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Nanomaterials 2017, 7(11), 373; https://doi.org/10.3390/nano7110373

Synthesis of Ferrofluids Made of Iron Oxide Nanoflowers: Interplay between Carrier Fluid and Magnetic Properties

1
Dipartimento di Fisica e Scienze della Terra, Università di Ferrara, I- 44122 Ferrara, Italy
2
Dipartimento di Ingegneria Industriale, Università di Padova, I- 35131 Padova, Italy
3
Dipartimento di Scienze del Farmaco, Università di Padova, I- 35131 Padova, Italy
*
Author to whom correspondence should be addressed.
Received: 2 October 2017 / Accepted: 1 November 2017 / Published: 5 November 2017
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Abstract

Ferrofluids are nanomaterials consisting of magnetic nanoparticles that are dispersed in a carrier fluid. Their physical properties, and hence their field of application are determined by intertwined compositional, structural, and magnetic characteristics, including interparticle magnetic interactions. Magnetic nanoparticles were prepared by thermal decomposition of iron(III) chloride hexahydrate (FeCl3·6H2O) in 2-pyrrolidone, and were then dispersed in two different fluids, water and polyethylene glycol 400 (PEG). A number of experimental techniques (especially, transmission electron microscopy, Mössbauer spectroscopy and superconducting quantum interference device (SQUID) magnetometry) were employed to study both the as-prepared nanoparticles and the ferrofluids. We show that, with the adopted synthesis parameters of temperature and FeCl3 relative concentration, nanoparticles are obtained that mainly consist of maghemite and present a high degree of structural disorder and strong spin canting, resulting in a low saturation magnetization (~45 emu/g). A remarkable feature is that the nanoparticles, ultimately due to the presence of 2-pyrrolidone at their surface, are arranged in nanoflower-shape structures, which are substantially stable in water and tend to disaggregate in PEG. The different arrangement of the nanoparticles in the two fluids implies a different strength of dipolar magnetic interactions, as revealed by the analysis of their magnetothermal behavior. The comparison between the magnetic heating capacities of the two ferrofluids demonstrates the possibility of tailoring the performances of the produced nanoparticles by exploiting the interplay with the carrier fluid. View Full-Text
Keywords: magnetic nanoparticles; ferrofluids; thermal decomposition; nanoflower structure; spinel iron oxides; magnetic interactions; Mössbauer spectroscopy; magnetic heating; spin canting; superparamagnetism magnetic nanoparticles; ferrofluids; thermal decomposition; nanoflower structure; spinel iron oxides; magnetic interactions; Mössbauer spectroscopy; magnetic heating; spin canting; superparamagnetism
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Spizzo, F.; Sgarbossa, P.; Sieni, E.; Semenzato, A.; Dughiero, F.; Forzan, M.; Bertani, R.; Del Bianco, L. Synthesis of Ferrofluids Made of Iron Oxide Nanoflowers: Interplay between Carrier Fluid and Magnetic Properties. Nanomaterials 2017, 7, 373.

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