A Preliminary Sorption Study of Uranium on MnO2 (Pyrolusite) in the Presence of Siderophore Desferrioxamine B—The Mechanism of a Ternary System
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. U-DFO Solution Preparation
2.3. Sorption Experiments
2.4. Elemental and DFOB Analysis
2.5. Determination of Acetate and Succinate
3. Results and Discussion
3.1. DFOB vs. DFOD
3.2. DFOB pH 6 vs. pH 8
3.3. Ligand-Metal Adsorption Mechanisms
3.4. Type 2 Ligand-like Mechanism
3.5. Type 3 Ligand-like and Metal-like Mechanism
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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[DFOB]supernatant (µM) | [Acetate] (µM) | [U(VI)]sorbed (µM) | [DFOB]supernatant + [Acetate] + [U(VI)]sorbed (µM) | [DFOB]total (µM) |
---|---|---|---|---|
37.44 | 14.35 | 24.4 | 76.19 (±4.00) | 78 |
26.206 | 12.15 | 21.95 | 60.31 (±4.45) | 60 |
14.01 | 10.55 | 15.0 | 39.56 (±0.75) | 37 |
2.02 | 8.40 | 8.59 | 19.01 (±0.36) | 12 |
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Snyder, M.; Hunley, L.; Stanberry, J.; Szlamkowicz, I.; Jones, B.; Anagnostopoulos, V. A Preliminary Sorption Study of Uranium on MnO2 (Pyrolusite) in the Presence of Siderophore Desferrioxamine B—The Mechanism of a Ternary System. Water 2023, 15, 3241. https://doi.org/10.3390/w15183241
Snyder M, Hunley L, Stanberry J, Szlamkowicz I, Jones B, Anagnostopoulos V. A Preliminary Sorption Study of Uranium on MnO2 (Pyrolusite) in the Presence of Siderophore Desferrioxamine B—The Mechanism of a Ternary System. Water. 2023; 15(18):3241. https://doi.org/10.3390/w15183241
Chicago/Turabian StyleSnyder, Morgan, Lucy Hunley, Jordan Stanberry, Ilana Szlamkowicz, Brandon Jones, and Vasileios Anagnostopoulos. 2023. "A Preliminary Sorption Study of Uranium on MnO2 (Pyrolusite) in the Presence of Siderophore Desferrioxamine B—The Mechanism of a Ternary System" Water 15, no. 18: 3241. https://doi.org/10.3390/w15183241