1. Introduction
Chemical pesticides are an important means employed in crop management for the control of diseases, pests, and weeds. However, the improper use of chemical pesticides can reduce their efficacy and pose significant threats to the surrounding environment and public safety [
1,
2,
3], especially when pesticides move beyond the target area during their application process.
The pesticide is atomized into fine droplets by the nozzle component of the spraying device, forming a droplet cluster. Each individual droplet within the cluster has its own initial droplet size and velocity attributes, and droplets with different properties together form a droplet cluster with a specific size and velocity distribution. The initial distribution of droplets within a droplet cluster significantly influences their trajectories from the nozzle to the target [
4]. Droplets with diameters less than 200 μm, when released from a height of 2 m, exhibit substantial drift under ambient wind conditions of 5 km/h [
5]. The initial droplet size and velocity distributions serve as essential input parameters for constructing models of droplet trajectories [
6,
7,
8]. Using computational fluid dynamics (CFD), Tang [
9] simulated the downwash flow field generated by a single-rotor unmanned aerial vehicle (UAV) and analyzed the trajectories of droplets influenced by this flow field. At 3.8 bar spray pressure, they experimentally measured the initial distribution of droplet characteristics and used these as the principal characterizing droplet dispersion in the trajectory model. In addition to numerical simulation approaches, researchers have also validated the influence of nozzle atomization patterns on both the deposition quality of pesticide droplets within target areas and the drift risk in non-target zones through extensive experimental investigations [
10]. Liu [
11] conducted experiments using PIV systems and wind tunnel laboratories to investigate the atomization characteristics and drift behavior of various hydraulic nozzles spraying different pesticide adjuvants. By analyzing the correlation between droplet size distribution and drift potential, the study revealed a strong and statistically significant relationship between the proportion of droplets smaller than 150 μm in the initial atomized droplet group and the drift potential. Current research on the influence of atomization characteristics on droplet deposition predominantly focuses on droplet size [
12,
13]. Correspondingly, existing nozzle classification criteria are primarily based on the measurement of droplet diameter, with little consideration given to droplet velocity. This is largely due to the inherent difficulty in accurately measuring droplet velocity and the associated challenges in interpreting such measurements. For hydraulic nozzles, increasing the spray pressure not only results in smaller droplet sizes but also leads to higher initial droplet velocities. While smaller droplets tend to increase the risk of drift due to their lower inertia, the higher initial velocities reduce the airborne residence time of the droplets, thereby mitigating the overall drift potential. Therefore, the trajectory of droplet movement is determined by the combined effect of droplet size and velocity. Therefore, assessing the influence of atomization performance on droplet trajectories solely from the perspective of droplet size is incomplete. Droplet velocity is likewise critical. In particular, the downwash flow generated by agricultural UAVs assists droplet transport toward the target [
14], and the initial ejection velocity can substantially affect in-flight trajectories. This contrasts with conventional ground-based sprayers, for which droplet speeds may rapidly decay to minimal levels due to aerodynamic drag. Accordingly, this study focuses on investigating the distribution of droplet size and velocity under different spraying conditions.
The atomization characteristics of nozzles are influenced by a variety of factors, among which liquid spray pressure is a critical parameter. In the study conducted by Ferguson [
15], the liquid pressure was adjusted to achieve different spray volumes, thereby altering the initial droplet size distribution. The results demonstrated that, compared to a spray volume of 50 L/ha, a spray volume of 100 L/ha resulted in a finer droplet spectrum, with a higher proportion of smaller droplets. In addition to droplet size, the velocity of droplets plays a critical role in determining their residence time in the air. Higher droplet velocities confer greater momentum, enhancing the droplets’ ability to penetrate through air resistance and thereby reducing the risk of drift. Dorr et al. [
16] investigated the droplet size and velocity distributions produced by various types of hydraulic nozzles under different spray pressures. Based on these experimental observations, a regression model was established to describe the relationship between droplet velocity, spray pressure, and droplet size. The physical properties of the solution, namely surface tension, viscosity, and density, also influence the initial distribution characteristics of the generated droplets. Among these properties, surface tension and viscosity play critical roles during the formation of the liquid sheet as the solution passes through the nozzle. Furthermore, these two parameters significantly affect the subsequent atomization process, during which the liquid sheet interacts with the surrounding airflow to form droplets. These interactions ultimately govern the resulting droplet size distribution. To reduce droplet drift, Hoffmann et al. [
17] conducted experiments in a high-speed wind tunnel to simulate aerial spraying conditions. They investigated the effects of eight different spray adjuvants—each characterized by distinct surface tension and viscosity properties—on the droplet size distribution of spray mixtures. The airflow environment surrounding the nozzle plays a critical role in influencing the atomization process of the liquid sheet. This environment encompasses both the natural airflow present in the ambient field conditions and the artificial airflow disturbances induced by the operation of spraying equipment. During aerial spraying with fixed-wing aircraft, the high-speed flight significantly increases the relative velocity between the nozzle and the surrounding air, thereby intensifying the breakup of the liquid sheet. In the case of rotor-based UAVs, the downward airflow generated by rotor rotation exerts a pronounced effect on droplet atomization. By contrast, under natural field conditions, the ambient airflow is relatively weak and predominantly influences the transport of atomized droplets toward the target [
18]. Extensive research has been conducted on the structural design of nozzles by scholars aiming to mitigate droplet drift [
19,
20,
21]. To this end, drift-reducing nozzles have been developed based on the Venturi principle [
22]. These nozzles introduce high-speed airflow into the liquid pesticide stream, facilitating gas–liquid mixing during both the liquid sheet formation and the subsequent atomization into droplets. This incorporation of air leads to the generation of gas-filled droplets, which exhibit increased droplet sizes and thereby reduce the likelihood of drift.
Based on the foregoing analysis of the factors influencing initial atomization, it is clear that, for flat-fan nozzles commonly used on crop-protection UAVs, spray pressure, the physicochemical properties of the spray liquid, and the geometric parameters of the nozzle are the key determinants. Prior studies have largely compared atomization performance across multiple nozzle types or among several spray adjuvants. However, systematic investigations focused on a specific nozzle–adjuvant combination are scarce. Such work is necessary because, in practice, frequently changing nozzles and adjuvants to accommodate operating conditions is cumbersome for operators. Therefore, this study, using a nozzle and adjuvant commonly employed on UAVs, investigates in depth the effects of adjuvant concentration and spray pressure on the liquid sheet breakup process and the initial atomization characteristics of a representative flat-fan nozzle, with the aim of providing a scientific basis for improving the deposition performance of pesticide droplets and mitigating their drift during field application.
2. Materials and Methods
The experimental setup used in this study is shown in
Figure 1, and it concludes a PIV system and a spraying system. The test site is shown in
Figure 2.
2.1. Spraying Systems
In the spraying system, water and SDS solutions of different concentrations stored in a tank were pressurized by a hydraulic pump, adjusted to the required experimental hydraulic pressures through a pressure control valve, and then transported through pipes to the nozzle, where they were atomized into droplets. An overflow valve was installed in the pipeline to serve as a safety mechanism, protecting the hydraulic system. A thermometer (TJ36-CAXL, Omega, Manchester Township, NJ, USA) was placed inside the tank to monitor the temperature of the solution, ensuring that the temperature variation of the solution remained within ±1 °C throughout the entire experimental period. The nozzle utilized in this study was a hydraulic nozzle (Teejet 110015, Spraying Systems Co., Ltd., Wheaton, IL, USA) commonly used on commercial plant protection drones. According to the manufacturer’s specifications, the spray angle of this nozzle model is 110° at a spray pressure of 0.28 MPa.
2.2. PIV-Based Flow Visualization Technique
The PIV system produced by TSI Incorporated was used to capture the dynamic evolution of liquid sheet and atomization information. The acquired data were subsequently extracted and analyzed for further insights. The PIV system consists of a CCD camera, a laser device, a synchronizer, an image analysis software, and a macro lens. The Litron laser device, consisting of a dual-pulse laser, a laser source and two laser arms, is capable of emitting two independent laser beams with a maximum emission frequency of 15 Hz. In this experiment, the emission frequency was set to 7.5 Hz. The time interval between the emissions of the two laser beams is dependent on the velocity of the liquid sheet. The laser source employed to empower the dynamic flow field includes a cylindrical lens and a spherical lens. The cylindrical lens expands the field angular of view of the light, while the spherical lens is used to control the thickness of the light sheet in the measurement area. The laser source is adjusted to achieve a laser sheet thickness of approximately 1 mm in the measurement region, where the laser intensity is relatively high at this thickness. The lens plane of the CCD camera (model 630091) with a resolution of 2048 × 2048 pixels is parallel to the liquid sheet plane during atomization in order to capture the plane information of the liquid sheet. The CCD camera, laser, and workstation are all connected through a synchronizer (model 610036), enabling coordinated operation of the system components. Upon receiving a command from the workstation, the synchronizer triggers the camera and laser to operate synchronously, positioning itself as the central component within the entire system. In addition to the hardware components used for data acquisition, the Tecplot software 11.1.0 is employed to analyze the motion parameters of particles, thereby obtaining the velocity field and size field of the droplet within the images.
The laser emitted by the laser source is co-planar with the spray plane, and the plane of the CCD camera lens is parallel to both the spray plane and laser plane. In this experiment, the distance between the nozzle and the laser source is 1 m, while the distance between the nozzle and the camera is 0.5 m.
Before the experiment, the camera position was adjusted to ensure that the entire liquid sheet and the initial droplets formed are within the field of view. A steel ruler was placed vertically in the same plane as the liquid sheet beneath the nozzle to calibrate the relationship between image pixels and actual dimensions. The calibration value for this experiment is that one pixel represents 39.92 µm. Each experimental group was repeated 100 times for image capture. Due to the laser emitting dual pulses during each exposure time of the camera, the frame capture system takes two snapshots per exposure. Therefore, each treatment resulted in a total of 200 frames of images.
2.3. Spray Mixtures
In this experiment, the SDS adjuvant (neoFroxx GmbH, Einhausen, Germany) was chosen to determine the surface tension of the solution. To investigate the effects of solution surface tension on liquid sheet breakup and atomization, different concentrations of SDS solutions were prepared. According to the study of Song [
23], when the concentration of SDS exceeds 0.5%, the reduction in surface tension becomes slower and less significant. Therefore, the SDS solutions were configured with the concentrations of 0, 0.2%, 0.5%, and 1.0%, respectively. By analyzing the data from these concentrations, the interplay how the surface tension impacts liquid sheet breakup and ultimately the effectiveness of atomization in agricultural spraying systems was understood. For the preparation of spray solution, ultrapure water was used as the solvent, which was produced by an ultrapure water system (Milli-Q, Millipore Corporation, Billerica, MA, USA). The ultrapure water produced by filtering regular water through the two-stage purification columns of the ultrapure water system contains very few impurities and has a high purity, meeting the water quality requirements for the spraying experiment.
The physical properties of the solution mainly include surface tension, viscosity, and density. The surface tension, viscosity, and density parameters of SDS solutions at different concentrations were measured using a surface tensiometer (EZ-Piplus, Kibron, Helsinki, Finland), a viscometer (NDJ-5S, Bangxi Instrument Technology Co., Ltd., Shanghai, China), and a densimeter (XF-120YT, Lichen Technology, Shanghai, China). The indoor temperature and relative humidity during the measurement of the solution’s physical properties were maintained at 25 ± 1 °C and 55% ± 2%, respectively. In this experiment, each spraying solution to be tested was atomized using a series of spray pressures ranging from 0.10 to 0.50 MPa, with an interval gradient of 0.05 MPa (0.10, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, and 0.50 MPa). The pressure levels were selected based on the pressure range attainable from the agricultural UAV’s pump.
2.4. Data Processing and Analysis
The Tecplot software in the PIV system was used for data extraction and analysis of the captured atomization flow field images. This process includes image calibration, image preprocessing, selection of the computational domain, image processing methods, and data post-processing. Image calibration is used to establish the relationship between image pixels and the actual size of the scene. Through preprocessing, the color image can be converted into a grayscale image, which facilitates subsequent droplet recognition and vector calculation. The Super-resolution Particle Velocimetry module was used to calculate the size and velocity vectors of droplet within the computational domain. Droplets in the image were identified when their grayscale value exceeds 40 and the droplet size was calculated through the calibration relationship. When calculating velocity vectors, the computational grid size was adjusted so that the displacement of droplet between a pair of images does not exceed one-quarter of the grid. Image post-processing involved repairing particles with calculation errors during the image processing, mainly by averaging the velocity vectors of the 5 × 5 surrounding droplets to provide the corrected value.
The breakup point refers to the position where the liquid sheet initial breaks and forms a liquid ribbon, and the breakup distance is the distance between the breakup point and the center of the nozzle exit. In actual spraying, the breakup distance is not constant, as the breakup point of the liquid sheet is primarily influenced by unstable waves, exhibiting periodicity. To ensure sufficient breakup of droplets and to detect their initial distribution, a 2 mm wide atomization zone was selected 60 mm below the nozzle to observe the breakup length of the liquid sheet, as shown in
Figure 3.
Data within the target regions of the acquired images were processed and extracted. Examination of the raw data revealed several outlier droplets, likely caused by PIV system noise, the projection of multiple droplets onto a two-dimensional plane being misidentified as a single large droplet, or secondary fragmentation of individual droplets. This led to mismatches between consecutive frames and abnormal velocities. To reduce the impact of these outliers, anomalous values were identified and removed using the interquartile range (IQR) method.
The droplets formed by the breakup of the liquid ribbon exhibited irregular shapes and quickly shrank into approximately spherical shapes under the action of surface tension. Due to the high speed of the droplets after initial atomization and the influence of air resistance, coarser droplets underwent deformation. Equation (1) is used to calculate the diameter of irregular spheres. In the formula,
d1 represents the short axis length (µm) of the irregular sphere, and
d2 represents the long axis length (µm) of the irregular sphere.
According to the ASABE S641 standard [
24] published by the American Society of Agricultural and Biological Engineers (ASABE), the median droplet volume diameter (D
V0.5) was used as an indicator of the overall droplet size distribution in a droplet group. Therefore, this experiment also used the D
V0.5 parameter to measure the initial droplet size distribution. Additionally, based on the research by Ferguson et al. [
15], droplets smaller than 150 µm had a higher potential for drift. Therefore, this experiment adopted the V
<150(%
vol) parameter to assess the degree of drift susceptibility in the droplet group. Specifically, the D
V0.5 refers to the droplet size corresponding to the point where the cumulative volume of droplets, arranged from smallest to largest, reaches 50% of the total detected volume during a spray. V
<150(%
vol) refers to the percentage of the total detected droplet volume made up of droplets smaller than 150 µm.
4. Discussion
This study investigated the effects of surfactant solution concentrations and spray pressures on atomization characteristics, including liquid sheet breakup length, initial droplet size, and droplet velocity distribution. The results showed that the concentration of the surfactant solution, which governs the surface tension of the solution, significantly influenced atomization metrics. Higher concentrations facilitated the expansion of the liquid sheet surface, thereby increasing the breakup length and prolonging the breakup process. Spray pressure also influenced droplet performance. It changed the liquid sheet breakup mode. As spray pressure increased, the breakup length gradually decreased, leading to a smaller overall droplet size distribution and a broader velocity distribution. The concentration of surfactant in the solution had a significant effect on the droplet distribution, mainly due to the lower surface tension of high-concentration surfactant solutions, which enhanced the liquid sheet’s expansion capability. To seek a new mechanical equilibrium, the breakup point of the liquid sheet moved from its original position to a location with lower inertial forces, corresponding to a lower velocity direction. As the liquid sheet moves through the air, the velocity decreases with distance from the nozzle due to air resistance, causing the breakup point to move farther from the nozzle, consistent with the findings of Miller’s research [
27]. However, it should be noted that although surfactant concentration can modify the liquid sheet breakup length and the median droplet diameter (D
V0.5), its influence on the shape of the initial droplet-size distribution is limited, which remained a normal distribution with a peak in the 100–200 µm range. Notably, the surfactant concentration not only altered the liquid sheet breakup length but also modified the shape of the initial droplet-size spectrum. Therefore, in practical applications, the optimal droplet size for pest control should first be determined, followed by selecting the appropriate nozzle type and model. Distinct from prior studies [
28,
29,
30], we collected the atomized droplets as comprehensively as possible and performed statistical analyses. Characterizing the spray with the droplet-size spectrum provides a more complete description of the population. Accordingly, the volume median diameter (D
V0.5) computed from the collected droplet statistics is more reliable than that obtained using a laser diffraction particle-size analyzer.
The experiments also revealed that the concentration of surfactant affects droplet velocity. Prior studies have mainly examined the effect of surfactants on droplet size [
31,
32], with limited attention to droplet velocity. However, high surfactant concentrations reduce droplet velocity. This finding indicates that researchers developing droplet deposition models should comprehensively account for the properties of the initial droplet population—not only the size distribution but also velocity—to improve model accuracy.
This study also has certain limitations. Although the adjuvant selected in the experiments is commonly used in crop-protection UAV applications, differences in molecular structure among adjuvants lead to variations in their dynamic response behavior. Therefore, future research should place greater emphasis on the dynamic surface tension of adjuvants and further explore the response mechanisms of adjuvants tailored for crop-protection UAV spraying applications.