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Open AccessArticle

Development of PVDF Ultrafiltration Membrane with Zwitterionic Block Copolymer Micelles as a Selective Layer

IEM, Univ Montpellier, CNRS, ENSCM, 34095 Montpellier, France
R&D Center for Membrane Technology, Department of Chemical Engineering, Chung Yuan Christian University, Chung-Li, Taoyuan 32023, Taiwan
Author to whom correspondence should be addressed.
Membranes 2019, 9(8), 93;
Received: 11 July 2019 / Revised: 25 July 2019 / Accepted: 26 July 2019 / Published: 1 August 2019
(This article belongs to the Special Issue Block Copolymer-Based Membranes)
In recent years, block copolymer micellar assemblies with the formation of structured nanoparticles have been considered as an emerging technology in membrane science. In this work, the poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymer was directly synthesized using Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization and self-assembled in a selective medium (2,2,2-trifluroethanol/water). Then, poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymers were casted onto a commercial PVDF membrane to form a thin porous selective layer. The prepared nanoparticles and the resulting membranes were fully characterized using microscopy methods (SEM and AFM), whereas the membrane performance was evaluated in terms of permeability and the molecular weight cut off. The results from this study demonstrate the preparation of an ultrafiltration membrane made from the assembly of poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymer micelles on the top of a PVDF membrane in the form of thin film. The copolymer chain orientation leads to a membrane surface enriched in hydrophilic PSBMA, which confers a suitable behavior for aqueous solution filtration on the membrane, while preserving the high chemical and mechanical resistance of the PVDF. View Full-Text
Keywords: block copolymer; zwitterion; self-assembly; nanostructured membranes block copolymer; zwitterion; self-assembly; nanostructured membranes
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MDPI and ACS Style

Thankappan, H.; Bousquet, G.; Semsarilar, M.; Venault, A.; Chang, Y.; Bouyer, D.; Quemener, D. Development of PVDF Ultrafiltration Membrane with Zwitterionic Block Copolymer Micelles as a Selective Layer. Membranes 2019, 9, 93.

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