Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria)
Abstract
1. Introduction
- ➢
- Characterize the current hydrochemical status of groundwater in the Saoura Valley and identify dominant geochemical processes;
- ➢
- Establish spatial hydrochemical zonation and facies evolution along flow paths;
- ➢
- Quantify long-term trends (1941–2024) by comparing present results with historical data;
- ➢
- Assess the respective roles of natural (evaporite dissolution, cation exchange, evaporation) and anthropogenic factors (over-pumping, irrigation return flow, fertilizer use) in the observed degradation;
- ➢
- Evaluate the vulnerability of the Saoura oases to salinization and discuss implications for their future sustainability.
2. Study Area
2.1. Geology of the Saoura Valley
- A Precambrian basement formed by volcanic formations that emerged in the cores of certain anticlinal structures [30,31]. Its largest exposure is within the Sebkhael Melah structure, containing a thick series of turbidites (>3500 m), intercalated with basaltic and andesine flow sand tuffs and intruded by dolerites and monzonites [27].
- The Cretaceous and Tertiary terranes comprise the Kemkem Plateau and the Hamada of Guir. These consist of sandy clays at the base and silicified lacustrine limestones.
- Quaternary alluvial deposits.
2.2. Saoura Hydrogeological System
3. Materials and Methods
3.1. Groundwater Sampling and Analytical Procedures
3.2. Multivariate Statistical Analysis
4. Results and Discussion
4.1. Hydrochemical Characterization and Facies Type of Groundwater in the Saoura Valley
- Na-Cl-SO4 (55% of samples): This facies is in el Ouata, Tamtart, Ouled Khoudéir, and Timoudi (obs34), characterized by high concentrations of Na+, Cl−, and SO42−. These samples plot near the Na+ and Cl− + SO42− apices, indicating halite and gypsum dissolution accompanied by evaporative enrichment [45].
- Ca-Mg-SO4 (30%): This type is in Beni Abbès, Ksabi, and Igli, with elevated Ca2+, Mg2+, and SO42−. These data point toward the Ca2+ + Mg2+ and SO42− vertices. The elevated sulfate levels (reaching 380 mg/L in Tamtart and 310 mg/L in Ksabi) indicate the dissolution of gypsum/anhydrite dissolution within sulfate-bearing formations [46].
- Ca-Mg-HCO3 (15%): This facies is in Beni Yakhlef and Kerzaz, characterized by low TDS and a relative dominance of Ca2+ and HCO3−. These samples are situated in the Ca2+-HCO3−. Situated in the left-central field of the diamond, these waters reflect more recent recharge within carbonate aquifers [47].
4.2. Correlation Matrix and Hierarchical Cluster Analysis
- ➢
- Group A comprises Cl−, Na+, EC, and K+, with very low dissimilarity (approx. 0.05 to 0.2). The extremely tight association between Cl− and Na+ confirms halite dissolution as a dominant process, while their link to EC reflects their primary role in the total mineralization of the groundwater [68]. The inclusion of K+ in this group suggests a common association with saline enrichment, potentially from agricultural runoff or secondary mineral weathering [66].
- ➢
- Group B comprisesMg2+, SO42−, and Ca2+. The close linkage between Mg2+ and SO42− (dissimilarity < 0.15) suggests a shared origin from the dissolution of gypsum and magnesium-bearing minerals within the aquifer matrix [68].
4.3. Geochemical Ratios and Water Origin
- Mineral Weathering and Evaporitic Influence: The Na+/Cl− relationship (Figure 11) indicates that the majority of samples plot along the 1:1 line, reflecting the influence of the region’s evaporitic lithology [72] rather than a single mineral source. This is complemented by gypsum/anhydrite dissolution, as evidenced by the distribution of Ca2+ and SO42− near the 1:1 line. However, several samples from Ouled Khoudéir and Timoudi deviate toward an excess of calcium, suggesting additional mineral sources or cation exchange processes [73].
- Carbonate Weathering and Deficits: Standard carbonate weathering typically follows a 1:2 molar trajectory between calcium and bicarbonate. However, the samples exhibit a severe HCO3− deficit, deviating significantly from both the 1:1 meq/L equiline and the 1:2 trajectory in the Ca2+ vs. HCO3− and Mg2+ vs. HCO3− plots [74]. This confirms that limestone and dolomite dissolution are secondary to evaporitic inputs. While the Ca2+ vs. Mg2+ relationship shows some samples near the 1:1 line, supporting some dolomitic limestone dissolution [75], the broad scatter indicates mixed calcium sources.
- Mixed Geochemical Controls: The SO42− vs. Cl− relationship shows a clear linear trend, indicating a common evaporitic origin for these ions, with higher concentrations observed in the terminal discharge zones [76]. The significant excess of Cl− relative to SO42− in high-salinity end-members like obs34 and obs40–45 highlights the impact of evaporative concentration and halite dissolution as the primary drivers of terminal salinity [77]. Finally, the SO42−/Cl− ratio indicates a predominance of sulfate, consistent with the contribution of gypsum dissolution alongside halite in the terminal flow paths [78].
4.4. Ion Exchange Processes and Hydrochemical Evolution
- Direct Cation Exchange (Softening): A significant portion of the samples, particularly those from the more evolved downstream zones like Ouled Khoudéir (e.g., obs40, obs41, obs42, obs45, obs46), plot in the upper-left quadrant. This indicates a direct exchange process where dissolved Ca2+ and Mg2+ are adsorbed onto clay surfaces, releasing Na+ into the groundwater [80]. This process is a key driver for the transition toward Na–Cl–SO4 facies observed in the terminal oases [81].
- Reverse Cation Exchange (Hardening): Conversely, a subset of samples, including those from Ksabi (obs50, obs51) and el Ouata (obs18), plots in the lower-right quadrant. This indicates reverse cation exchange, where Na+ in solution is adsorbed onto clay surfaces, causing the release of Ca2+ and Mg2+ in the groundwater [82].
- Process Dominance and Equilibrium: In zones where samples cluster near the origin, such as certain points from Kerzaz and Beni Yakhlef (e.g., obs24, obs27, obs32, obs33), the chemical signature suggests a state of relative equilibrium where cation exchange is less pronounced compared to the primary influence of mineral dissolution [83]. However, as samples move away from the origin along the regression line, the strong correlation demonstrates that cation exchange becomes the dominant modifier of the major ion chemistry [84].
- Localized Anomalies: While most samples follow the predictable exchange trend, the wide vertical dispersion of samples like obs45 and obs41 suggests that in specific high-salinity locations, the exchange processes are intensified by high ionic strength or localized variations in the clay content of the alluvial matrix.
4.5. Temporal Evolution and Drivers of Groundwater Quality
4.6. Vulnerability and Pollution Index
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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| Sample | Oasis | T °C | pH | Electrical Conductivity (EC) (milliS) | Dry Residue (DR) (mg/L) | Ca2+ (mg/L) | Mg2+ (mg/L) | Na+ (mg/L) | K+ (mg/L) | Cl− (mg/L) | SO4− (mg/L) | NO3− (mg/L) | HCO3− (mg/L) | Total Hardness (TH) (mg/L CaCO3) | Total Alkalinity (TAC) (mg/L CaCO3) | Ion Balance (%) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Obs1 | Igli | 25.3 | 7.6 | 0.8 | 530 | 42 | 42 | 45 | 9.1 | 120 | 95 | 48 | 119 | 277.8 | 98 | −2.2 |
| Obs2 | 26.3 | 7.4 | 0.7 | 480 | 76 | 16 | 35.5 | 7 | 90 | 70 | 28 | 122 | 255.7 | 100 | 2.9 | |
| Obs3 | 26.1 | 7.4 | 0.7 | 440 | 76 | 16 | 35.8 | 7 | 95 | 75 | 9 | 122 | 255.7 | 100 | 3.5 | |
| Obs4 | 24.2 | 7.4 | 0.8 | 500 | 84 | 13 | 45 | 6 | 65 | 160 | 0 | 113 | 263.3 | 93 | 2.5 | |
| Obs5 | 25.9 | 7.7 | 0.7 | 450 | 59 | 21 | 45 | 6.8 | 110 | 78 | 14 | 125 | 233.8 | 102 | −1.4 | |
| Obs6 | 23.1 | 7.6 | 0.9 | 560 | 67 | 16 | 80 | 7.6 | 140 | 80 | 48 | 107 | 233.2 | 88 | 1.20 | |
| Obs7 | Beni Abbès | 24.3 | 7.6 | 1.1 | 740 | 63 | 16 | 150 | 5.2 | 220 | 80 | 19 | 183 | 223.2 | 150 | −0.3 |
| Obs8 | 20.5 | 7.7 | 1.2 | 780 | 76 | 16 | 145.5 | 8.3 | 185 | 180 | 12 | 195 | 255.7 | 160 | −2.9 | |
| Obs9 | 25.4 | 7.4 | 1.2 | 800 | 72 | 34 | 124.6 | 12.2 | 160 | 275 | 9 | 110 | 319.8 | 90 | −0.2 | |
| Obs10 | 26.7 | 7.6 | 0.8 | 510 | 76 | 26 | 37.9 | 6.6 | 105 | 83 | 53 | 119 | 296.8 | 98 | 1.7 | |
| Obs11 | 24.8 | 7.4 | 1.1 | 700 | 118 | 24 | 60 | 6.2 | 120 | 205 | 45 | 146 | 393.5 | 120 | −0.6 | |
| Obs12 | Tamtart | 23.9 | 7.5 | 1 | 620 | 72 | 21 | 90 | 5.4 | 120 | 200 | 34 | 104 | 266.3 | 85 | −2.2 |
| Obs13 | 25.3 | 7.4 | 0.9 | 600 | 84 | 24 | 60 | 5.7 | 90 | 210 | 1.8 | 146 | 308.6 | 120 | −2.2 | |
| Obs14 | 26.6 | 7.6 | 1.2 | 780 | 80 | 21 | 120.9 | 6.5 | 160 | 240 | 35 | 107 | 286.2 | 88 | −2.9 | |
| Obs15 | 31.4 | 7.5 | 1.7 | 1050 | 122 | 26 | 171.8 | 3.3 | 295 | 230 | 15 | 128 | 411.7 | 105 | 1.1 | |
| Obs16 | 30 | 7.5 | 1.6 | 970 | 97 | 58 | 133.6 | 2.8 | 185 | 380 | 21 | 119 | 481.1 | 98 | 0.3 | |
| Obs17 | 26.1 | 7.7 | 0.6 | 391 | 59 | 16 | 33.5 | 3.5 | 50 | 100 | 26 | 104 | 213.2 | 85 | 1.7 | |
| Obs18 | el Ouata | 16.2 | 7.7 | 1.6 | 1100 | 114 | 24 | 194.4 | 7.6 | 150 | 385 | 75 | 125 | 383.5 | 102 | 2.6 |
| Obs19 | 19.6 | 7.5 | 1.2 | 800 | 84 | 50 | 90 | 11.8 | 148 | 280 | 53 | 113 | 415.7 | 93 | −0.7 | |
| Obs20 | 25.5 | 7.7 | 0.9 | 560 | 84 | 24 | 43.6 | 5.9 | 116 | 110 | 35 | 107 | 308.6 | 88 | 2.1 | |
| Obs21 | 21.3 | 7.8 | 1.1 | 710 | 80 | 24 | 105.8 | 7.9 | 100 | 260 | 25 | 156 | 298.6 | 128 | −1.9 | |
| Obs22 | 24.2 | 7.6 | 1.1 | 670 | 34 | 47 | 107.6 | 7.9 | 100 | 260 | 21 | 140 | 278.4 | 115 | −1.9 | |
| Obs23 | 24.3 | 7.8 | 1 | 620 | 84 | 18 | 85 | 6.7 | 108 | 180 | 26 | 146 | 283.9 | 120 | −0.3 | |
| Obs24 | Beni Yakhlef | 24.4 | 7.7 | 0.5 | 350 | 46 | 13 | 40 | 2.7 | 60 | 70 | 17 | 125 | 168 | 102 | −2.8 |
| Obs25 | 24 | 7.6 | 0.5 | 340 | 46 | 13 | 32.5 | 3 | 50 | 28 | 30 | 156 | 168 | 128 | −1.8 | |
| Obs26 | 24.8 | 7.6 | 0.5 | 340 | 59 | 5 | 28.9 | 2.2 | 60 | 30 | 59 | 76 | 167.9 | 62 | 1.7 | |
| Obs27 | 25.1 | 7.6 | 0.6 | 380 | 46 | 13 | 37 | 2.2 | 54 | 50 | 35 | 122 | 168 | 100 | −0.9 | |
| Obs28 | Kerzaz | 25.9 | 7.8 | 0.5 | 300 | 42 | 5 | 40 | 2.4 | 70 | 50 | 14 | 82 | 125.5 | 67 | −3.1 |
| Obs29 | 22.9 | 7.7 | 0.5 | 290 | 42 | 5 | 31.4 | 6.8 | 50 | 60 | 3 | 79 | 125.5 | 65 | 0.6 | |
| Obs30 | 25.8 | 7.5 | 0.4 | 280 | 38 | 5 | 29.4 | 2.1 | 33 | 50 | 21 | 92 | 115.5 | 75 | −2.4 | |
| Obs31 | 20.9 | 7.4 | 0.5 | 340 | 51 | 13 | 31.4 | 2.4 | 58 | 65 | 40 | 70 | 180.9 | 57 | 2.7 | |
| Obs32 | Timoudi | 26.7 | 7.7 | 0.5 | 320 | 38 | 16 | 32 | 2.3 | 35 | 45 | 23 | 137 | 160.8 | 112 | 1.3 |
| Obs33 | 17.4 | 7.5 | 0.5 | 340 | 46 | 11 | 34 | 2.2 | 40 | 40 | 31 | 125 | 160.2 | 102 | 2.5 | |
| Obs34 | 23.2 | 7.8 | 3.1 | 2000 | 257 | 74 | 260 | 10.7 | 395 | 925 | 40 | 37 | 946.5 | 30 | −1.8 | |
| Obs35 | 26.2 | 7.8 | 0.7 | 430 | 67 | 8 | 50 | 3 | 80 | 120 | 15 | 82 | 200.2 | 67 | −0.7 | |
| Obs36 | Ouled Khoudéir | 19.3 | 7.7 | 1 | 600 | 63 | 21 | 106 | 11.2 | 72 | 240 | 1.3 | 162 | 243.8 | 133 | 0.4 |
| Obs37 | 23.8 | 7.7 | 1.1 | 730 | 63 | 39 | 115 | 10.2 | 86 | 310 | 25 | 156 | 317.9 | 128 | −0.9 | |
| Obs38 | 24 | 7.6 | 0.7 | 430 | 63 | 13 | 45 | 6.2 | 70 | 130 | 25 | 104 | 210.9 | 85 | −3.5 | |
| Obs39 | 24.5 | 7.7 | 0.6 | 410 | 59 | 18 | 40 | 8.5 | 63 | 120 | 9 | 113 | 221.5 | 93 | 0.9 | |
| Obs40 | 20.8 | 7.5 | 3.1 | 1945 | 168 | 95 | 335 | 47 | 530 | 620 | 85 | 110 | 810.7 | 90 | 1.5 | |
| Obs41 | 25.8 | 7.4 | 3.1 | 1950 | 181 | 111 | 300 | 42 | 530 | 650 | 60 | 92 | 909 | 75 | 2.1 | |
| Obs42 | 22.6 | 7.5 | 3.3 | 2150 | 173 | 97 | 391.2 | 44.9 | 620 | 620 | 80 | 101 | 831.4 | 83 | 2.1 | |
| Obs43 | 27.3 | 7.7 | 3 | 1880 | 122 | 84 | 326.9 | 45.3 | 500 | 640 | 85 | 95 | 650.6 | 78 | −3.3 | |
| Obs44 | 26.4 | 7.7 | 2.4 | 1500 | 84 | 89 | 247.1 | 51.3 | 380 | 470 | 77.5 | 110 | 576.3 | 90 | 0.1 | |
| Obs45 | 26.6 | 7.4 | 2.6 | 1640 | 126 | 105 | 247.8 | 51.3 | 470 | 470 | 75 | 76 | 747 | 62 | 2.9 | |
| Obs46 | 26.4 | 7.6 | 1.7 | 1160 | 105 | 45 | 170 | 46.1 | 280 | 260 | 70 | 82 | 447.5 | 67 | 5.2 | |
| Obs47 | 20.4 | 7.6 | 1.2 | 1150 | 135 | 34 | 209.2 | 12.8 | 320 | 300 | 65 | 110 | 477.1 | 90 | 2.3 | |
| Obs48 | Ksabi | 26 | 7.8 | 1.2 | 740 | 84 | 42 | 95 | 8.5 | 142 | 280 | 2 | 125 | 382.7 | 102 | 0.4 |
| Obs49 | 21.8 | 7.6 | 1 | 600 | 80 | 29 | 49.1 | 5.5 | 85 | 198 | 5 | 125 | 319.2 | 102 | 0.1 | |
| Obs50 | 21.7 | 7.6 | 1.2 | 800 | 54 | 39 | 150.4 | 10.5 | 96 | 330 | 3 | 168 | 295.4 | 138 | 1.4 | |
| Obs51 | 26.1 | 7.7 | 1.2 | 790 | 63 | 37 | 130 | 10.4 | 80 | 310 | 11 | 214 | 309.7 | 175 | −1.1 |
| PC1 | PC2 | PC3 | PC4 | PC5 | |
|---|---|---|---|---|---|
| T | 0.010 | −0.094 | −0.044 | 0.978 | −0.054 |
| pH | −0.053 | 0.044 | 0.986 | −0.045 | −0.107 |
| EC | 0.967 | −0.084 | −0.019 | 0.034 | 0.209 |
| DR | 0.970 | −0.085 | −0.025 | −0.011 | 0.216 |
| Ca | 0.890 | −0.279 | −0.108 | −0.116 | −0.097 |
| Mg | 0.885 | −0.052 | −0.077 | 0.128 | 0.307 |
| Na | 0.933 | 0.031 | 0.025 | −0.047 | 0.271 |
| K | 0.711 | −0.069 | −0.019 | 0.125 | 0.610 |
| Cl | 0.903 | −0.130 | −0.078 | 0.081 | 0.312 |
| SO4 | 0.961 | −0.101 | 0.057 | −0.075 | 0.026 |
| NO3 | 0.378 | −0.301 | −0.200 | −0.179 | 0.736 |
| HCO3 | −0.127 | 0.977 | 0.027 | −0.052 | −0.106 |
| TH | 0.961 | −0.175 | −0.100 | 0.012 | 0.122 |
| TAC | −0.126 | 0.977 | 0.031 | −0.064 | −0.102 |
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Mekkaoui, A.; Ameri, S.; Belkendil, A.; Merzougui, T.; Larabi, B.; Mansouri, Z.; Al-Farraj, E.S.; Alghamdi, M.A.; Abou El-Reash, Y.G.; Mouni, L. Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria). Water 2026, 18, 831. https://doi.org/10.3390/w18070831
Mekkaoui A, Ameri S, Belkendil A, Merzougui T, Larabi B, Mansouri Z, Al-Farraj ES, Alghamdi MA, Abou El-Reash YG, Mouni L. Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria). Water. 2026; 18(7):831. https://doi.org/10.3390/w18070831
Chicago/Turabian StyleMekkaoui, Abderrahmane, Sarra Ameri, Abdeldjalil Belkendil, Touhami Merzougui, Boudjemaa Larabi, Zineb Mansouri, Eida S. Al-Farraj, Mashael A. Alghamdi, Yasmeen G. Abou El-Reash, and Lotfi Mouni. 2026. "Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria)" Water 18, no. 7: 831. https://doi.org/10.3390/w18070831
APA StyleMekkaoui, A., Ameri, S., Belkendil, A., Merzougui, T., Larabi, B., Mansouri, Z., Al-Farraj, E. S., Alghamdi, M. A., Abou El-Reash, Y. G., & Mouni, L. (2026). Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria). Water, 18(7), 831. https://doi.org/10.3390/w18070831

