Next Article in Journal
Preparation and Application of Hybrid Nanomaterials
Previous Article in Journal
Development of a Sensitive Induction-Based Magnetic Nanoparticle Biodetection Method
Article Menu
Issue 11 (November) cover image

Export Article

Open AccessArticle

Poly(vinylidene fluoride) and Carbon Derivative Structures from Eco-Friendly MOF-5 for Supercapacitor Electrode Preparation with Improved Electrochemical Performance

Nanomaterials Physicochemistry Department, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Szczecin, Piastów Ave. 42, 71-065 Szczecin, Poland
*
Authors to whom correspondence should be addressed.
Nanomaterials 2018, 8(11), 890; https://doi.org/10.3390/nano8110890
Received: 3 October 2018 / Revised: 23 October 2018 / Accepted: 26 October 2018 / Published: 1 November 2018
  |  
PDF [10942 KB, uploaded 1 November 2018]
  |  

Abstract

Electrodes from carbonized Zn4O(1,4-benzodicarboxylic acid) (MOF-5) structures were prepared successfully via evaporating the solvent with a poly(vinylidene fluoride) (PVDF) binder. The solvent used for a nanocomposite cast was easily removed. Such an elegant method for preparing electrodes provides a facile, cost-effective, and void/cracking-free nanocomposite distribution on the current collector. The highly porous nanoparticles containing pure carbon attach well to the PVDF membrane which results in an increased active surface area of the electrode to 847 m2/g. The electrochemical analysis shows that the best weight ratio of CMOF-5 to PVDF equals 85:15, 80:20, and 75:25, respectively. The specific capacitance of these samples is 218 F/g, 210 F/g, and 180 F/g, correspondingly. An additional advantage of the electrode prepared from the carbonized MOF-5 is the possibility to synthesis MOF structures from recovered substrates used in its synthesis (distilled N,N-Dimethylformamide DMF and terephthalic acid recovered from polyethylene terephthalate waste). We will demonstrate this in this contribution as well. Furthermore, the carbonized MOF-5 can be recovered from the spent electrode and reused again in the electrochemical device. View Full-Text
Keywords: MOF-5 synthesis; MOF-5 synthesis from recycled DMF; supercapacitors; MOF-5 carbonization; electrode preparation MOF-5 synthesis; MOF-5 synthesis from recycled DMF; supercapacitors; MOF-5 carbonization; electrode preparation
Figures

Graphical abstract

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

Supplementary material

SciFeed

Share & Cite This Article

MDPI and ACS Style

Cendrowski, K.; Kukulka, W.; Kedzierski, T.; Zhang, S.; Mijowska, E. Poly(vinylidene fluoride) and Carbon Derivative Structures from Eco-Friendly MOF-5 for Supercapacitor Electrode Preparation with Improved Electrochemical Performance. Nanomaterials 2018, 8, 890.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Nanomaterials EISSN 2079-4991 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top