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Open AccessArticle

Activated Carbon from Yam Peels Modified with Fe3O4 for Removal of 2,4-Dichlorophenoxyacetic Acid in Aqueous Solution

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Chemical Engineering Program, Nanomaterials and Computer Aided Process Engineering Research Group, University of Cartagena, Cartagena 130015, Colombia
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Doctorate in Engineering Program, Nanomaterials and Computer Aided Process Engineering Research Group, University of Cartagena, Cartagena 130015, Colombia
*
Author to whom correspondence should be addressed.
Water 2019, 11(11), 2342; https://doi.org/10.3390/w11112342 (registering DOI)
Received: 15 September 2019 / Revised: 30 October 2019 / Accepted: 3 November 2019 / Published: 8 November 2019
The removal of organic pollutants from water sources can be enhanced using suitable adsorbents. The aim of this research was to study the adsorption capacity and potential reuse of a magnetic adsorbent prepared from agricultural wastes of yam peels (Dioscorea rotundata) for 2,4-dichlorophenoxyacetic (2,4-D) acid removal. The procedure was performed through carbonization and activation at 400 and 500 °C, respectively. Then, the as-prepared activated carbon (AC) was chemically modified using magnetite (Fe3O4) nanoparticles. The AC and magnetic activated carbon (MAC) were characterized and then used for batch adsorption and regeneration tests at different pH, initial concentrations of 2,4-D, and temperature. AC and MAC were showed to have microporous structures with surface areas of 715 and 325 m2/g, respectively. Superparamagnetic behavior was observed for MAC with a saturation magnetization of 6 emu/g. The results from the batch experiments showed higher adsorption capacity at high initial concentration of 2,4-D, low pH, and room temperature. The thermodynamic parameters indicated that the experiments proceeded as exothermic and spontaneous adsorption. Our findings also showed that MAC can be separated from the water medium through a facile magnetic procedure, and from regeneration experiments, MAC showed better results with 60% of its initial adsorption capacity after five cycles. Hence, MAC was found to be a promising alternative adsorbent of pesticides in water. View Full-Text
Keywords: yam peel; carbonization; activation; magnetic activated carbon; 2,4-dichlorophenoxyacetic acid yam peel; carbonization; activation; magnetic activated carbon; 2,4-dichlorophenoxyacetic acid
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Herrera-García, U.; Castillo, J.; Patiño-Ruiz, D.; Solano, R.; Herrera, A. Activated Carbon from Yam Peels Modified with Fe3O4 for Removal of 2,4-Dichlorophenoxyacetic Acid in Aqueous Solution. Water 2019, 11, 2342.

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