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Article

An Infinite Set of One-Range Addition Theorems Without an Infinite Second Series, for Slater Orbitals and Their Derivatives, Applicable to Multiple Coordinate Systems

Department of Physics, Portland State University, Portland, OR 97207-0751, USA
Axioms 2026, 15(4), 242; https://doi.org/10.3390/axioms15040242
Submission received: 19 January 2026 / Revised: 13 March 2026 / Accepted: 18 March 2026 / Published: 24 March 2026

Abstract

Addition theorems have been indispensable tools for the reduction of quantum transition amplitudes. They are normally utilized at the start of the process to move the angular dependence within plane waves, Coulomb potentials, and the like, into a sum over spherical harmonics that allows the angular integration to be carried out. These have historically been “two-range” addition theorems, characterized by the two-fold notation r>=Max[r1,r2] and r<=Min[r1,r2] and comprising a single infinite series. More recently, “one-range” addition theorems have been created that have no such piecewise notation, but at the cost of the introduction of another infinite series. We use a very different approach to derive an infinite set of addition theorems for Slater orbitals, hydrogenic and Hylleraas wave functions, and so on, that retain the one-range variable dependence but have, at worst, a finite second series rather than an infinite one. In addition, unlike previous addition theorems, they are applicable to more than one coordinate system. One of these addition theorems may also be used for Yukawa-like functions that may appear late in the reduction of amplitude integrals, and we show its utility for an integral that has stubbornly defied reduction to analytic form for nearly sixty years. Finally, we craft indefinite integrals of 15 half-integer Macdonald functions multiplied by (inverse) powers and negative exponentials containing squares of the integration variable.
Keywords: addition theorem; integral transform; integral representation; quantum amplitudes; Macdonald functions; hypergeometric functions; Meijer G-functions; Slater orbitals; Yukawa exchange potential; Debye–Hückel potential; Thomas–Fermi potential; free-space Green function; hydrogenic wave functions; Hylleraas wave functions; ellipsoidal coordinates; Hylleraas coordinates; indefinite integrals of Macdonald functions; modified spherical Bessel function of the second kind; reduced Bessel functions addition theorem; integral transform; integral representation; quantum amplitudes; Macdonald functions; hypergeometric functions; Meijer G-functions; Slater orbitals; Yukawa exchange potential; Debye–Hückel potential; Thomas–Fermi potential; free-space Green function; hydrogenic wave functions; Hylleraas wave functions; ellipsoidal coordinates; Hylleraas coordinates; indefinite integrals of Macdonald functions; modified spherical Bessel function of the second kind; reduced Bessel functions

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MDPI and ACS Style

Straton, J.C. An Infinite Set of One-Range Addition Theorems Without an Infinite Second Series, for Slater Orbitals and Their Derivatives, Applicable to Multiple Coordinate Systems. Axioms 2026, 15, 242. https://doi.org/10.3390/axioms15040242

AMA Style

Straton JC. An Infinite Set of One-Range Addition Theorems Without an Infinite Second Series, for Slater Orbitals and Their Derivatives, Applicable to Multiple Coordinate Systems. Axioms. 2026; 15(4):242. https://doi.org/10.3390/axioms15040242

Chicago/Turabian Style

Straton, Jack C. 2026. "An Infinite Set of One-Range Addition Theorems Without an Infinite Second Series, for Slater Orbitals and Their Derivatives, Applicable to Multiple Coordinate Systems" Axioms 15, no. 4: 242. https://doi.org/10.3390/axioms15040242

APA Style

Straton, J. C. (2026). An Infinite Set of One-Range Addition Theorems Without an Infinite Second Series, for Slater Orbitals and Their Derivatives, Applicable to Multiple Coordinate Systems. Axioms, 15(4), 242. https://doi.org/10.3390/axioms15040242

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