3.1. Effect of Different Gas Compositions on Arc Shape
Figure 3 shows images of arc shapes for different gas compositions at 380 A preset current and 3.5 kW laser power. Under the protection of pure argon, the shape of the arc fluctuated greatly, and the overall shape of the arc was irregular, as shown in
Figure 3a. There were obvious bulges in the arc near the contact point, and the arc obviously deflected towards the laser.
Figure 3b indicates that the overall arc shape became more regular, and the shape of the arc fluctuation decreased when the CO
2 content reached 10%. Meanwhile, part of the arc at the lower wire end expanded to a certain extent. When the CO
2 content further increased to 18%, the overall arc shape shown in
Figure 3c was more regular, showing a bell shape. The size of the arc bottom is further expanded, and the arc stiffness increased. Compared to conventional welding technology such as FCAW [
22], the CWW process demonstrates a continuously improved arc morphology and regularity with CO
2 content increasing up to 18%, resulting in a broader stability window. Furthermore, in contrast to conventional GMAW processes which typically attain optimal arc stability at approximately 20% CO
2, the laser–CWW system exhibits a distinct trend of continuously enhanced arc stability and morphological regularity as CO
2 content rises to 18% [
17]. This behavior is attributed to the multi-wire CWW configuration, which promotes a more distributed heat input and exhibits synergistic interaction with the laser-induced plasma.
Figure 4 presents the quantitative analysis results of the arc morphology obtained from high-speed videography in
Figure 3. Using the fixed wire diameter as a reference scale, arc dimensions were determined by converting pixel measurements from the images to physical values, thereby deriving the actual arc width and height. This calibration method ensures accurate dimensional representation of the observed arc characteristics. According to the diagram, the volume of the arc decreased continuously with increasing CO
2 content. When the content of CO
2 increased to 10%, the arc height decreased by 13.4%. The arc height decreased by only 3.67% when the content of CO
2 further increased to 18%. Therefore, as the CO
2 content increases to 18%, the length of the arc decreases, while the width of the arc increases, with an increase of more than 10% compared to pure argon.
Figure 5 shows the current and voltage curves under different shielding gases, obtained in synergic laser–arc hybrid mode. The current and voltage waveforms reflect process stability of welding.
Figure 5a indicates that the obtained welding parameter waveforms were in the form of pulses. The welding current changed greatly, but the waveform stability was good. With increasing CO
2 content, the welding current and voltage waveforms are shown in
Figure 5b. The addition of CO
2 gas reduced the variation in welding current, while the variation in welding voltage decreased slightly, and the voltage stability increased. When the CO
2 content reached 18%, the variation in welding current increased, the current stability of the welder became significantly worse, and the variation in voltage increased.
Figure 5d presents the average values of the arc voltage and welding current under different shielding gas compositions investigated in this study. These values were determined by selecting a representative steady-state electrical signal segment from a stable welding cycle and calculating the arithmetic mean from all data points within that segment. The figure shows that the average welding current decreased with increasing CO
2 content from 430 A to 392 A while the voltage and voltage fluctuations were small. The voltage reached a maximum of 31.8 V under the protection gas of 82%Ar + 18% CO
2. On the whole, with increasing CO
2 content, the stability of electrical parameters first increased slightly and then decreased.
Figure 6 shows the comparison of electrical signals under different carbon dioxide contents. This figure was generated by extracting synchronized voltage–current data from stable welding periods for each shielding gas condition and plotting them as scatter points using Origin 2023.
Figure 6a is a scatter diagram under pure argon protection. From the diagram, it can be seen that the scatter diagram is presented as a rectangular area as a whole. At the same time, the scatter points are mostly distributed on the rectangular frame line, and there is basically no scatter point distribution inside. The scatter point distribution is mostly concentrated between current 420 A and 435 A, voltage 21 V to 45 V. The distribution of scattered points under 10% CO
2 protection in
Figure 6b is similar to that in
Figure 6a, but the distribution of scattered points is more concentrated in the center of the rectangle, and the distribution range of scattered points is smaller, mostly concentrated in the current of 410 A to 420 A, and the voltage is between 23 V and 44 V. At this time, the arc stability is better than that under pure argon protection. When the carbon dioxide content increases to 18%, the scatter diagram is similar to the scatter diagram under pure argon. There is basically no scatter distribution inside the rectangle, but the scatter distribution range increases, and there are deviated scatter points. This is mainly due to the ionization and endothermic of carbon dioxide, which makes the arc temperature decrease, and further increases in CO
2 will make the arc energy decrease, the arc stability deteriorate, and the droplet transition become difficult. In summary, the welding transition is the most stable under the protective gas of Ar + 10% CO
2.
Figure 7 presents the relative frequency distribution of electrical signals. The statistical analysis was performed by counting occurrences of acquired current and voltage data points within defined intervals over a stable sampling period. A narrower and taller signal peak corresponds to a more concentrated electrical parameter distribution, reflecting greater welding process stability. The concentration of data points in specific ranges directly correlates with arc stability, where narrower distributions correspond to more consistent welding performance. The arc voltage and frequency basically show bimodal curve characteristics under different shielding gases.
Figure 7a shows that the relative frequency peak of voltage is between 20 and 25 V in the lower voltage range under 20–35 V, and the relative frequency peak of voltage is between 40 and 45 V in higher voltage range under 35–50 V. A continuous electrical signal was recorded for a duration of 5 s, enabling the cumulative analysis of approximately 600 cyclic samples. In the lower voltage range and higher voltage range, 90% Ar + 10% CO
2 has a larger and narrower peak, indicating that the arc stability is better. When using pure Ar protective gas, although the peak value of pure argon is narrower and stronger in the low-pressure range, there is also a smaller peak value of pure argon in the range of 20–40 V, indicating that the arc stability is poor at this time.
Figure 7b shows that the current peaks under the three shielding gas components all show a multi-peak curve. The three curves are distributed between 380–400 A, 405–423 A and 420–440 A, respectively. It shows that the peak intensity of the curve of 90% Ar + 10% CO
2 is the largest and the peak range is the narrowest, indicating that the current is more stable.
Figure 8 shows the arc morphology.
Figure 8a indicates the arc was taller, the rotating arc of the cable welding wire had a strong interaction with the laser plasma, and the arc stability was poor when the shielding gas was pure argon. This finding is consistent with the unstable and scattered nature of the electrical signals recorded in pure Ar, as shown in
Figure 6a.
Figure 4 shows that the welding current was the largest at this time, and the arc was contracted towards the inwards arc center by the electromagnetic contraction force, resulting in a smaller arc width.
Figure 8b shows that in the argon-rich shielding gas with 10% CO
2, the thermal decomposition of CO
2 absorbed energy, reducing the arc temperature and decreasing the average ionization degree of the shielding gas, consequently leading to a reduction in welding current. This finding aligns with the results reported by Yang et al. [
23]; they demonstrated that the addition of CO
2 to Ar-based shielding gases results in decreased arc temperature and reduced welding current. According to the minimum voltage principle, to ensure heat generation and heat release balance, the arc shrank downwards, the arc height decreased, the arc volume decreased, and the heat loss was reduced. The constricted and stable arc morphology observed under Ar + 10% CO
2 shielding gas is directly correlated with the concentrated electrical signals in
Figure 6b and the stable current–voltage distribution in
Figure 7. As shown in
Figure 8c, when the CO
2 content was further increased, the enhanced thermal decomposition of CO
2 extracted more heat from the arc, leading to further reduction in welding current, decreased arc height, diminished arc volume, and reduced heat loss. This observation aligns with the results reported by Cai et al. [
15].
Figure 9 is an image of the arc shape under 18% CO
2 content.
Figure 9a indicates that the upper section of the arc was noticeably compressed, the arc had a concave appearance, the lower part of the arc was expanded, and the diameter at the base of the arc was greater.
Figure 9b is a schematic diagram of the location of the ionization of CO
2 molecules. Equations (1) and (2) are the decomposition formula of carbon dioxide under a high temperature arc. It can be seen from the formula that carbon dioxide absorbs heat and decomposes into carbon monoxide and oxygen, and the decomposition products can also be compounded and release heat.
Figure 9 shows that CO
2 molecules were mainly ionized and decomposed in the upper part of the arc, and the decomposition of CO
2 absorbed a large amount of heat. According to Trinh et al., the decomposition of CO
2 at high temperatures primarily involves two distinct stages: direct dissociation and stepwise dissociation [
24]. This multi-stage decomposition process leads to a significant increase in the temperature gradient within the upper region of the arc. Due to the arc thermal effect, the arc is compressed and height is reduced. The oxygen atoms and carbon atoms decomposed in the upper part of the arc recombined in the bottom of arc, releasing heat, making the bottom of arc expand and the width increase so that more metal vapor at the laser keyhole entered the compressed arc, making the upper part of the arc bulge.
3.2. Effect of Different Gas Compositions on Droplet Transfer
The content of carbon dioxide in GMAW is a key factor affecting droplet transfer processing.
Figure 8 indicates the process of droplet transfer and the corresponding current–voltage curve under pure argon shielding gas.
Figure 10a shows that the droplet was in the formation stage, and the values of the voltage and current were small. With increasing current and voltage, the arc energy increased, and the droplets grew at the wire end, as shown in
Figure 10b. During droplet growth, the current and voltage remained at a large value, and the droplet grew continuously. The droplet formed a necking and broke from the wire end with promotion force, as shown in
Figure 10c,d. At the same time, when the droplet was about to break away, the droplet current still maintained a large value, while the voltage decreased rapidly. Finally, the droplets left the wire and flew to the molten pool, as shown in
Figure 10e. At this time, the welding current decreased rapidly.
Figure 11 displays images of droplet transfer during hybrid welding under different gases.
Figure 11a shows that under the protection of pure argon, the path of droplet detachment from the wire to the droplet was very short, and the droplet did not fall off the wire but contacted the molten pool (t + 1287).
Figure 11b indicates that the droplet transition path became significantly longer, and the droplet melted and grew at the end of the wire and transitioned to a spherical shape with 10% CO
2. The droplet was observed to deviate from the wire center-line (t + 2340) as the CO
2 content was further increased to 18%. When the droplet flew in the arc space, it also deviated from axial direction of CWW, undergoing a nonaxial transition. Finally, it descended into the pool area located adjacent to the side of the laser beam.
Figure 12 indicates that the droplet transition frequency decreases continuously as CO
2 increased, and the droplet diameter first decreased and then increased, reaching its smallest value under the shielding gas condition of 10% CO
2.
According to the principle of static equilibrium, when a droplet separates from a wire, the force causing detachment is greater than the force holding the droplet in place. The forces that primarily act upon the droplet include the following:
The droplet gravitational force [
17] can be formulated as
In this equation, R represents the diameter of the droplet, ρd is density, and g is constant (9.80 m/s2).
The droplet effect [
17] by electromagnetic force can be given as
In this context, μ0 is constant, while I is current. Additionally, rd and rw are droplet and wire, respectively, and θ denotes the arc root angle.
The force [
7] effect by plasma flow on the droplet can be described as
where C
p is constant, ρ
p is plasma density, r
d is radius, and K is scaling factor.
The reaction force [
17] of the metal vapor is [
25] expressed as
Here, Rh is metal vapor area, v0 (3.4 × 102 m/s) is melt velocity, Ap is projected area, Na is Avogadro’s number, TS is surface temperature, kB is the Boltzmann constant, Ma is vapor molecular weight, B0 is constant of the evaporation, Lv is evaporation, and DLA is distance of laser and wire.
When arc temperature changes, the surface tension F
σ during welding changes significantly. The surface tension [
7] of metal droplets is expressed as
where r
d is wire diameter, σ is liquid coefficient of surface tension, and
f is correction coefficient.
The CWW is also subjected to the rotational force F
r when the CWW is burned. The expression for the rotational force [
7] is
where R
1 is the single wire diameter at the periphery, α is peripheral wire helix angle, V is feeding speed, v
1 is peripheral wire linear speed of rotation, and m is the droplet mass.
Figure 13 shows an image of droplet transfer under the protection of pure argon and mixed gas.
Figure 13a shows that under pure argon, the tips of the wire were pencil-shaped, and the distance from the molten pool to the droplet was very short. As shown in
Figure 13d, the droplet was mainly hindered by the F
σ and the F
RL. Under the promotion of the Fem and Fr, the droplet gradually grew and broke away from the CWW. The droplet is very close to pool, and the droplet size is slightly smaller than the diameter of CWW. Meanwhile, the gravity of the droplet is 4.29 × 10
−4 N.
Figure 5d shows that the welding current was large at this time, which can be seen from Equations (4), (5) and (8). The Fem, F
p and F
r that promote droplet transfer were affected by the current size. The larger the current was, the stronger the promotion effect on transfer frequency. Meanwhile, the larger the current was, the higher the arc temperature. Equation (7) shows that a high arc temperature reduced the droplet F
σ and reduced droplet size while increasing transfer frequency.
Figure 13b shows droplet transfer under 10% CO
2. The droplet underwent droplet transfer at this time, and the path of the droplet from the wire to the welding pool became significantly longer.
Figure 8 demonstrates that the droplet diameter is significantly decreased and is much smaller than the wire, and the gravity of the droplet is also greatly reduced to 1.75 × 10
−4 N, and the droplet transited along the axial direction.
Figure 13e indicates that the droplet is retarded by F
σ and F
RL. The thermal ionization and decomposition of carbon dioxide produce oxygen, which can significantly reduce the droplet surface tension coefficient. Equation (7) indicates that the decomposition of carbon dioxide produces oxygen, which significantly reduces the surface tension of the droplet, thereby decreasing its size. However, because the decomposition of carbon dioxide absorbed part of the arc energy, the arc energy was reduced and the welding current decreased. From the calculation of Equations (4) and (8), the electromagnetic force is reduced by 6.86% due to the decrease in current, the Fr is reduced by 1.4 × 10
−4 N due to the decrease in droplet size, and the final metal transfer frequency was still less than that of protection by pure argon.
Figure 13c shows an image of droplet transfer under 18% CO
2. This figure shows that the droplet transition changed from axial to nonaxial when the CO
2 content increased to 18%. At this moment, the electromagnetic force direction underwent a shift, which formed an α angle as shown in
Figure 13f. Additionally, the Fem decreased by 10.8%. During the growth stage, the droplets were divorced from the center of CWW. Meanwhile, the decrease in welding current weakened promoting forces such as the F
p that facilitate droplet transfer. Additionally, the ionization and decomposition of carbon dioxide reduced the arc temperature, and the F
σ was affected by temperature. When the droplet detached from the wire, F
σ and FRL caused the droplet to transition into a nonaxial shape, with the droplet diameter exceeding the wire diameter. Due to the change in droplet diameter, the F
g increases to 5.78 × 10
−4 N, and the Fr of the droplet increases by 1.59 × 10
−4 N.
Figure 10 shows that droplet transfer frequency decreases continuously, and the size first decreases and then increases as the CO
2 content increases. The droplet transfer mode under pure argon protective gas was mainly droplet-based, and the droplets in the gas mixtures showed a droplet-like transition. In contrast to the stable spray transfer mode achieved with 20% CO
2+ Ar reported by Zhang et al. [
17] in laser–arc hybrid welding, no such transition was observed in the present laser–CWW process. This key difference suggests that the substantial thermal input associated with the CWW suppresses the electromagnetic contraction force necessary for spray transfer, thereby fundamentally altering the droplet transfer behavior.