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29 November 2024

Progress in Aluminum-Based Composites Prepared by Stir Casting: Mechanical and Tribological Properties for Automotive, Aerospace, and Military Applications

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1
Surface Science and Tribology Lab, Department of Mechanical Engineering, Shiv Nadar Institute of Eminence, Gautam Buddha Nagar 201314, India
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Faculty of Engineering, University of Kragujevac, Sestre Janjić 6, 34000 Kragujevac, Serbia
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Department of Physics, GLA University, Mathura 281406, India
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Department of Physics, Faculty of Applied and Basic Sciences, SGT University, Gurugram 122505, India
This article belongs to the Special Issue Friction and Wear of Alloys

Abstract

Manufacturing sectors, including automotive, aerospace, military, and aviation, are paying close attention to the increasing need for composite materials with better characteristics. Composite materials are significantly used in industry owing to their high-quality, low-cost materials with outstanding characteristics and low weight. Hence, aluminum-based materials are preferred over other traditional materials owing to their low cost, great wear resistance, and excellent strength-to-weight ratio. However, the mechanical characteristics and wear behavior of the Al-based materials can be further improved by using suitable reinforcing agents. The various reinforcing agents, including whiskers, particulates, continuous fibers, and discontinuous fibers, are widely used owing to enhanced tribological and mechanical behavior comparable to bare Al alloy. Further, the advancement in the overall characteristics of the composite material can be obtained by optimizing the process parameters of the processing approach and the amount and types of reinforcement. Amongst the various available techniques, stir casting is the most suitable technique for the manufacturing of composite material. The amount of reinforcement controls the porosity (%) of the composite, while the types of reinforcement identify the compatibility with Al alloy through improvement in the overall characteristics of the composites. Fly ash, SiC, TiC, Al2O3, TiO2, B4C, etc. are the most commonly used reinforcing agents in AMMCs (aluminum metal matrix composites). The current research emphasizes how different forms of reinforcement affect AMMCs and evaluates reinforcement influence on the mechanical and tribo characteristics of composite material.

1. Introduction

Over the past few decades, researchers have concentrated on creating materials that are both light and strong. As a result, the scientists’ attention switched from researching monolithic materials to investigating composite materials. Composite is a material system made up of a continuous phase (matrix) and a discrete component (reinforcement). Composite materials, such as polymer matrix, metal matrix, and ceramic composites, are often classified based on the physical or chemical properties of the matrix phase []. However, metal matrix composites, or MMCs, are metals reinforced with additional metal, ceramic, or biological components that are dispersed throughout the metal matrix []. Reinforcements are often used to improve the properties of the base metal, including its conductivity, strength, stiffness, resistance to corrosion, and wear []. Metal matrices for composite materials are commonly made of metals, including silicon, aluminum, copper, titanium, magnesium, and nickel. The most attention has been paid to aluminum and its alloys as base metals for metal matrix composites (MMCs) owing to their outstanding corrosion resistance, low weight, high strength, appropriate electrical and thermal conductivity, exceptional malleability, and simplicity of machining []. Aluminum alloys from 2000, 5000, 6000, and 7000 alloy families are most commonly used as a matrix phase. Fibers, whiskers, monofilaments, and particulate types are commonly used as reinforcement phases. Particle reinforcements homogenize in the matrix material more effectively due to their higher isentropic properties compared to others. Aluminum-based composites are predominantly utilized as particle reinforcements in car applications due to their exceptional tribological performance []. Automotive, aerospace, and structural sectors have placed greater emphasis on Al-based composite materials due to their enhanced mechanical properties and robust temperature stability []. Composite utilizes the combining effects of matrix and reinforcement, imparting outstanding ductility and density (low) of the alloys while producing materials with significantly higher strength compared to the base material. Adding reinforcements in the form of high-strength particles is an additional method to overcome any disadvantages with matrix materials []. Incorporating reinforcement into an aluminum matrix enhances the composite’s hardness, impact resistance, compressive strength, and tensile strength [,,].
AMMCs often outperform aluminum alloys or unreinforced aluminum in terms of wear resistance through the usage of a wide range of materials that are employed as reinforcements. By incorporating micro- or nano-sized reinforcing particles made from synthetic substances, ceramics, waste from industries, and agricultural waste into aluminum-based material, it is possible to efficiently create aluminum-based composites []. Modern materials have evolved where aluminum metal matrix composites are concerned. The creation of lightweight alloys raises the standard of the material that is favored for design purposes. Aluminum metal matrix composites (AMMCs) gained significant attention owing to their lightweight, having a low thermal expansion coefficient, high specific modulus, excellent wear resistance, high strength-to-weight ratio, outstanding corrosion resistance, and high specific modulus [,]. However, the fundamental requirement of the automobile industry is to discover new materials that can decrease fuel consumption and vehicle emissions. Aluminum, magnesium, and titanium are frequently used as the matrix in structural applications to provide robust support for the reinforcement. Cobalt and cobalt-nickel alloy matrices are commonly used in applications that require extremely high temperatures []. In composites, the matrix is infused with the strengthening agent. Reinforcement also alters COF, wear resistance, and thermal conductivity. Discontinuous metal matrix composites (DMMCs) can exhibit isotropic properties and can be effectively processed using conventional techniques, i.e., rolling, forging, or extrusion []. Reinforcement, such as silicon carbide/carbon fiber, is employed for the purpose of providing continuous reinforcement. An anisotropic structure is produced, where the orientation of the material influences its strength as a result of the fibers being inserted into the matrix in a certain direction. Boron filament was mainly employed as reinforcement. Particles, small strands, or whiskers are used in discontinuous reinforcement []. Within this group, silicon carbide and alumina are the most often used reinforcing elements.
Although composites are viable substitutes for traditional materials, there are still several drawbacks that need to be explored. Achieving enhanced material characteristics is the main goal of composite manufacture, and it depends on a number of variables, including the fabrication method, process parameters, component materials, and composition []. For MMCs, a wide variety of production processes have been investigated, including liquid-state and solid-state processes. The stir-casting process is the most widely used manufacturing route in the commercial world because of its unique characteristics []. Large-scale manufacturing may be economically facilitated by this cost-effective technology due to its simplicity and versatility. Stir casting is used to create complex profiled MMCs without destroying the reinforcing particles. When creating composites using the stir casting process, a homogeneous distribution of reinforcing components occurred []. Aluminum metal matrix composites consist of two distinct phases: the matrix phase and the reinforcement phase. The reinforcement phase comprises robust reinforcements such as SiC, B4C, TiC, and Al2O3. Applying a coating to the reinforcing zone can prevent chemical reactions with the matrix []. Carbon fibers are commonly utilized in an aluminum matrix to produce composites that exhibit a low density and high strength. However, the combination of carbon with aluminum leads to the formation of the water-soluble and fragile complex aluminum carbide over the fiber surface. To counteract this, carbon fiber is coated with titanium boride/nickel. Singla has been working on developing Al-based material reinforced with SiC particulate with the aim of attaining uniform dispersion of ceramic material and creating a traditional, cost-effective method of generating MMCs []. The stir casting technique’s two-step mixing process has been used, showing hardness and impact strength enhanced with the amount of SiC.
Further, Sharma et al. studied the surface structure and mechanical characteristics of Al/SiC-reinforced composites prepared by stir casting and revealed hardness and tensile strength have been strengthened with the addition of silicon carbide reinforcements []. Al Matrix’s microstructural examination showed that the SiC particles were non-homogeneously distributed and clustered. James examined the impact of incorporating silicon carbide (SiC) and titanium diboride (TiB2) into the metal matrix of hybrid aluminum composites on their mechanical properties and ability to be machined []. Aside from analyzing machining characteristics (feed rate, cutting speed, surface roughness, and depth of cut), the mechanical characteristics (hardness, density, and UTS) also improved. Flanagan et al. analyzed the mechanical behavior of the Al/SiC composite and showed that as temperature increases, the material’s hardness decreases progressively []. Prabha discussed the optimization of the Taguchi methodology and the performance of dry sliding in hybrid metal matrix composites made from Al7075, TiC, and MoS2, which were produced using stir-casting, revealing that the wear characteristics improved []. However, reinforcement has a detrimental effect on losing weight. When reinforcement is increased, weight loss diminishes. The second generation of AMC (alloy matrix composite), known as HAMC, has better mechanical and physical characteristics than single-reinforcement AMC. HAMC (hybrid alloy matrix composite) uses a large amount of aluminum and two or more reinforcements []. The advantageous nature of HAMC depends on the size and amount of reinforcement added to the aluminum matrix. Secondary reinforcement successfully combines desired composite characteristics, while additional primary reinforcement improves the fundamental []. Thus, in several industrial applications, HAMC replaces traditional aluminum. HAMC is separated into three categories: synthetic reinforced ceramics mixed with agricultural residue, synthetic ceramics reinforcement, and waste from industry [,,].
Further, nanocomposites created through stir casting demonstrated improved mechanical properties. Nevertheless, there is a scarcity of research on the stir casting of Al MMNCs. A significant issue noted in this process is the formation of porosity. The nano-sized reinforcement particles possess a greater surface-to-volume ratio but low wettability, leading to an uneven distribution of nanoparticles within the matrix []. This heterogeneous distribution of reinforcement particles also impacts the composite’s properties. An increase in the reinforcement weight fraction beyond a certain threshold result in a deterioration of characteristics. Typically, at elevated reinforcement levels, nanoparticles tend to cluster and agglomerate, negatively influencing the properties []. Additionally, as the quantity of nanoparticulate rises, the volume of porosity will also increase []. Therefore, it is essential to carefully regulate the addition of reinforcement. The existing research indicates that employing ultrasonic-assisted stir casting tailed by squeeze casting can significantly minimize porosity while enhancing the uniform dispersion of nanoparticles []. The use of ultrasonic vibrations proves highly effective for achieving an even dispersion of nanoparticles within the matrix []. The intense vibrations produced by the ultrasonic vibrator can prevent the development of clusters and agglomeration within the composites. High-power ultrasonic vibrations from the ultrasonic probe can result in strong cavitation effects and acoustic streaming []. The transient cavitation phenomenon initiates the disintegration of gas microbubbles located near the clusters of reinforcement particles, effectively breaking apart these clusters and ensuring a uniform dispersion within the molten pool []. Furthermore, the movement of liquid induced by the acoustic pressure gradient, known as acoustic flow, contributes to the efficiency of the stirring process. It is highly advisable to utilize squeeze casting for the composite, as it significantly minimizes material defects and enhances mechanical properties. The application of pressure during solidification leads to a microstructure characterized by fine grains and uniform dispersion []. Future research may explore the production of MMNCs through a combination of stir casting and squeeze casting, given that this approach has demonstrated both cost-effectiveness and efficiency in MMNC fabrication. The current research emphasizes how different forms of reinforcement affect AMMCs and evaluates reinforcement influence on the mechanical and tribo characteristics of composite material.

2. Processing Approach: Stir Casting

A wide variety of techniques have been developed in the last 10 years to produce MMCs. The preparation strategy is crucial in assessing the mechanical behavior of composites and also determines the cost of production. Depending upon the state of the metal, the manufacturing procedures can be categorized as solid-state and liquid-state processing. In addition, there are other techniques available that involve a partially solid matrix, including rheo-casting, compo-casting, spray deposition, and in situ fabrication. However, utilization is not as prevalent as solid/liquid state approaches []. In solid-state manufacturing, the bonding of matrix and reinforcing agents occurs due to the mutual diffusion that occurs between them at elevated pressure and temperature levels in the solid state []. Reinforcements are dissolved into the molten matrix during liquid state production, and then the matrix solidifies using casting or infiltration techniques. Compared to solid-state manufacturing approaches, liquid-state techniques are more affordable. Amongst liquid state techniques, stir casting is a widely used and cost-effective, commercially available technique that offers improved wettability, decreased porosity, and rather uniform distribution of reinforcements throughout the matrix []. The main process of stir-casting included the mixing of reinforcing agents with Al-based material through stirring. The stir-casting furnace is frequently powered by electrical energy, and the most popular way to produce heat is by electrical resistance heating []. The procedure entails raising the temperature of the matrix within the crucible until it melts. The crucible is constructed to be chemically inert to the reinforcements and matrix. However, it is essential to preheat the reinforcements in order to enhance the mixing of the components. Melting occurs during the mixing stage. To lower the possibility of casting defects, an inert state is maintained throughout stirring. Generally, an injection cannon is used to feed particulate reinforcements in order to minimize the risk of gas entrapment []. Rotational motion is provided by the stirrer’s propeller blades, which are fixed to a shaft that is linked to the electrical motor’s output. A lead screw arrangement driven by a different electrical motor may efficiently regulate the stirrer’s vertical motion. Stepper motors are frequently utilized for alteration in spinning speed through a stirrer []. However, the matrix and reinforcement need to be wettable for a homogeneous mixture. The schematic experimental setup of the stir-casting approach is depicted in Figure 1. The properties of AMCs are largely dependent on a number of stir-casting process variables, including the size of the reinforcement, the stirrer’s speed, the duration of the stirring, the design of the stirrer blade, and the melt temperature []. The stir-casting process parameters are mentioned below.

2.1. Reinforcement Size

The size of the reinforcement has a significant impact on the material’s strength, as it is fabricated via stir casting []. A micro-ceramic particle is included as reinforcement into the liquid metal matrix, which increases the material’s strength while decreasing its elongation []. Introduction of nano-ceramic particles in the composite revolutionaries the research scenario of composite material. The size of ceramic reinforcements significantly influences composite material. It improves the base material properties while preserving high resistance to temperature creep and beneficial elongation. However, the nano-sized reinforcing particles promote lower wettability, signifying the non-homogeneity of reinforcing agents in the matrix []. The characteristics of composites are also influenced by the heterogeneous dispersion of reinforcing particles inside the matrix. Composites with lower reinforcing sizes frequently have better mechanical behavior. Composites of Al-10Sb cast aluminum alloy and SiC were created by Youssef et al. with SiC particles with diameters of 115 μm, 225 μm, and 350 μm and weight fractions of 3%, 5%, and 9% chosen to reinforce the matrix []. The composite with the finest reinforcement particles (115 μm) and 9 wt.% SiC showed the greatest increase in mechanical characteristics when subjected to material characterization. The use of finer reinforcement particles maximizes the strengthening effect. AZ91D alloy-SiC AMC was created by Poddar et al. using the stir-casting technique for 15 vol.% of SiC (15 μm and 150 μm) []. The addition of reinforcements resulted in a decrease in average grain size. Comparing composites reinforced with 150 μm particles, the grain size of the former was much larger than the latter. Finer particles increased the refining of grains. In comparison to AZ91D alloy-150 μm SiC, composites made with AZ91D alloy-15 μm SiC likewise possessed better mechanical properties.

2.2. Stirring Speed and Stirring Time

The characteristics of reinforcement distribution in AMC are largely determined by the viscosity of the molten matrix. Increased viscosity hinders the reinforcement particles’ smooth motion during stirring, which is undesirable []. Conversely, reduced viscosity is ineffective for suspending and retaining particles. The inter-particle distance can be increased by increasing the stirring speed. The stirrer blade profile affects the stirrer speed []. The homogeneous dispersion of reinforcements will result in the maximum properties of the composites. At longer stirring times, increased interparticle distances and distribution uniformity can be attained. Stirring time is differentiable based on the blade profile []. Moses et al. found that the mechanical characteristics of AMC were significantly impacted by a variety of stir-casting parameters, including stirring temperature, blade angle, speed, and duration []. Poor ultimate tensile strength is accountable for porosity, clumping, and segregation at the grain boundaries, attained with low or high values of parameters. The optimized range of process variables produced the least porous and most effective casting products with evenly distributed reinforcements. As a result, it is chosen over extremely high parameter values.

2.3. Melt Temperature

A high melt temperature can improve the wettability of the melt. High temperatures, however, are not usually preferred, causing the melt’s viscosity to decrease [,]. Particle agglomeration in a melt is encouraged by a low melting temperature. Therefore, the middle-range temperature value is preferred, providing improvement in mechanical characteristics.

2.4. Stirrer Blade Design

Since zirconia may stop reactions among stainless steel and Al-based materials at high temperatures, it is frequently employed as a coating material for stirrer blades []. As a result, while stir-casting AA 6061 MMCs, a zirconia covering is strongly advised. In order to achieve ideal melting mixing, an impeller design helps to create a vortex.
Further, Unlu conducted a study comparing the PM (powder metallurgy) and casting methods and determined that the casting process exhibited higher mechanical behavior compared to the powder metallurgy approach []. Problems with the PM approach include porosity, insufficient bonding between the reinforcement and matrix, challenges in achieving an even distribution of particles, inadequate wetting of the reinforcement and matrix, chemical reactions between the reinforcement material and the matrix alloy, and clumping caused by differences in density between the matrix and reinforcement []. Several manufacturing casting process variables, such as the size of the sink, stirring time, capacity and size of the impeller, the temperature of the molten metal, length of melting, stirring speed, type and size of reinforcement, melting rate, and mold temperature, etc., are accountable for assessing and improving the mechanical behavior of composite []. During the stir-casting process, it is crucial to observe and assess the dispersion of reinforcing particles inside the matrix. Ensuring homogeneity in dispersion throughout is typically challenging because of density differences [,]. Aluminum alloy composites prepared with ceramic particles are extensively utilized in the automotive and aerospace industries.
Figure 1. Schematic experimental setup of stir casting approach [].
The dispersion and distribution of ceramic nanoparticles in liquid metal are the only factors that affect the characteristics of metal matrix nanocomposites []. The effects of stirring temperature and duration on ABOw (aluminum borate whisker) and SiCp-reinforced Al6061 composite were examined by Guan et al. []. The microstructure showed accumulation of composites with ABOw and SiCp, as when the stirring temperature and duration are increased, the uniformity of the reinforcement distribution first rises and subsequently declines (Figure 2a–d) []. To further conclude, the evidence of ABOw and SiCp was depicted in the XRD and TEM. The XRD results of the composite produced at 640 °C for 30 min are illustrated in Figure 2e. It is evident that neither Al4C3 nor MgAl2O4 is present in the composites, indicating that the pretreatment of ABOw and SiCp successfully inhibits interfacial reactions with the matrix alloy. However, the diffraction peak corresponding to ABOw is not visible in Figure 2e, attributed to its low concentration within the composite []. Figure 2f present the TEM micrograph of the hybrid composite, revealing the presence of ABOw and the formation of an Al2O3 interlayer between the matrix and the ABOw reinforcement. This suggests that during stirring and squeeze casting, ZnO can react with molten aluminum, enhancing the wettability between ABOw and the matrix alloy while effectively preventing damage to ABOw []. Shear and friction between the semisolid slurry and reinforcement, which is proportionate to the viscosity, is the concern behind []. The semi-solid slurry’s viscosity and solid fraction both rise at a lower churning temperature. When the temperature drops to 630 °C, the matrix alloy is no longer liquid during stirring. It becomes extremely difficult to stir completely because of the significantly increased viscosity or friction resistance, which makes it impossible to distribute reinforcement uniformly throughout the composites []. The optimized value of stir parameters is taken as 640 °C and 30 min.
Figure 2. SEM image of composites made of (5%ABOw + 15%SiCp)/6061Al and subjected to varying stir temperatures for 30 min: (a) 680 °C, (b) 650 °C, (c) 640 °C, and (d) 630 °C. Further, (e) shows the XRD pattern of the composite, and (f) reveals the TEM micrographs of composites [].

4. Strengthening Mechanism

The effect of particle quantity and size on the strength of composites is widely acknowledged. Research indicates that larger particles can create voids around them, which diminishes the overall strength of the mixture due to their dispersion. When the size of the reinforcing particles is reduced, the spacing between them in metal matrix composites (MMCs) decreases. This reduction enhances the resistance to dislocation movement, thereby increasing the strength of the MMCs []. Additionally, the nano-reinforcing agent improves particle hardening mechanisms, thereby enhancing the overall characteristics of composites and alleviating stress concentrations at their edges [,]. Research has demonstrated that incorporating ceramic nano-particulates smaller than 100 nm can greatly improve the strength of composites while preserving their ductility [].
The smaller grain structure and limited dislocation movement contribute to the enhanced durability of the composites []. However, when analyzing reinforced nanoparticles that fall below a critical size, the Orowan reinforcement effect shows a notable increase []. In contrast, this effect diminishes when the nanoparticle size surpasses the threshold value (<100 nm). A notable improvement in durability is observed with reinforcement size <20 nm, as interfacial surface contact is improved []. Nonetheless, reduction simultaneously diminishes the load-bearing capacity of composites []. Jayalakshmi et al. observed a significant increase in durability with a decrease in ductility with the addition of nano-size reinforcement in Al-based material []. However, strengthening is accompanied by the load transfer ability of material offering strong interfacial bonding []. At the same time, the integration of hard particles has a substantial effect on the fundamental mechanism responsible for enhancing the composite’s strength. Ceramic particle-reinforced aluminum metal matrix composites (AMMCs) are widely known for their enhanced mechanical properties, making them suitable for a variety of aerospace, automotive, and military applications. The incorporation of ceramic reinforcements into an aluminum matrix results in a variety of reinforcement mechanisms that significantly improve the material’s properties []. The detailed discussion regarding strengthening mechanisms focusing on how they contribute to the overall properties of AMMCs was depicted below:

4.1. Mechanism of Load Transfer

The mechanism of load transfer plays a crucial role in the enhancement of strength in AMMCs. When external forces are applied to a composite material, the harder ceramic particles distribute the load alongside the more malleable aluminum matrix. This mechanism proves to be especially effective at an increased volume fraction of ceramic particles, which can result in more efficient load distribution []. Further, the effective load transfer is guaranteed by strong bonding at the interface between the aluminum matrix and ceramic particles []. Inadequate bonding may cause debonding, diminishing the effectiveness of this process. The size, shape, and arrangement of ceramic particles within the matrix significantly influence the effectiveness of load transfer []. For instance, smaller particles generally enhance load transfer by facilitating a more consistent distribution of stress. The yield strength (σyc) using the load transfer mechanism for composite is calculated using Equation (1) [],
σyc = σym[Vr(0.5S + 1) + Vm]
where σym is matrix yield strength, Vr is reinforcement volume fraction, Vm is matrix volume fraction, and S is reinforcement particulate aspect ratio, with S = 1 for particulates with a spherical or equiaxed shape.

4.2. Orowan Strengthening Mechanism

In the MMCs, fractures within the particle agglomerates are initiated by the applied load. Due to the continuous application of load, the composites undergo a gradual spread of defects, which ultimately results in early failure []. Achieving a uniform dispersion of reinforcing particles through acoustic ultrasonic cavitation and streaming significantly reduces the initiation of fractures in areas where particulate agglomeration takes place. The increase in yield strength (YS) is attributed to the interplay between dislocations in the grains of the matrix and the robust reinforcing particulates []. This interaction inhibits the development of fractures under applied stress. Additionally, the notable difference in the modulus of elasticity between the reinforcement particulates and the alloy matrix creates a distinct interaction between the reinforcement particulates and dislocations. A crucial mechanism known as Orowan strengthening takes place when dislocations navigate around hard ceramic particles. When these dislocations meet such particles, their hardness makes it difficult for them to pass directly through. Instead, the dislocations curve around the particles, forming loops that enhance the overall strength. Hard ceramic reinforcements result in dislocations bowing outward in the spaces between them, which effectively raises the stress needed for the movement of dislocations []. Localized stress concentrations arise from the interaction of dislocations with ceramic particles, thereby improving overall strength []. This mechanism is especially important when working with tough ceramics like silicon carbide (SiC) or alumina (Al2O3), both of which exhibit high hardness levels. Dislocation loops associated with Orowan reinforcements act as barriers to dislocation motion, thereby increasing the overall strength of the composite []. As the reinforcement content in the alloy matrix increases, the resistance to dislocation motion and fracture propagation also increases, resulting in increased strength of MMCs at higher strengthening levels.

4.3. Dislocation Strengthening Mechanism

The improvement in mechanical properties of MMNCs is attributed to the larger interface area between reinforcement and matrix due to the incorporation of nano-size reinforcement []. In addition, the thermal mismatch between the nano-size reinforcement and Al alloy matrix induces thermal stresses (cooling), inducing plastic deformation at the interface as thermal equilibrium is only established at the contact temperature during processing. Therefore, the appearance of tiny defects, such as dislocations in the vicinity of nanoscale particles, occurred []. The research studies confirm the presence of dislocation density near the matrix–reinforcement interface [,,,]. High cohesion at the atomic level between the matrix and reinforcement enhanced the direct bonding between the nanoparticles and the matrix []. Further, the yield strength is directly associated with dislocation motion, which is hindered by several obstacles. The presence of volume stress leads to the generation of geometrically necessary dislocation loops (GNDs) near the reinforcing particles, which is accompanied by variation in CTE between reinforcements and the alloy matrix, consistent with the Taylor strengthening process []. These GNDs can compensate for the dislocations generated due to the significant change in CTE. This increases the yield strength of the composite []. The strength of the MMC increases with nanoparticles, depicting a high incidence of the GND loop.

4.4. Grain-Refined Strengthening

Grain refinement takes place when ceramic particles serve as nucleation sites throughout the solidification process. This phenomenon results in a more refined microstructure within the aluminum matrix, which plays a crucial role in enhancing strength via the Hall–Petch effect []. According to the Hall–Petch relationship, smaller grains obstruct dislocation movement more efficiently than their larger counterparts, leading to an increase in yield strength. However, ceramic particles facilitate heterogeneous nucleation during the solidification process, resulting in reduced grain sizes. The presence of smaller grains elevates dislocation density, which additionally aids in strengthening via interactions among dislocations []. Studies indicate that AMMCs featuring fine-grained microstructures possess enhanced mechanical properties in contrast to their coarser-grained counterparts, owing to these influences [,,]. The increase in strength can be attributed to the increase in matrix grain fineness. The hindrance of dislocation movement is caused by the increase in lattice disorder caused by this refinement. The improperly arranged lattice structure requires excess energy to reallocate dislocation movement and transfer to adjacent grains []. Due to grain refinement, the grain boundary area increases, restricting dislocation movement and contributing to the increase in yield strength. However, nanoparticles are included at the matrix grain boundaries during solidification, hindering grain development and leading to a finer microstructure.

5. Challenges in Fabricating AMMCs

The problem in producing HAMC is devising a production procedure that is simultaneously efficient and effective. Stir casting is the most effective technique for mass manufacturing. However, the matrix’s inadequate dispersion of nanoparticles and its high porosity counterbalance this advantage. The process of fabricating Al-matrix composites with alumina particles by casting is often challenging because of the poor wetting capacity of alumina particles and the tendency for them to clump together. These issues lead to an uneven distribution of particles. Manufacturing of composites is expensive and challenging due to the poor wetting behavior. PM is the effective approach for optimal homogeneity. However, its application to mass production is challenging because it incurs very significant costs. Diffusion bonding produces a joint material that is uniform in nature and exhibits consistent properties. This process is highly efficient and adaptable while also being relatively straightforward. There has been a substantial increase in usage of composites utilizing diffusion-bonding approaches. Nevertheless, the utilization of the diffusion-bonding technique in numerous industrial applications has been restricted owing to the high cost associated with removing the oxide layer. Concerning environmental issues, additional research will need to be conducted on the utilization of scrap, biowaste, and mineral waste as possible reinforcing materials for HAMC and its sustainability. The joint material produced by diffusion bonding has homogeneous characteristics and is a highly prolific, versatile method that is reasonably easy.

6. Conclusions

The characteristics of the aluminum-based composite material are significantly impacted by various aspects related to the stir-casting process, including the speed of the stirrer, the duration of stirring, the design of the stirrer blade, the size of the reinforcement, and the temperature of the melt. Factors such as density, porosity, CTE, dislocation density, and thermal mismatch significantly influence the performance of MMCs. Optimizing process parameters, such as finer reinforcement particles, optimized stirring configurations, preheating the reinforcement, and curing under pressure, is essential for achieving consistent distribution of reinforcements and preventing clustering. The addition of ceramic reinforcements like alumina, silicon carbide, and titanium diboride generally improves the mechanical strength of aluminum MMCs but may have a negative impact on ductility. Nano-ceramic reinforcements show the potential to simultaneously improve the strength and ductility of aluminum composites.
Bonding between the matrix and reinforcement is significantly enhanced through improved quality and surface treatments of reinforcements. Pre-treatment methods, including coating or preheating, are necessary to guarantee optimal integration and enhancement of properties in MMCs. The hardness of aluminum-based composites (AMMCs) is significantly influenced by the temperature during processing and subsequent heat treatment. High temperatures can promote the precipitation of strengthening phases within the matrix, leading to an increase in hardness levels. Additionally, higher temperatures can induce microstructural alterations that influence hardness, such as grain growth and dissolving reinforcing particles. The incorporation of hard reinforcement particles like SiC or Al2O3 greatly enhances wear resistance by redirecting crack propagation and bridging fractures.
Temperature also plays a vital role in wear resistance, as higher processing temperatures improve interfacial bonding between the matrix and reinforcement, enhancing load transfer during wear evaluations. Particle size also plays a significant role in the strength of composites. Reducing the size of reinforcing particles decreases spacing between them, increasing resistance to dislocation movement and increasing the strength of MMCs. Nano-reinforcements improve particle hardening mechanisms, enhancing the mechanical properties of the matrix. Furthermore, the strengthening mechanism, i.e., mechanism of load transfer, Orowan strengthening mechanism, dislocation strengthening mechanism, and grain-refined strengthening, were critically discussed, which focused on improving the overall characteristics of AMMCs.

Author Contributions

Conceptualization, S.K.S., S.G., R.P. and L.K.S.; methodology, S.K.S., L.K.S., R.P., I.M. and Y.S.; writing—original draft preparation, S.K.S.; writing—review and editing, S.K.S., S.G. and B.S.; funding acquisition, S.G. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Conflicts of Interest

The authors declare no conflict of interest.

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