Suwon-Si, Gyeonggi-Do 16419, Korea
Department of Energy Systems Research and Department of Materials Science and Engineering, Ajou University, Suwon, Gyeonggi-Do 16499, Korea
Department of Physics, Mokpo National University, Muan-gun, Jeollanam-Do 58554, Korea
Authors to whom correspondence should be addressed.
These authors contributed equally to this work.
Nanomaterials 2019, 9(11), 1642;
Received: 28 October 2019 / Revised: 8 November 2019 / Accepted: 13 November 2019 / Published: 19 November 2019
(This article belongs to the Section Nanocomposite Thin Films and 2D Materials)
The electrical and optical properties of semiconducting transition metal dichalcogenides (TMDs) can be tuned by controlling their composition and the number of layers they have. Among various TMDs, the monolayer WSe2 has a direct bandgap of 1.65 eV and exhibits p-type or bipolar behavior, depending on the type of contact metal. Despite these promising properties, a lack of efficient large-area production methods for high-quality, uniform WSe2 hinders its practical device applications. Various methods have been investigated for the synthesis of large-area monolayer WSe2, but the difficulty of precisely controlling solid-state TMD precursors (WO3, MoO3, Se, and S powders) is a major obstacle to the synthesis of uniform TMD layers. In this work, we outline our success in growing large-area, high-quality, monolayered WSe2 by utilizing methane (CH4) gas with precisely controlled pressure as a promoter. When compared to the catalytic growth of monolayered WSe2 without a gas-phase promoter, the catalytic growth of the monolayered WSe2 with a CH4 promoter reduced the nucleation density to 1/1000 and increased the grain size of monolayer WSe2 up to 100 μm. The significant improvement in the optical properties of the resulting WSe2 indicates that CH4 is a suitable candidate as a promoter for the synthesis of TMD materials, because it allows accurate gas control. View Full-Text
Keywords: TMD; 2D material; WSe2; monolayer; methane promoter; single-crystal TMD; 2D material; WSe2; monolayer; methane promoter; single-crystal
Show Figures

Graphical abstract

MDPI and ACS Style

Jang, H.-S.; Lim, J.-Y.; Kang, S.-G.; Hyun, S.-H.; Sandhu, S.; Son, S.-K.; Lee, J.-H.; Whang, D. Methane-Mediated Vapor Transport Growth of Monolayer WSe2 Crystals. Nanomaterials 2019, 9, 1642.

Show more citation formats Show less citations formats
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Access Map by Country/Region

Back to TopTop