Effect of Al-3Ti-4.35La Master Alloy on the Aggregation and Sedimentation Characteristics of TiC in Al-7Si Alloys
Abstract
:1. Introduction
2. Experiment
3. Results and Discussion
3.1. Analysis of Al-TiC and Al-3Ti-4.35La Master Alloys
3.2. Influence of Al-3Ti-4.35La Master Alloy on the Aggregation Property of TiC
3.3. Influence of Al-3Ti-4.35La Master Alloy on the Settling Property of TiC
3.4. Effect of Al-3Ti-4.35La Master Alloy on the Stability of TiC in Al-Si Alloy
4. Conclusions
- (1).
- The dissolution of the Ti2Al20La phase releases La elements into the melt, which accumulate on the surface of TiC particles. This accumulation enhances the interfacial wettability between TiC particles and the Al matrix, thereby reducing the agglomeration tendency of TiC particles. When the Al-3Ti-4.35La master alloy was incorporated into the Al-7Si alloy and held for 15 min, the distribution of TiC particles became more uniform.
- (2).
- The Ti elements released by the dissolution of the Ti2Al20La phase will form a Ti-rich zone around or on the surface of TiC particles. This Ti-rich zone reduces the density difference between the TiC particles and the aluminum melt, thereby decreasing their sedimentation behavior. After holding periods of 30 min and 60 min, the amount of TiC precipitation at the bottom of the sample was notably reduced.
- (3).
- The atomic arrangement at the Si-TiC interface exhibits an ordered structure without any detectable distortion, which demonstrates that Si does not exert a direct influence on the agglomeration and sedimentation behavior of TiC particles in the Al-7Si alloy.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Alloy | Al | Si | Mg | Ti | Mn | La | C | Zn |
---|---|---|---|---|---|---|---|---|
Al-3Ti-4.35La | Bal. | - | - | 3.4 | - | 4.24 | - | - |
Al-TiC | Bal. | - | - | 4.7 | - | - | 1.1 | - |
Al-7Si | Bal. | 6.78 | 0.315 | 0.18 | 0.039 | - | - | 0.037 |
Samples | Mass Ratio | Holding Time (min) | Mixing Method | ||
---|---|---|---|---|---|
Al-Si Alloy | Al-TiC | Al-Ti-La | |||
A0 | 2 | 1 | - | 15 | stirring |
A1 | 2 | 1 | 1 | 15 | stirring |
A2 | 2 | 1 | - | 30 | stirring |
A3 | 2 | 1 | 1 | 30 | stirring |
A4 | 2 | 1 | - | 60 | stirring |
A5 | 2 | 1 | 1 | 60 | stirring |
Point | Elements At.% | ||||
---|---|---|---|---|---|
Al | Ti | C | La | Si | |
1 | 21.34 | 34.02 | 38.34 | 2.02 | 4.28 |
2 | 32.80 | 0.00 | 0.00 | 4.68 | 66.20 |
3 | 0.00 | 0.00 | 0.00 | 40.40 | 59.60 |
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Mu, L.; An, J.; Tian, X.; Yu, H.; Zhang, H.; Ding, W. Effect of Al-3Ti-4.35La Master Alloy on the Aggregation and Sedimentation Characteristics of TiC in Al-7Si Alloys. Metals 2025, 15, 351. https://doi.org/10.3390/met15040351
Mu L, An J, Tian X, Yu H, Zhang H, Ding W. Effect of Al-3Ti-4.35La Master Alloy on the Aggregation and Sedimentation Characteristics of TiC in Al-7Si Alloys. Metals. 2025; 15(4):351. https://doi.org/10.3390/met15040351
Chicago/Turabian StyleMu, Long, Jiazhi An, Xudong Tian, Haicun Yu, Haixia Zhang, and Wanwu Ding. 2025. "Effect of Al-3Ti-4.35La Master Alloy on the Aggregation and Sedimentation Characteristics of TiC in Al-7Si Alloys" Metals 15, no. 4: 351. https://doi.org/10.3390/met15040351
APA StyleMu, L., An, J., Tian, X., Yu, H., Zhang, H., & Ding, W. (2025). Effect of Al-3Ti-4.35La Master Alloy on the Aggregation and Sedimentation Characteristics of TiC in Al-7Si Alloys. Metals, 15(4), 351. https://doi.org/10.3390/met15040351