Aqueous MXene-Assisted Charge Transport for Sliding Cu/n-Si DC Triboelectric Nanogenerators

This study explores the influence of MXene solution as an interfacial liquid on the output performance of a Cu/n-Si-based direct current triboelectric nanogenerator (DC-TENG) system. The ${\mathrm{Ti}}_3{\mathrm{AlC}}_2$ MAX phase was successfully transformed into ${\mathrm{Ti}}_3{\mathrm{C}}_2{\mathrm{T}}_{\mathrm{x}}$ MXene through selective etching and was confirmed by scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS) and X-ray diffraction (XRD) analyses, which revealed an increase in d-spacing from 8.99 to 9.58 Å and a transition from dense layered grains to delaminated, sheet-like structures. Electrochemical impedance spectroscopy (EIS) demonstrated a pronounced reduction in impedance with the introduction of MXene solution, indicating enhanced interfacial conductivity and charge transfer capability. The presence of MXene in deionized (DI) water led to the formation of an electrical double layer (EDL) at the Cu/n-Si interface, contributing to additional interfacial capacitance and more efficient charge relaxation dynamics. As a result, the DC-TENG output was significantly enhanced with the incorporation of MXene into the system, exhibiting a markedly higher current compared to the dry contact condition. Moreover, the MXene solution helped suppress charge decay compared to dry interfaces, highlighting its role as an effective liquid medium for stabilizing surface charge and improving interfacial electron transport in DC-TENG systems.