Hydrogen Enrichment in Methanol Dual-Fuel CI Engines: A Computational Assessment of Engine Performance and Major Combustion Parameters and Emissions

Hydrogen enrichment of compression ignition (CI) engines has emerged as a promising strategy to simultaneously enhance thermal efficiency and reduce carbon-based emissions. This study numerically investigates how hydrogen enrichment affects engine performance and emissions in methanol–diesel dual-fuel CI engines, a combustion mode gaining increasing attention for replacing fossil diesel with sustainable fuels, particularly in hard-to-abate sectors such as maritime transport. The simulations are based on the Unsteady Reynolds-Averaged Navier–Stokes (URANS) equations, incorporating the RNG k–ε turbulence model, the Eddy Dissipation Concept (EDC) for turbulence–chemistry interaction, and the G-equation for turbulent premixed flame propagation. The numerical model is validated against experimental data for in-cylinder pressure and heat release rate at 45% methanol substitution ratio (by energy). The results indicate that increasing the hydrogen enrichment ratio (HER, defined on an energy basis) from 5% to 20% raises the Sauter mean diameter (SMD) of the diesel fuel from 20.2 µm to 28.0 µm (+38%), driven by reduced aerodynamic breakup intensity associated with modified gas-phase properties under hydrogen enrichment. Furthermore, hydrogen’s elevated adiabatic flame temperature and superior mass diffusivity intensify combustion, raising peak in-cylinder pressure from 75.2 to 79.1 bar (+5.2%), amplifying the peak heat release rate from 129 to 211 J/°CA (+63.6%), and elevating maximum in-cylinder temperature from 1542 to 1735 K (+193 K). Under the investigated CFD operating conditions, these thermodynamic gains translate into an engine-level 6% improvement in indicated thermal efficiency and a 14% reduction in indicated specific fuel consumption (accounting for hydrogen, methanol, and diesel) at HER 20%. On the emissions front, CO₂ declines by 24% in direct proportion to the carbon-containing fuel mass displaced by hydrogen substitution, while NOₓ increases approximately twofold from 0.10 g/kWh at HER 0 to 0.21 g/kWh at HER 20, driven by peak temperature elevation. These findings establish hydrogen-enriched methanol–diesel dual-fuel combustion as a viable pathway toward high-efficiency, low-carbon CI engine operation for heavy-duty transport applications.