A Review on Recent Advancements of Ni-NiO Nanocomposite as an Anode for High-Performance Lithium-Ion Battery
Abstract
:1. Introduction
2. Working of the Lithium-Ion Battery
3. Anode Materials
4. Nanocomposite NiO as Anode of LIB
4.1. Nanocomposite of NiO with Carbon
4.2. Nanocomposite of NiO with Graphene Nanosheet
4.3. Nanocomposite of NiO with Carbon Nanotube (CNT)
4.4. Nanocomposite of NiO with Reduced Graphene Oxide
4.5. Nanocomposite of NiO with Ni
5. Conclusions
- As compared to commercial graphite, NiO has two times higher specific capacity, is environmentally friendly, and has high stability. When NiO is incorporated with carbon to synthesize nanocomposite it shows enhanced cycling performance. In addition, NiO with CNT, MWCNT, RGO, GNS, HCS, etc. exhibited remarkable improvements in performance because these carbon structures provide cushioning and act as a support matrix, hence improving the conductivity as well as impeding the detachment of active material from the electrode.
- The doping of Ni into NiO causes the formation of Ni-NiO nanocomposite which facilitates the ionic conductivity of the material due to the presence of metallic Ni within the structure. The presence of metallic nickel assists the reverse reaction during charging decomposition of SEI and Li2O. The incorporation of Ni into NiO shows better electrochemical performance than the carbonaceous compound.
- When Ni-NiO nanocomposite powder is used as anode the powder structure can smoothly buffer the volume change as a result of continuous expansion/contraction. Therefore, performance enhancement and increased conductivity can be observed. The electrode surface area, electrode/electrolyte contact, and short Li+ diffusion distance can be increased due to the nanocomposite structure.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Materials | Specific Capacity (mAh g−1) | Remarks | Ref. |
---|---|---|---|
Si/graphite composite with polymer microsphere | Charge and discharge capacity of 1493 mAh g−1 and 1091 mAh g−1, respectively with 73.0% 1st cycle coulombic efficiency. | The capacity drops rapidly with continuous cycling and became approx. 790 mAh g−1 at 50 cycles. | [46] |
Si/porous-C composite with voids | A reversible capacity of 980 mAh g−1 after 80 cycles, little capacity decay per cycle (0.17%), excellent rate capability of 721 mAh g−1 at a high current density of 2000 mA g−1. | Rapid capacity depletion as a result of crack formation and mechanical degradation of active electrode material over cycling. | [47] |
3D-Carbon fiber/Si nanocomposite | The reversible capacity in the 1st cycle at a 0.05 C rate was between 2.5 Ah g−1 and 3 Ah g−1. | High reversible specific capacity, low cyclability. | [48] |
Raspberry-like HSi/C nanocomposite | Reversible specific capacity of 886.2 mAh g−1 at 0.5 A g−1 current density after 200 cycles with high rate capability and cycle ability of 516.7 mAh g−1 at 2 A g−1 after 500 cycles. | The specific capacity decreases rapidly with cycling and increasing current density and electrodes become pulverized. | [49] |
Si/graphene nanocomposite | The initial discharge capacity of 769 mAh g−1, at 4000 mA g−1 current rate. | Improved reversible specific capacity, low initial capacity, capacity decreased with high C-rate. | [50] |
Dual yolk-shell Si/C structure | Stable specific capacity of 956 mAh g−1 at 0.46 A g−1 after 430 cycles with 83% capacity retention. | Reversible capacity, capacity drastically decays with cycling. | [51] |
Materials | Specific Capacity (mAh g−1) | Remarks | Ref. |
---|---|---|---|
NiO-C nanocomposite | A high initial capacity of 1102 mAh g−1. After 50 cycles, 37% of initial discharge capacity was retained. | High initial specific capacity, small capacity retention ability. | [102] |
Net-structured NiO-C | A reversible capacity of 429 mAh g−1 even after 40 cycle at 71.8 mA g−1 current density. | Stable cycle performance due to carbon inclusion. | [140] |
Spherical shaped NiO-C nanocomposite | High specific capacity of 430 mAh g−1 after 40 cycles with 66.6% initial coulombic efficiency at 0.5C rate. | Good cyclic performance and high initial coulombic efficiency. | [103] |
NiO/C nanocomposite | A high reversible capacity of 585.9 mAh g−1 after 50 cycles. | High specific discharge, remarkable cyclic stability and good rate performance. | [104] |
Egg shell-yolk structured NiO/C porous composite | The first specific discharge capacity was 1175.2 mAh g−1 with 0.22 V discharge voltage. It maintained 625.3 mAh g−1 capacity after 100 cycles. | High capacity retention ability, good rate capability. | [105] |
NiO/C nanocapsules | Initial discharge capacity of 1689.4 mAh g−1 at 0.5 C rate with a high reversible capacity of 1157.7 mAh g−1 after 50 cycles. | Outstanding discharge capacity, high rate capability, and exceptional cycling stability | [106] |
3D-hierarchical NiO-graphene nanosheet (GNS) composite | A high specific discharge capacity of 1400 mAh g−1. Even after 50 cycles, the composite can retain 1065 mAh g−1 specific capacity at 200 mA g−1 current density. | High discharge capacity, outstanding rate performance. | [107] |
NiO nanowalls/GNS nanocomposites | A high reversible capacity of 844.9 mAh g−1 at 0.1C rate with little capacity fading of 7.1% after 50 cycles. | High capacity, cyclic stability and little capacity decay. | [108] |
NiO@hollow carbon sphere | The structure provides an initial reversible capacity of 598 mAh g−1 at 0.1A g−1 current density. Even after 400 cycles delivers discharge capacity of 243 mAh g−1 at high current density of 2 A g−1. | Outstanding reversible capacity, stable cycle performance and rate capability. | [109] |
Hollow nanospheric NiO/GCS | High reversible capacities of 1073.6 mAh g−1 and 966.6 mAh g−1 after 300 cycles at 0.5C and 1C rates | Highly reversible capacity, excellent cyclic performance and rate capability. | [110] |
NiO nanosheets@CMK-3 composite | The composite delivers discharge and charge capacity of 1641 and 1097 mAh g−1, merely 9.8% capacity fading after 50 cycles at a 400 mA g−1 rate. | High average specific capacity, remarkable cycling performance, excellent rate capacity. | [111] |
NiO/3DGF nanocomposite | It shows an extremely high reversible capacity of 1104 mAh g−1 at 0.2C rate after 250 cycles, and an excellent rate capability with 440 mAh g−1 specific capacity at 3C rate. | Highly reversible capacity, excellent rate performance, superior capacity retention. | [112] |
NiO–PPy composite | The initial reversible capacity was 638 mAh g−1, which became 436 mAh g−1 after 30 cycles. The composite can retain 66% of capacity after 30 cycles. | Low decay in reversible capacity, good cycle ability and capacity retention. | [114] |
Amorphous CNT-NiO nanosheet composite | A high discharge capacity of 1034 mAh g−1 was delivered after 300 cycles at a relatively 800 mA g−1 current density and 98.1% coulombic efficiency | High discharge capacity, coulombic efficiency, and high specific reversible capacity. | [117] |
3D G-CNT-Ni nanostructures | It exhibited an initial capacity of 2395.2 mAh g−1 with a high reversible capacity of 648.2 mAh g−1 after 50 cycles. | High initial capacity, excellent stability, high reversible capacity. | [119] |
MWCNT/NiO nanocomposite | Initial discharge and charge capacities of 1083.8 and 720.2 mAh g−1, respectively, with 66.45% coulombic efficiency. This sample maintained a stable ~800 mAh g−1 discharge capacity and 97% coulombic efficiency after 50 cycles. | High coulombic efficiency, stable discharge capacity, excellent cyclability. | [120] |
NiO-G-CNTs nanohybrid composite | The nanohybrids delivered an initial discharge capacity of 1515.1 mAh g−1, a stable reversible specific capacity of 1022 mAh g−1, also after 50 cycles, a specific capacity of 858.1 mAh g−1 at 100 mA g−1 current density. | High initial discharge, stable reversible capacity, remarkable cycle stability and rate performance. | [121] |
Biochar-CNT-NiO composite | An initial discharge capacity of 981.0 mAh g−1 with 65.18% coulombic efficiency. | Highly stable cycle performance, outstanding rate capacity. | [122] |
RGO/NiO composite | The initial specific discharge/charge capacities were of 1641 mAh g−1 and 1097 mAh g−1, respectively, with 1041 mAh g−1 specific discharge capacity after 50 cycles at 100 mA g−1 current density and an excellent rate capacity of 727 mAh g−1 at 1600 mA g−1 current density. | High initial specific capacities, highly stable cycle performance and rate capability. | [97] |
rGO/NiO nanosheet composite | Specific discharge/charge capacity of 1570 and 1193 mAh g−1 with 75.6% coulombic efficiency. | High coulombic efficiency, remarkable rate capability, high cycle stability. | [123] |
NiO/rGO composite | It exhibited high reversible capacity of 1036.8 mAh g−1, even after 50 cycles. | High reversible capacity, can retain capacity closed to initial capacity. | [125] |
3D NiO-Ni nanowire composite | The composite offered a capacity of 827 mAh g−1 at 10th cycle, at 100 mA g−1 current density. At the 40th cycle the specific capacity reaches 424 mAh g−1, at 1000 mA g−1 current density, with a stable capacity retention up to 900 mAh g−1 | Highly stable cyclability, high capacity retention ability. | [132] |
3D-flower-like NiO/Ni nanocomposite | The Ni-doped NiO/Ni nanocomposite exhibited discharge/charge of 1316 mAh g−1 and 898 mAh g−1, respectively. | Stable reversible capacity, better capacity retention, superior cyclability, and rate performance | [137] |
NiO-Ni nanocomposite | The first discharge capacity of 1152.4 mAh g−1 with 71.2% coulombic efficiency. | Higher reversible capacities and cycling ability | [138] |
Spherical NiO/Ni nanocomposite | A high specific capacity of 800 mAh g−1 after 50 cycles, at a current density of 0.1C. with a reversible capacity of 450 mAh g−1, even at 5C rate, and 635 mAh g−1 capacity for 300 cycles at 2C, at 50 °C temperature. | High reversible capacity, excellent rate capability, and significantly long cycle stability. | [139] |
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Siddiqui, S.-E.-T.; Rahman, M.A.; Kim, J.-H.; Sharif, S.B.; Paul, S. A Review on Recent Advancements of Ni-NiO Nanocomposite as an Anode for High-Performance Lithium-Ion Battery. Nanomaterials 2022, 12, 2930. https://doi.org/10.3390/nano12172930
Siddiqui S-E-T, Rahman MA, Kim J-H, Sharif SB, Paul S. A Review on Recent Advancements of Ni-NiO Nanocomposite as an Anode for High-Performance Lithium-Ion Battery. Nanomaterials. 2022; 12(17):2930. https://doi.org/10.3390/nano12172930
Chicago/Turabian StyleSiddiqui, Safina-E-Tahura, Md. Arafat Rahman, Jin-Hyuk Kim, Sazzad Bin Sharif, and Sourav Paul. 2022. "A Review on Recent Advancements of Ni-NiO Nanocomposite as an Anode for High-Performance Lithium-Ion Battery" Nanomaterials 12, no. 17: 2930. https://doi.org/10.3390/nano12172930