Utilization of Waste Leather Powders for Highly Effective Removal of Dyes from Water
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of CL Powder
2.3. Adsorption Study
2.4. Characterization
3. Results and Discussion
3.1. Characterization of CL and CL Powder
3.2. Adsorption Isotherms
3.3. Adsorption Kinetics
3.4. Comparison of CL with Other Powders
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Dyes | Langmuir Isotherm | Freundlich Isotherm | ||||
---|---|---|---|---|---|---|
Qm (mg·g−1) | Kl (L·mg−1) | R2 | Kf (mg·g−1) (L·mg−1)1/n | 1/n | R2 | |
RR120 | 167.0 | 0.0229 | 0.9813 | 7.5268 | 0.5548 | 0.9231 |
RY167 | 178.9 | 0.0174 | 0.9953 | 6.4474 | 0.5946 | 0.9863 |
RB222 | 129.5 | 0.0300 | 0.9824 | 8.0707 | 0.4877 | 0.9622 |
C0 (mg·L−1) | Dyes | Qe,exp (mg·g−1) | Pseudo-First Order | Pseudo-Second Order | ||||
---|---|---|---|---|---|---|---|---|
k1 (min−1) | Qe,cal (mg·g−1) | R2 | k2 (g·mg−1·min−1) | Qe,cal (mg·g−1) | R2 | |||
50 | RR120 | 7.9861 | 0.0187 | 1.0179 | 0.3029 | 0.4502 | 8.0626 | 0.9984 |
RY167 | 8.5526 | 0.0336 | 1.1972 | 0.5204 | 0.0706 | 8.6118 | 0.9920 | |
RB222 | 7.1078 | 0.0034 | 1.6949 | 0.1497 | 0.1909 | 6.9818 | 0.9934 | |
100 | RR120 | 16.667 | 0.0467 | 1.7518 | 0.5170 | 0.4081 | 16.667 | 0.9999 |
RY167 | 15.278 | 0.0151 | 1.5394 | 0.1910 | 0.0602 | 15.258 | 0.9956 | |
RB222 | 16.071 | 0.0068 | 1.4082 | 0.2124 | 0.0831 | 15.654 | 0.9893 | |
200 | RR120 | 33.378 | 0.0411 | 1.1530 | 0.5745 | 0.3771 | 33.378 | 0.9999 |
RY167 | 30.503 | 0.0104 | 2.8279 | 0.1709 | 0.0518 | 30.503 | 0.9973 | |
RB222 | 32.068 | 0.0193 | 3.5523 | 0.2061 | 0.0222 | 32.227 | 0.9996 | |
300 | RR120 | 50.000 | 0.0213 | 1.3612 | 0.2770 | 0.2391 | 49.900 | 0.9999 |
RY167 | 45.856 | 0.0180 | 10.457 | 0.3515 | 0.0306 | 45.856 | 0.9984 | |
RB222 | 48.918 | 0.0309 | 12.086 | 0.5965 | 0.0113 | 49.617 | 0.9992 |
Adsorbent | Dyes | Qm (mg·g−1) | Ref. |
---|---|---|---|
Leather powder | Reactive red 120 Reactive yellow 167 Reactive blue 222 | 167.0 178.9 129.5 | This work |
Banana peel powder | Reactive black 5 | 49.20 | [8] |
Congo red | 164.6 | ||
Silk fibroin powder | Methylene blue | 20.58 | [16] |
Down powder | Acid brilliant scarlet 3R | 147.7 | [32] |
Mango seed kernel powder | Methylene blue | 142.9 | [63] |
Neem tree leaf powder | Methylene blue | 30.66 | [64] |
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Xia, L.; Li, C.; Zhou, S.; Fu, Z.; Wang, Y.; Lyu, P.; Zhang, J.; Liu, X.; Zhang, C.; Xu, W. Utilization of Waste Leather Powders for Highly Effective Removal of Dyes from Water. Polymers 2019, 11, 1786. https://doi.org/10.3390/polym11111786
Xia L, Li C, Zhou S, Fu Z, Wang Y, Lyu P, Zhang J, Liu X, Zhang C, Xu W. Utilization of Waste Leather Powders for Highly Effective Removal of Dyes from Water. Polymers. 2019; 11(11):1786. https://doi.org/10.3390/polym11111786
Chicago/Turabian StyleXia, Liangjun, Chen Li, Sijie Zhou, Zhuan Fu, Yun Wang, Pei Lyu, Jiajing Zhang, Xin Liu, Chunhua Zhang, and Weilin Xu. 2019. "Utilization of Waste Leather Powders for Highly Effective Removal of Dyes from Water" Polymers 11, no. 11: 1786. https://doi.org/10.3390/polym11111786