1. Introduction
The accumulation of non-biodegradable plastic waste has become one of the most significant environmental problems of our time. Global plastic production has increased dramatically over the last fifty years, and polyethylene (PE) has become one of the most common types of plastic waste [
1,
2,
3,
4,
5]. Traditional disposal methods such as landfilling or incineration not only lead to the use of valuable land but also increase environmental pollution and greenhouse gas emissions [
6]. Therefore, researchers are increasingly investigating the use of waste plastics in construction materials to both reduce the waste management problem and develop new materials.
Concrete, one of the most commonly used materials in the construction sector, offers a significant opportunity for the recovery of plastic waste. Using plastics in concrete can both reduce the amount of waste going to landfills and decrease the need for natural aggregates. Therefore, plastic-modified concrete is seen as a viable solution compatible with the circular economy approach and economically advantageous in resource-scarce regions [
7,
8,
9,
10,
11]. Studies have shown that replacing natural aggregates with polyethylene types such as high-density polyethylene (HDPE) and low-density polyethylene (LDPE) can reduce the thermal conductivity and energy consumption of building elements [
6,
12]. Furthermore, the use of LDPE instead of fine aggregate has been investigated, and X-ray diffraction analyses have shown that this material has a partially crystalline structure and can be compatible with the cement matrix [
13]. In studies where LDPE pellets were used in permeable concrete, it was observed that abrasion resistance increased, but compressive strength generally decreased [
14]. In addition, it has been reported that recycled plastics can be used as aggregates, fibers, or additives in concrete and asphalt mixtures and can provide benefits such as reduced density, increased crack resistance, and improved durability under appropriate conditions [
15,
16].
In addition to concrete applications, innovative methods have emerged in developing countries. One of these methods is melting waste LDPE bags and mixing them with sand. Durable pavement blocks are produced from this mixture. These materials are called LDPE binder sand composites. And they can achieve compressive strengths close to concrete. This method offers both environmental and economic benefits in regions where recycling infrastructure is insufficient [
17]. In addition, LDPE has been used in cementless pavement blocks, lightweight concrete, and self-compacting concrete. In these applications, the use of LDPE generally contributes to reduced density, increased flexural strength, and improved thermal properties [
18,
19]. Furthermore, it has been determined that PE-containing mixtures can exhibit sufficient mechanical performance in some non-structural elements. The use of LDPE in concrete is being investigated, particularly in terms of its potential to reduce thermal conductivity and increase the ductility of the material [
20,
21].
Studies on polymer-modified asphalt concretes are also noteworthy. Studies have shown that mixing HDPE and LDPE-containing aggregates with dry or wet mixing methods can improve rutting resistance, Marshall stability, stiffness, and durability [
22,
23,
24,
25,
26]. Similarly, studies where recycled concrete aggregates were mixed with polyethylene granules yielded stiffness and modulus of elasticity values that could be suitable for pavement base and substrate applications [
27]. Other studies also show that replacing some of the natural aggregates in asphalt mixes with LDPE or HDPE aggregates can improve rutting resistance, modulus of elasticity, and modulus of dynamics [
28].
While there are advantages to using LDPE in some structural materials, there are also some disadvantages. Substituting LDPE in concrete generally leads to a decrease in compressive strength. This can be attributed to the weak bond between LDPE particles and cement [
29]. However, some studies show that LDPE is feasible when used in low proportions. Substitution rates between 5% and 20% are generally recommended to achieve a suitable balance between the mechanical performance of the building material and the environmental benefit [
30,
31]. Furthermore, studies highlight that recycled LDPE can offer advantages in terms of thermal insulation, durability, and sustainability. However, attention should be paid to the percentage of substitution to minimize strength losses.
Prior investigations [
32,
33] into the utilization of LDPE as a replacement material in construction have introduced predictive models aimed at estimating mechanical performance. Among these contributions, one study developed equations suggesting that the extent of LDPE substitution exerts an influence on both compressive and tensile strengths through linear relationships. The equation for compressive strength suggested in [
32] is presented in Equation (1), whereas the corresponding tensile strength relationship is provided in Equation (2). In these equations,
represents the percentage of LDPE incorporated as a replacement,
represents the tensile strength of those specimens, and
represents the compressive strength of specimens containing LDPE.
In this research, LDPE was incorporated into concrete as a partial substitute for river sand, with replacement levels of 10%, 20%, and 30% by volume. This approach was adopted to support the preservation of natural resources while simultaneously enhancing the recycling of LDPE. In addition to the experimental program, results from similar studies on concrete and mortar reported in the literature were compiled. And the relationships among the experimental results were examined. Based on this analysis, exponential models were proposed for LDPE-substituted concrete and mortar instead of the previously suggested linear models. Despite the growing number of studies on LDPE-modified concrete, limited research has focused on developing reliable predictive models for estimating mechanical properties based on LDPE content. Therefore, this study aims to address this gap by proposing and validating exponential prediction models based on an extensive experimental database.
2. Materials and Methods
Grain size distributions of the aggregates were determined by performing individual sieve analyses on the coarse and fine aggregate (crushed limestone and river sand), following the methodology outlined in EN 933-1 [
34].
Table 1 presents the sieve analysis results for crushed limestone.
Table 2 presents the sieve analysis results for river sand.
CEM I 42.5 R type Portland cement was used in the concrete mixes. This cement conforms to the properties defined in EN 197-1 [
35] standard. The LDPE granules employed in this investigation were sourced from a recycling plant located in Türkiye. A visual representation of LDPE granules is given in
Figure 1. The properties of LDPE, coarse aggregate, and fine aggregate are summarized in
Table 3.
Coarse and fine aggregate, cement, LDPE, and water were added to a mechanical mixer and the machine was started. This ensured proper distribution, and concrete samples were prepared. To maintain consistency throughout the experiment, the ratios of coarse aggregate, cement, and water were kept constant. The water-to-cement ratio was chosen as 0.5. 10%, 20%, and 30% by volume of river sand were replaced with LDPE. The reference mixture (0% LDPE) was designed to achieve a target strength consistent with the C25/30 concrete class, providing a standard structural baseline for the evaluation of LDPE-modified samples.
The mix proportions of all concrete specimens are presented in
Table 4. The quantities of each material were kept constant except for the fine aggregate, which was partially replaced by LDPE at specified ratios. A coding method was used to distinguish the samples during the test. The details of the sample name coding are given in
Table 4.
Fresh concrete was subjected to a slump test and evaluated for workability. Specimens of cylindrical geometry (100 mm × 200 mm) were produced for testing both compressive strength and splitting tensile strength. Beams with dimensions of 100 × 100 × 400 mm were prepared for flexural strength testing. Compressive, splitting tensile, and flexural strength specimens were subjected to water curing for 28 days. The curing process was carried out in a water tank at a temperature of 20 ± 2 °C to ensure consistent hydration conditions for all specimens. They were then dried, weighed, and their densities determined.
A compressometer was used for compressive strength evaluation. To ensure the reliability of the results, axial and lateral deformations were monitored using two independent measurement systems: potentiometers connected to a compressometer and strain gauges attached directly to the specimens. The displacement values obtained from these two systems were compared and found to be in close agreement. The reported deformation values were determined by averaging the results obtained from both measurement techniques. All compressive strength tests were conducted under controlled loading conditions, and the loading rate was maintained constant at 0.5 MPa/s to ensure consistency and comparability of results. Stress and strain values were obtained. The experimental setup is shown in
Figure 2.
In the splitting tensile strength test, a cage was used to subject cylindrical specimens to tensile force. During the test, the specimens, which were previously placed vertically in the compressive strength test, were this time placed horizontally on the machine. Each specimen was loaded at a constant rate of 0.5 MPa/s. The highest load withstood before fracture was considered the splitting tensile strength.
The flexural performance of the concrete was assessed using prismatic beam specimens subjected to a three-point bending configuration. In this setup, the support span was fixed at 300 mm, and the loading was applied at a constant displacement rate of 5 mm/min.
3. Concrete Tests
Specimens of concrete were tested for slump, density, and mechanical properties including compressive, tensile, and flexural strengths. The full dataset is reported in
Table 5.
3.1. Compressive Strength Test
Figure 3 displays the stress–strain responses generated during the compressive strength testing. The corresponding values of peak compressive strength (
), the axial strain at peak stress (
), and the lateral strain recorded at the same stress level (
) are summarized in
Table 6. According to the test results, the reference concrete mixture without LDPE exhibited a compressive strength of 26.91 MPa.
A gradual decrease in compressive strength occurred as a result of increasing LDPE substitution for fine aggregate. At a 10% substitution level, the strength decreased by 12.93% and fell to 23.43 MPa. When the substitution rate was 20%, the decrease became more pronounced, reaching 27.73%, and the strength became 19.45 MPa. The most significant decrease occurred at 30% substitution, and the strength decreased by 38.45% to 16.56 MPa. The results indicate that incorporating polymer-based materials leads to a reduction in the concrete’s load-bearing capacity.
Although compressive strength decreased with increasing LDPE substitution percentage, axial and lateral strain values increased. Mixtures containing LDPE showed greater deformation capacity before fracture. Specifically, axial strain increased by 6.25%, 11.60%, and 17.19% at 10%, 20%, and 30% LDPE substitution levels, respectively. Lateral strain increased by 9.82%, 38.12%, and 48.75% at the same substitution rates. These results indicate that LDPE substitution reduces the strength of concrete while simultaneously increasing its ductility.
The reduction in strength may be attributed to the low stiffness and weak interfacial bonding between LDPE particles and the cement matrix. In addition, differences in elastic properties between LDPE and river sand may lead to stress concentrations within the interfacial transition zone. However, the higher strain measurements suggest that LDPE-modified mixtures can undergo greater deformation before fracture. This property may be advantageous in applications where deformation capacity and ductility are prioritized over high compressive strength. This increased deformability can improve energy dissipation and seismic performance, as the material resists brittle failure by enduring larger strains.
3.2. Splitting Tensile Strength Test
Increasing the level of LDPE substitution decreased the splitting tensile strength. At 10% substitution, the strength decreased by approximately 8.22% to 2.26 MPa. At 20% substitution, the strength decreased by approximately 18.37% to 2.01 MPa. The most significant decrease occurred at 30% substitution. At 30% substitution, the splitting tensile strength decreased by approximately 25.26% to 1.84 MPa. The results obtained from the splitting tensile strength test are given in
Table 7.
3.3. Flexural Strength Test
Flexural strength was determined by means of a three-point bending test.
Figure 4 displays the stress–strain responses, and
Table 8 summarizes the peak strength and strain values.
A gradual decrease in flexural strength was observed with increasing LDPE substitution for river sand. At 10% substitution, the strength decreased by 7.61% to 3.12 MPa. At 20% substitution, the strength decreased by 16.64% to 2.81 MPa. The most significant decrease occurred at 30% substitution. At 30% substitution, the strength decreased by 23.35% to 2.59 MPa. These results show that LDPE substitution reduces the maximum flexural stress values of the concrete.
Conversely, the maximum strain values increased with higher LDPE content. With 10% substitution, the flexural strain increased by 13.76%. At 20%, the increase was 28.33%. And at 30%, it increased by 33.90%. This shows that despite the decrease in flexural strength, concrete with LDPE substitution has the ability to deform further before fracturing.
3.4. Modulus of Elasticity Test
Table 9 presents the modulus of elasticity values determined through compressive strength tests, calculated from the associated stress–strain responses. The modulus of elasticity of concrete without LDPE was calculated as 30,574.17 MPa.
A decrease in the modulus of elasticity was observed with increasing LDPE substitution for river sand. At 10% substitution, the modulus of elasticity decreased by 15.57% to 25,815.23 MPa. At 20% substitution, a modulus of elasticity of 21,027.20 MPa was obtained, a decrease of 31.23%. The most significant decrease occurred at 30% substitution. At 30% substitution, the modulus of elasticity decreased by 34.46% to 20,039.28 MPa.
3.5. Slump Test
The concrete slump test results are shown in
Figure 5. The slump value of the mixture without LDPE was measured as 48 mm. The slump values decreased continuously as a result of replacing river sand with LDPE. When 10% of the river sand was substituted with LDPE, the slump decreased by 8.33%, reaching 44 mm. At a 20% replacement level, the slump dropped by 16.67% to 40 mm. The most pronounced reduction was observed at 30% replacement. When 30% was replaced, the slump value decreased by 27.08% to 35 mm.
3.6. Density Test
The density outcomes of the concrete mixtures are illustrated in
Figure 6. For the reference mix without LDPE, the measured density was 2307.88 kg/m
3.
Substituting LDPE for river sand caused a decrease in density. At 10% substitution, the density decreased by 4.02% to 2215.18 kg/m3. At 20% substitution, it decreased by 5.73% to 2175.53 kg/m3. The most significant decrease occurred at 30% substitution. At 30% substitution, the density decreased by 8.93% to 2101.71 kg/m3.
4. Assembly of Experimental Results and Development of Models
This section aims to develop models that predict various properties of concrete and mortar containing LDPE. To this end, a comprehensive dataset was compiled. This dataset was created using data from previous studies where LDPE was used as a partial substitute for fine aggregate. Experimental results obtained in this study were also included in this dataset. The experimental data compiled for LDPE-substituted concrete and mortar are summarized in
Table 10.
The table compiled in this study is based on a comprehensive literature review conducted under specific boundary conditions. Only studies involving fine aggregate substitution were considered, while those including coarse aggregate substitution were excluded. In addition, only granular LDPE substitution was taken into account, and fiber-based substitutions were not included. The dataset is limited to concrete and mortar samples, excluding self-compacting concrete. Furthermore, only LDPE-substituted mixtures were considered, and no other types of plastic were included. For compressive strength (CS), tensile strength (TS), and flexural strength (FS), only 28-day test results were collected. In cases where cube specimens were used to determine compressive and tensile strengths, equivalent cylinder strengths were calculated by applying a conversion factor of 0.8 and reported separately in the table. The modulus of elasticity (MoE) values are also included. Details regarding sample dimensions are provided; if not explicitly stated, the relevant testing standard is specified instead. Additionally, the table presents the specific gravity, bulk density, and particle size of the LDPE material, as well as the substitution percentage. Concrete density values, water-to-cement (W/C) ratios, and slump test results are also reported in the table.
Using the assembled experimental database, new predictive relationships were established to evaluate the main mechanical and physical characteristics of concrete and mortar containing LDPE. These models were formulated to estimate properties such as modulus of elasticity, compressive strength, flexural strength, and tensile strength. Their reliability was subsequently examined by comparing the predictions with equations previously reported in the literature.
The agreement of model estimates with experimental observations was calculated using the statistical indicators given in
Table 11. These statistical indicators are mean absolute percentage error (MAPE), mean absolute bias error (MABE), and the coefficient of determination (R
2). The R
2 value indicates the quality of fit of the model with the variance in the experimental data. MABE represents the mean absolute deviation between the estimated and observed values. MAPE expresses this deviation as a percentage [
40,
41,
42,
43].
In
Table 11,
denotes individual experimental measurements, whereas
corresponds to the respective model predictions. The terms
and
indicate the mean values of the experimental results and model outputs, respectively.
4.1. Formulation of the Compressive Strength Prediction Model
The compressive strength values reported in earlier studies are given in
Table 11. In order to examine the influence of LDPE incorporation on compressive strength, a compressive strength ratio (
) was determined. This ratio was calculated by dividing the compressive strength of concrete containing LDPE by that of the corresponding reference concrete mixture. In this formulation, (
) is defined as the compressive strength of concrete incorporating LDPE, whereas (
) corresponds to the compressive strength measured for the control specimen.
The influence of LDPE replacement is depicted in a graph where the vertical axis represents the compressive strength ratio and the horizontal axis indicates the percentage of LDPE substitution (
). Ratios exceeding unity signify an enhancement in compressive strength due to LDPE incorporation, whereas values below unity reflect a reduction. The corresponding graphical illustration is provided in
Figure 7.
Trendlines were applied to the data to formulate the effect of LDPE on experimental results. These lines were generated to represent the experimental outcomes obtained in the present study, mortar mixtures, concrete mixtures, as well as the complete dataset. Exponential trend lines were found to provide more accurate predictions compared to linear trend lines. The resulting exponential equations are presented in
Table 12.
Previous models proposed in the literature for LDPE-modified concrete and mortar, and the models proposed in this study, were evaluated using statistical parameters. The results of this evaluation are presented in
Table 13 and
Table 14.
The model proposed by Sancak et al. for estimating the compressive strength of LDPE-substituted concrete demonstrated higher performance than the previously proposed model by Mohammed et al. [
32], with an R
2 value of 0.719. The use of a linear function in the Mohammed et al. model [
32] had a negative effect on the R
2, MABE, and MAPE values. In contrast, the exponential function proposed by Sancak et al. was found to be more compatible with the response of concrete to increasing LDPE ratios.
Figure 8 presents a graphical evaluation of the models, displaying R
2 and MABE metrics.
Table 14 provides a performance comparison of the proposed models for LDPE-substituted mortar. In
Table 14, the symbol
denotes the density of mortar incorporating LDPE,
denotes water-to-cement ratio,
denotes LDPE content and
denotes curing age.
Among the evaluated models, the model proposed by Sancak et al. provided the highest prediction accuracy for the compressive strength of LDPE-substituted mortar. This model has an R
2 value of 0.981. The Ohemeng and Ekolu [
33] (Mortar I) model came in second with an R
2 value of 0.759. In contrast, the model introduced by Muhammed et al. [
32] showed a very poor prediction performance. This model has only an R
2 value of 0.069.
Figure 9 presents a graphical comparison of the R
2 and MABE values of these models.
4.2. Formulation of the Tensile Strength Prediction Model
A method similar to that used for generating compressive strength models was followed in generating splitting tensile strength models. A graphical representation was created where the vertical axis represents the tensile strength ratio (
) and the horizontal axis represents the LDPE substitution percentage (
). The resulting graph is shown in
Figure 10.
Trendline analyses were carried out on the plotted datasets to determine the mathematical relationship between the LDPE replacement percentage and the tensile strength ratio. The analysis considered four different groups of data: the experimental results obtained in the present study, experimental data reported in the literature for concrete mixtures, experimental data for mortar mixtures, and a combined dataset including all available results related to LDPE substitution in concrete.
The equations obtained from this analysis are given in
Table 15. These equations show how the percentage of LDPE substitution affects the tensile strength. In
Table 15,
is defined as the tensile strength of concrete incorporating LDPE, while
corresponds to the tensile strength of the reference mix without LDPE. The parameter
denotes the proportion of LDPE particles employed as a substitute for fine aggregate.
Tensile strength models for LDPE-modified concrete reported in prior studies, together with the models developed in this work, were examined using statistical measures derived from the unified experimental dataset. The findings of this evaluation, along with the relevant equations, are presented in
Table 16. The survey of prior studies revealed that no existing model has been published which explicitly examines the relationship between LDPE substitution levels and the tensile strength of mortar.
The tensile strength model proposed by Sancak et al. performed better than the previous model proposed by Mohammed et al. [
32]. The Sancak et al. model achieved an R
2 value of 0.835. Both approaches produced comparable predictions when applied to a limited amount of data. However, the exponential formulation proposed by Sancak et al. more consistently matched the behavior of concrete for increasing LDPE substitution levels. A comparison of the models in terms of R
2 and MABE indicators is shown in
Figure 11.
Extensive research has explored the interrelation between the compressive and tensile strengths of concrete, with several studies proposing empirical formulations to characterize this linkage. The present work critically reviews these prior approaches and seeks to establish comparable models by utilizing a consolidated experimental database. To illustrate the relationship, a graph comparing compressive and tensile strengths was prepared. During the creation of the dataset, it was observed that there were differences in sample geometry among the studies in the literature. In previous studies, compressive strength was generally measured on cubic specimens, while tensile strength was measured on cylindrical specimens. To correct for this geometric difference, cubic strength values were converted to equivalent cylindrical strengths. This comparison is shown in
Figure 12.
Trendlines were used to estimate the relationship between compressive and tensile strength. These trendlines also formed the basis for the development of new prediction models.
Table 17 provides the mathematical expressions obtained from the trendlines together with the associated model structures.
This study assessed previously published models describing the compressive–tensile strength relationship in LDPE concrete alongside newly formulated models, using statistical measures derived from aggregated experimental data. The findings and corresponding equations are summarized in
Table 18. The literature review confirmed the absence of models addressing the compressive–tensile strength correlation in LDPE-modified mortar.
The model of the relationship between tensile strength and compressive strength proposed by Sancak et al. achieved an R
2 value of 0.854, showing a much superior performance compared to the previous model proposed by Mohammed et al. [
32]. The R
2 value of the model proposed by Mohammed et al. [
32] was quite close to 0. The comparison of the models in terms of R
2 and MABE indicators is shown in
Figure 13.
4.3. Formulation of the Flexural Strength Prediction Model
A graph was employed to assess flexural strength, with the vertical axis expressing the ratio
and the horizontal axis showing (
). The ratio provided a normalized basis for evaluating LDPE-modified mixtures against the reference concrete. The resulting chart is displayed in
Figure 14.
Trend lines were obtained expressing the mathematical relationship between the percentage of LDPE substitution and the flexural strength ratio. Separate models were proposed for concrete mixes, mortar mixes, the experimental results obtained in this study, and all results.
The mathematical expressions obtained are documented in
Table 19, with
referring to the flexural strength of LDPE-substituted concrete,
pertaining to the control mix, and
expressing the substitution ratio of LDPE particles.
Extensive investigations have addressed the relationship between the compressive and flexural strengths of concrete, with several studies proposing analytical models to characterize this interaction. Building upon previously proposed models, this study creates a graph comparing compressive strength to flexural strength, as shown in
Figure 15. Trend lines are plotted based on the data set in this graph. New models are then created using these trend lines to predict flexural strength from compressive strength values. The resulting equations and models are presented in
Table 20.
Review of prior studies confirmed the absence of models addressing either the compressive strength–LDPE substitution ratio or the compressive–flexural strength relationship in LDPE concrete. The validity of the proposed models was examined using statistical measures, with results summarized in
Table 19 and
Table 20.
4.4. Formulation of the Modulus of Elasticity Prediction Model
A plot was employed to examine the modulus of elasticity, where the vertical axis corresponds to the ratio
and the horizontal axis reflects (
). The ratio provided a normalized basis for evaluating LDPE-modified mixtures against the control concrete, with the graphical outcome presented in
Figure 16.
The relationship between LDPE substitution percentage and the modulus of elasticity was modeled by applying a trendline to the observed data. The review of current literature revealed no prior studies reporting modulus of elasticity values for LDPE-modified concrete. Therefore, the fitted trendline only considers the data from this study.
The equation derived from this trendline is presented in
Table 21. In
Table 19,
is defined as the modulus of elasticity of concrete incorporating LDPE, whereas
corresponds to the modulus of elasticity of the reference concrete without LDPE substitution. The parameter
designates the proportion of LDPE employed as a replacement for fine aggregate.
A graph illustrating the relationship between compressive strength and modulus of elasticity of LDPE-substituted concrete is presented in
Figure 17.
To capture the relationship between compressive strength and the modulus of elasticity, a trendline was fitted to the data, and the resulting equation is reported in
Table 22.
The review of prior studies revealed a lack of models addressing compressive strength in relation to LDPE substitution or modulus of elasticity. Reliability of the models proposed in this work was examined through statistical evaluation, with results and equations presented in
Table 21 and
Table 22.
This study has several limitations that should be acknowledged. First, the experimental program was limited to specific LDPE substitution ratios (10%, 20%, and 30%) and a single water-to-cement ratio, which may restrict the generalizability of the results. Second, the database compiled from the literature includes variability in experimental conditions, specimen geometries, and testing standards, which may influence the accuracy of the proposed models. Although normalization procedures were applied, these differences may still introduce uncertainties. Third, the study focuses only on the mechanical properties of LDPE-modified concrete, and no microstructural analyses, such as scanning electron microscopy (SEM) or X-ray diffraction (XRD), were conducted to explain the internal mechanisms governing the observed behavior. In addition, only granular LDPE used as fine aggregate replacement was considered, excluding other forms such as fibers or hybrid plastic systems. While the increased strain capacity is documented, the practical implications of this behavior on structural performance—such as specific seismic resistance parameters or dynamic impact strength—were not directly tested in this study and remain as significant areas for future investigation. Finally, the proposed models are based on available experimental data and may require further validation with larger and more diverse datasets to ensure broader applicability.