Mg,Sr-Cosubstituted Hydroxyapatite with Improved Structural Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthetic MgSr-HA Macro-Granules
2.2. The 3D Porous Scaffold of MgSr-HA
2.3. Characterizations of the Materials
2.3.1. Thermal Stability Analysis
2.3.2. XRD Analysis
2.3.3. Macro- and Microstructural Compositional Evaluation
2.3.4. Mechanical Characterization
3. Results and Discussion
3.1. Thermal Stability of As-Prepared Mg,Sr-Cosubstituted HA
3.2. Ion Exchange of Mg in Sr-HA Samples: “Subsequent Mg Substitution”
3.2.1. Development of the Process
3.2.2. Effectiveness of the Process
3.2.3. Evaluation of the Mechanical Properties of MgSr-HA
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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a (Å) | c (Å) | V (Å3) | |
---|---|---|---|
SrHA | 9.462 | 6.913 | 536.0 |
SM1d1 | 9.418 | 6.880 | 528.4 |
SM1d5 | 9.342 | 6.827 | 516.0 |
SM2d1 | 9.407 | 6.879 | 527.2 |
SM2d5 | 9.352 | 6.819 | 516.5 |
Ca (mol%) | P (mol%) | Mg (mol%) | Sr (mol%) | Ca/P | (cat)/P | Mg/Ca | Sr/Ca | Mg/Sr | |
---|---|---|---|---|---|---|---|---|---|
SrHA | 21.87 | 14.45 | - | 2.84 | 1.51 | 1.71 | - | 0.130 | - |
SM1d1 | 21.83 | 13.80 | 0.74 | 2.64 | 1.58 | 1.83 | 0.034 | 0.121 | 0.280 |
SM1d5 | 21.03 | 13.90 | 1.00 | 2.69 | 1.51 | 1.78 | 0.048 | 0.128 | 0.372 |
SM2d1 | 22.00 | 13.52 | 0.89 | 2.59 | 1.63 | 1.88 | 0.040 | 0.118 | 0.344 |
SM2d5 | 20.46 | 13.53 | 1.79 | 2.57 | 1.51 | 1.83 | 0.087 | 0.126 | 0.696 |
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Landi, E.; Guizzardi, S.; Papa, E.; Galli, C. Mg,Sr-Cosubstituted Hydroxyapatite with Improved Structural Properties. Appl. Sci. 2021, 11, 4930. https://doi.org/10.3390/app11114930
Landi E, Guizzardi S, Papa E, Galli C. Mg,Sr-Cosubstituted Hydroxyapatite with Improved Structural Properties. Applied Sciences. 2021; 11(11):4930. https://doi.org/10.3390/app11114930
Chicago/Turabian StyleLandi, Elena, Stefano Guizzardi, Elettra Papa, and Carlo Galli. 2021. "Mg,Sr-Cosubstituted Hydroxyapatite with Improved Structural Properties" Applied Sciences 11, no. 11: 4930. https://doi.org/10.3390/app11114930