Relationship between Structure and Properties of Intermetallic Materials Based on γ-TiAl Hardened In Situ with Ti3Al
Abstract
:1. Introduction
2. Materials and Methods
2.1. Objects and Procedures
2.2. Characterization
2.3. Mechanical Testing
2.4. Tribology Testing
2.5. Thermodynamic Analysis
3. Results and Discussion
3.1. Synthesis Characterization
3.2. X-ray Powder Diffraction and Microstructure
3.3. Mechanical Characteristics
3.4. Tribological Characteristics
4. Conclusions
- (1)
- Under the conditions of free SHS compression, from the initial components of titanium and aluminum, intermetallic materials based on γ-TiAl were obtained and in situ strengthened by the Ti3Al phase. To increase the exothermicity of the studied compositions, a chemical furnace based on the Ti–C composition was used, which made it possible to increase the combustion temperature and stabilize the combustion front. It is shown that by changing the composition and synthesis time, it is possible to control the phase composition and structure of the material.
- (2)
- It has been established that a decrease in the molar fraction of titanium and an increase in the molar fraction of aluminum in the initial mixture leads to an increase in the mechanical and tribological characteristics of intermetallic materials, as well as their mechanical and tribological properties.
- (3)
- It has been established that, for the material of the initial composition Ti–Al, the wear is 4–4.5 times lower and the friction coefficient is 2.4 times lower as compared to the compositions 1.5 Ti–Al and 3 Ti–Al in the Al2O3 intermetallic–ceramic friction pair. In this case, the size of the running-in area of the Al2O3 ceramic counterbody to the surface of the studied materials has practically the same value.
Author Contributions
Funding
Conflicts of Interest
References
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Composition | Ratio of Initial Components, mol | Composition of Initial Components, wt % | Adiabatic Combustion Temperature (without Chemical Furnace), °C | Combustion Temperature under Experimental Conditions (without Chemical Furnace), °C | Combustion Temperature under Experimental Conditions (with Chemical Furnace), °C | Synthesis Time (with Chemical Furnace), s | |
---|---|---|---|---|---|---|---|
Ti | Al | ||||||
I | Ti–Al | 64 | 36 | 1250 | 1120 | 1350 | 8.5 |
II | 1.5 Ti–Al | 72 | 28 | 1000 | 890 | 1150 | 10 |
III | 3 Ti–Al | 84 | 16 | 670 | no | 1000 | 16 |
Parameter | Value |
---|---|
Track length | 4 mm |
Applied load | 1 N |
Maximum speed | 10 cm/s |
Counterbody | A ball with a diameter of 3 mm |
Counterbody material | Al2O3 |
Run | 10,000 cycles (80 m) |
Medium | Air |
Parameter | Composition | ||
---|---|---|---|
I | II | III | |
Hardness, GPa | 9.4–10.2 | 8.7–9.1 | 6.8–8.1 |
Modulus of elasticity, GPa | 187–215 | 177–185 | 151–170 |
Wear, 10−4 × mm3/N/m | 1.03 | 4.07 | 4.64 |
Friction coefficient | 0.1 | 0.25 | 0.22 |
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Avdeeva, V.; Bazhina, A.; Antipov, M.; Stolin, A.; Bazhin, P. Relationship between Structure and Properties of Intermetallic Materials Based on γ-TiAl Hardened In Situ with Ti3Al. Metals 2023, 13, 1002. https://doi.org/10.3390/met13061002
Avdeeva V, Bazhina A, Antipov M, Stolin A, Bazhin P. Relationship between Structure and Properties of Intermetallic Materials Based on γ-TiAl Hardened In Situ with Ti3Al. Metals. 2023; 13(6):1002. https://doi.org/10.3390/met13061002
Chicago/Turabian StyleAvdeeva, Varvara, Arina Bazhina, Mikhail Antipov, Alexander Stolin, and Pavel Bazhin. 2023. "Relationship between Structure and Properties of Intermetallic Materials Based on γ-TiAl Hardened In Situ with Ti3Al" Metals 13, no. 6: 1002. https://doi.org/10.3390/met13061002