Optimization of Greenhouse Gas Accounting Methods for Wastewater Treatment Plants in East Chinese Regions: A Comparative Analysis of IPCC and Group Standards Based on 49 Plants in Shandong Province
Abstract
1. Introduction
2. Materials and Methods
2.1. Shandong Province’s WWTPs
2.2. Data Sources
2.3. Accounting Method
- (1)
- Measurement Method: This method obtains direct emission data through on-site air sampling and continuous monitoring, which offers high precision. However, it is limited by instrument sensitivity and maintenance costs, making it unsuitable to apply on a large scale.
- (2)
- Modeling Method: Based on biodynamic models that simulate microbial metabolic processes, this method can quantify the generation of GHG in specific processes. Nevertheless, the model parameters (such as nitrification/denitrification rates) require calibration with localized data, and the universality of this method is relatively poor.
- (3)
- Carbon Footprint Method: Using a life cycle assessment framework, this method accounts for both emissions throughout the entire process of WWTP construction, operation, and demolition. Although it can provide a basis for systemic emission reduction, it faces data availability issues during the construction phase, limiting its application scope.
- (4)
- Emission Factor Method: This method estimates carbon emissions by combining the activity level (such as electricity consumption) with the corresponding emission factor (such as CH4/kgCOD). It has the advantages of being easy to operate and applicable to regional assessments and is widely used for provincial-scale evaluations. However, the regional heterogeneity of emission factors (such as differences in processes and management levels) may lead to calculation deviations, necessitating dynamic corrections with local data.
- (1)
- IPCC 2019 Revised Edition: This is applicable for national-level carbon emission accounting. The accounting targets focus on the direct emissions of CO2, CH4, and N2O.
- (2)
- Technical Specification for Low-Carbon Operation Evaluation of WWTPs (T/CAEPI 49-2022 [26]): This document is targeted at the operation stage of WWTPs. It can directly calculate the emissions of CH4 and N2O, along with indirect emissions like those from electricity and chemical consumption (calculated in CO2 equivalents), providing a quantitative basis for low-carbon operation.
- (3)
- Standard for Carbon Emission Reduction Assessment of Urban WWTPs (T/CUWA 50055-2023) [27]: This document is based on a life cycle perspective, covering all stages from construction to operation and decommissioning. In addition to accounting for the emissions of fossil-derived CO2, CH4, and N2O during the operation stage, it also integrates calculation methods for the emission reduction thanks to low-carbon technologies such as heat pumps, photovoltaic applications, and sludge anaerobic fermentation.
- (1)
- Electricity Consumption: All three accounting methods use the latest 2021 China electricity carbon dioxide emission factor published to calculate the indirect emissions related to electricity consumption, ensuring consistency in the accounting of indirect emissions from electricity use.
- (2)
- Chemical Consumption: T/CAEPI 49-2022 and T/CUWA 50055-2023 use the chemical emission factors provided in their respective appendices for calculation. Specifically, T/CAEPI 49-2022 uses Table S9, and T/CUWA 50055-2023 uses Table S4 in Supplementary Materials. Since IPCC 2019 does not provide accounting parameters related to chemicals, the method for calculating indirect emissions from chemical consumption uniformly adopts the chemical emission factor method from T/CUWA 50055-2023.
3. Results and Discussion
3.1. Direct Carbon Emissions Assessed by Three Different Methods
3.1.1. Comparison of N2O Emission Calculations
3.1.2. Comparison of CH4 Emission Calculations Using Different Methods
3.1.3. Calculation of Fossil-Derived CO2 Emissions Using T/CUWA 50055-2023
3.2. Indirect Carbon Emissions Assessed Using Three Different Methods
3.2.1. Comparison of Chemical Carbon Emission Calculation Results Using T/CAEPI 49-2022 and T/CUWA 50055-2023
3.2.2. Carbon Emissions from the Energy Consumption of the 49 WWTPs
3.3. The Impact of Various Emission Intensities on the Total Emission Intensity
3.4. The Impact of Different Influencing Factors on Carbon Emissions in Wastewater Treatment
3.4.1. The Impact of Treatment Processes on Carbon Emissions
3.4.2. The Influence of Scale upon Carbon Emissions
3.4.3. The Impact of Influent Load Rate on Carbon Emissions
3.4.4. The Impact of Influent Water Quality and Emission Standards on Carbon Emissions
4. Conclusions
- (1)
- Methodological innovation and standard adaptability
- (2)
- Key emission characteristics and driving mechanisms
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Abbreviations
WWTPs | Wastewater treatment plant |
IPCC | United Nations Intergovernmental Panel on Climate Change |
GS 2023 | Group Standard 2023, T/CUWA 50055-2023 |
GS 2022 | Group Standard 2022, T/CAEPI 49-2022 |
COD | Chemical oxygen demand |
TN | Total nitrogen |
BOD | Biochemical oxygen demand |
TP | Total phosphorus |
AAO | Anaerobic-anoxic-oxic |
AO | Anaerobic-oxic |
OD | Oxidation ditch process |
UCT | University of Capetown |
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Accounting Items | IPCC 2019 | GS 2022 | GS 2023 |
---|---|---|---|
Pretreatment | √ | √ | √ |
Biological Treatment | √ | √ | √ |
In-Plant Sludge Dewatering | √ | √ | √ |
Off-Site Pipeline Networks | × | × | × |
Chemical Consumption | × (refer to GS 2023) | √ | √ |
Biogenic CO2 | × | × | × |
Fossil-Derived CO2 | × | × | √ |
Off-Site Sludge Disposal | × | × | × |
Applicability | Internationally applicable | Operation phase | Full life cycle |
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Wang, H.; Li, L.; Lin, Z.; Abulimiti, A.; Guan, M.; Zhao, T.; Tian, Y. Optimization of Greenhouse Gas Accounting Methods for Wastewater Treatment Plants in East Chinese Regions: A Comparative Analysis of IPCC and Group Standards Based on 49 Plants in Shandong Province. Appl. Sci. 2025, 15, 6175. https://doi.org/10.3390/app15116175
Wang H, Li L, Lin Z, Abulimiti A, Guan M, Zhao T, Tian Y. Optimization of Greenhouse Gas Accounting Methods for Wastewater Treatment Plants in East Chinese Regions: A Comparative Analysis of IPCC and Group Standards Based on 49 Plants in Shandong Province. Applied Sciences. 2025; 15(11):6175. https://doi.org/10.3390/app15116175
Chicago/Turabian StyleWang, Haoyu, Lipin Li, Zhengda Lin, Aliya Abulimiti, Ming Guan, Tianrui Zhao, and Yu Tian. 2025. "Optimization of Greenhouse Gas Accounting Methods for Wastewater Treatment Plants in East Chinese Regions: A Comparative Analysis of IPCC and Group Standards Based on 49 Plants in Shandong Province" Applied Sciences 15, no. 11: 6175. https://doi.org/10.3390/app15116175
APA StyleWang, H., Li, L., Lin, Z., Abulimiti, A., Guan, M., Zhao, T., & Tian, Y. (2025). Optimization of Greenhouse Gas Accounting Methods for Wastewater Treatment Plants in East Chinese Regions: A Comparative Analysis of IPCC and Group Standards Based on 49 Plants in Shandong Province. Applied Sciences, 15(11), 6175. https://doi.org/10.3390/app15116175