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Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution

Institute of Marine Materials Science and Engineering, College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing Institute of Petrochemical Technology, Beijing 102617, China
Authors to whom correspondence should be addressed.
Polymers 2019, 11(5), 850;
Received: 11 April 2019 / Revised: 4 May 2019 / Accepted: 6 May 2019 / Published: 10 May 2019
(This article belongs to the Special Issue Graphene-Polymer Composites II)
PDF [5565 KB, uploaded 10 May 2019]


The corrosion behavior of zinc-rich epoxy primers or paints (ZRPs) with different conducting polyaniline-grafted graphene (PANI/Gr) contents was investigated. Conductivity of the formed PANI/Gr nanosheets was significantly improved by employing the Gr as the inner template to synthesize the PANI. The protective properties and electrochemical behavior of coatings with artificial defects were investigated by monitoring the free corrosion potential versus time and by using localized electrochemical impedance spectroscopy (LEIS). A synergetic enhancement of the physical barrier role of the coating and the zinc sacrificial cathodic protection was achieved in the case of ZRP including PANI/Gr nanosheets. In addition, the ZRP mixed with the PANI/Gr at a content of 0.6% exhibited the best anticorrosion performance across the range of investigated PANI/Gr contents. View Full-Text
Keywords: conducting polymer; PANI; LEIS; graphene; corrosion conducting polymer; PANI; LEIS; graphene; corrosion

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Lei, Y.; Qiu, Z.; Liu, J.; Li, D.; Tan, N.; Liu, T.; Zhang, Y.; Chang, X.; Gu, Y.; Yin, Y. Effect of Conducting Polyaniline/Graphene Nanosheet Content on the Corrosion Behavior of Zinc-Rich Epoxy Primers in 3.5% NaCl Solution. Polymers 2019, 11, 850.

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