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Polymers 2018, 10(9), 990;

Morphology and Thermal Properties of Calcium Alginate/Reduced Graphene Oxide Composites

College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China
College of Life Sciences, Qingdao University, Qingdao 266071, China
Authors to whom correspondence should be addressed.
Received: 21 August 2018 / Revised: 3 September 2018 / Accepted: 4 September 2018 / Published: 5 September 2018
(This article belongs to the Special Issue Thermal Properties and Applications of Polymers)
PDF [2957 KB, uploaded 7 September 2018]


Calcium alginate (CaAlg) is a kind of biodegradable and eco-friendly functional material, and CaAlg/reduced graphene oxide (rGO) composites are expected to be applied as new textile, heat-generating, and flame-retardant materials. In this paper, the CaAlg/rGO composites were prepared by a sol-gel method and their morphological and thermal properties were studied. The results showed that the introduction of rGO can efficiently improve the thermal stability of CaAlg. Further study showed that rGO increased the carbon formation rate by 4.1%, indicating that the thermal stability was improved by the promotion of carbon formation. Moreover, the weight loss rate of the composites was faster at 180–200 °C than that of CaAlg, after which the rate was less comparatively, suggesting the better thermal stability of the composite. This maybe because the high heat transfer efficiency of rGO allowed the material to reach the temperature of the thermal decomposition of the glycan molecule chain within a short time, and then promoted carbon formation. The thermal cracking mechanism of the composites is proposed based on the experimental data. View Full-Text
Keywords: calcium alginate; reduced graphene oxide; composites; morphology; thermal stability calcium alginate; reduced graphene oxide; composites; morphology; thermal stability

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Zhao, W.; Qi, Y.; Wang, Y.; Xue, Y.; Xu, P.; Li, Z.; Li, Q. Morphology and Thermal Properties of Calcium Alginate/Reduced Graphene Oxide Composites. Polymers 2018, 10, 990.

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