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Article

Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance

1
St. Petersburg State University, 7/9 Universitetskaya Nab., 199034 St. Petersburg, Russia
2
Sirius University of Science and Technology, 1 Olympic Ave, 354340 Sochi, Russia
3
Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov Str., 220072 Minsk, Belarus
*
Author to whom correspondence should be addressed.
Polymers 2021, 13(16), 2804; https://doi.org/10.3390/polym13162804
Submission received: 21 July 2021 / Revised: 14 August 2021 / Accepted: 17 August 2021 / Published: 20 August 2021
(This article belongs to the Special Issue Advanced Polymeric Materials for Membrane Technology)

Abstract

Wide application of ultrafiltration in different industrial fields requires the development of new membranes with tailored properties and good antifouling stability. This study is devoted to the improvement of ultrafiltration properties of poly(m-phenylene isophtalamide) (PA) membranes by modification with titanium oxide (TiO2) particles. The introduction of TiO2 particles improved membrane separation performance and increased antifouling stability and cleaning ability under UV irradiation. The developed membranes were characterized by scanning electron and atomic force microscopy methods, the measurements of water contact angle, and total porosimetry. The transport properties of the PA and PA/TiO2 membranes were tested in ultrafiltration of industrially important feeds: coolant lubricant (cutting fluid) emulsion (5 wt.% in water) and bovine serum albumin (BSA) solution (0.5 wt.%). The PA/TiO2 (0.3 wt.%) membrane was found to possess optimal transport characteristics in ultrafiltration of coolant lubricant emulsion due to the highest pure water and coolant lubricant fluxes (1146 and 32 L/(m2 h), respectively), rejection coefficient (100%), and flux recovery ratio (84%). Furthermore, this membrane featured improved ability of surface contamination degradation after UV irradiation in prolonged ultrafiltration of BSA, demonstrating a high flux recovery ratio (89–94%).
Keywords: poly(m-phenylene isophthalamide); titanium oxide; ultrafiltration; fouling; cutting fluid; bovine serum albumin poly(m-phenylene isophthalamide); titanium oxide; ultrafiltration; fouling; cutting fluid; bovine serum albumin
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MDPI and ACS Style

Dmitrenko, M.; Kuzminova, A.; Zolotarev, A.; Liamin, V.; Plisko, T.; Burts, K.; Bildyukevich, A.; Ermakov, S.; Penkova, A. Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance. Polymers 2021, 13, 2804. https://doi.org/10.3390/polym13162804

AMA Style

Dmitrenko M, Kuzminova A, Zolotarev A, Liamin V, Plisko T, Burts K, Bildyukevich A, Ermakov S, Penkova A. Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance. Polymers. 2021; 13(16):2804. https://doi.org/10.3390/polym13162804

Chicago/Turabian Style

Dmitrenko, Mariia, Anna Kuzminova, Andrey Zolotarev, Vladislav Liamin, Tatiana Plisko, Katsiaryna Burts, Alexandr Bildyukevich, Sergey Ermakov, and Anastasia Penkova. 2021. "Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance" Polymers 13, no. 16: 2804. https://doi.org/10.3390/polym13162804

APA Style

Dmitrenko, M., Kuzminova, A., Zolotarev, A., Liamin, V., Plisko, T., Burts, K., Bildyukevich, A., Ermakov, S., & Penkova, A. (2021). Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance. Polymers, 13(16), 2804. https://doi.org/10.3390/polym13162804

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